Silver-containing P-type semiconductor
A technology of n-type semiconductor and semiconductor, which is applied in the direction of lead wire materials, electrical components, circuits, etc. of thermoelectric devices, which can solve the problems of low efficiency of thermoelectric devices.
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Embodiment 1
[0096] The formula Ag was prepared by using stoichiometric amounts of Ag (0.2234g), Pb (4.2919g), Sn (2.4586g), Sb (0.1681g) and Te (5.8726g) 0.9 Pb 9 sn 9 Sb 0.6 Te 20 thermoelectric materials. Various elements were loaded in a 13 mm quartz tube and placed under vacuum (10 -4 support or below) seal. The tube was placed in an oven and heated for 20 hours up to a temperature of 980°C. The furnace was held at 980°C for an additional hour, then the furnace was shaken at 980°C for 2 hours. Shake at a frequency of 1-2 cycles / min. The oven was then stopped from shaking and held vertically at 980°C for an additional hour. The furnace was then cooled to 450°C in 53 hours and further cooled to 50°C in 20 hours.
[0097] Measure electrical conductivity, thermoelectromotive force and thermal conductivity from 300K to 800K, and calculate figure of merit based on temperature. The figure of merit is about 1.0 at 620K, about 1.3 at 700K, and about 1.4 at 800K.
Embodiment 2
[0099] In a similar manner, Ag 0.9 Pb 10 sn 8 Sb 0.8 Te 20 . It has a figure of merit of 1.6 at 800K.
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