Extrusion or injection molding composition and method for preparing molded part
A technology of extrusion molding and injection molding, which is applied in the direction of ceramic molding machines, manufacturing tools, ceramic products, etc., and can solve the problems that depend on the shape and size of ceramic particles, unpredictable effects, and inability to achieve effects, etc.
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[0021] In the preparation of methylcellulose, in addition to methyl chloride or dimethyl sulfate, mixed ethers such as hydroxypropylmethylcellulose and hydroxypropylmethylcellulose can also be prepared by reacting ethylene oxide or propylene oxide. Ethyl methylcellulose. A hydroxyl group having a degree of substitution of 19-30 wt% of methyl groups and a degree of substitution of 4-12 wt% of hydroxyethyl or hydroxypropyl groups and a viscosity of 50-200,000 mPa.s in a 2 wt% aqueous solution at 20°C can be used. Ethyl methylcellulose and hydroxypropyl methylcellulose. The degree of substitution and viscosity can be measured by the method described in "Japanese Pharmacopoeia", 14th edition. These cellulose ethers with a degree of substitution outside the range defined above may be insufficiently water soluble and fail to develop sufficient cohesion when drying molded ceramic parts. A viscosity that is too low may result in insufficient cohesion, while at a viscosity that is to...
Embodiment 1-9
[0030] To 100 parts by weight of alumina particles (obtained from Admatechs Co., Ltd.) with an average particle diameter of 0.4-13 μm and a sphericity shown in Table 1 (obtained from Admatechs Co., Ltd.), 2.0-10.0 parts by weight of of cellulose ether and water in the amounts shown in Table 1. They were mixed in Super-Mixer (Kawada Mfg. Co., Ltd.) by driving stirring blades at 1000 rpm, and then at 15° C. on a small three-roll mill (Inoue Mfg. Co. Ltd.). The resulting compound was extrusion-molded into a billet honeycomb member using a laboratory honeycomb extruder (Miyazaki Iron Works Co., Ltd.) with a honeycomb die having rib lines of 0.2 mm Thickness (rib gage), rib line spacing of 5mm and diameter of 20mm. It was dried at 100°C for 16 hours. After drying, the honeycomb structure was heated at 500°C for 2 hours, the binder was burned off and sintered in an electric furnace at 1700°C.
[0031] In all the molding trials of Examples 1-9 shown in Table 1, no parting or rib l...
Embodiment 10-18
[0053] In these examples, the compounds of Examples 1-9 were extruded into a honeycomb member through a honeycomb die having a rib line thickness of 0.1 mm, a rib line spacing of 4 mm, and a diameter of 20 mm , and dried at 100°C for 16 hours. After drying, the honeycomb member was heated at 500°C for 2 hours to burn off the binder and sintered in an electric furnace at 1700°C.
[0054] In all molding trials of Examples 10-18, no parting waves were obtained during molding, especially near the outer periphery, and after molding, no cracking occurred during the drying step ceramic honeycomb components.
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