Titanium-zirconium-niobium-tin high-temperature shape memory alloy material and preparation method thereof
A technology of memory alloy and shape alloy is applied in the field of titanium zirconium niobium tin high temperature shape memory alloy material to achieve the effect of improving the high temperature shape memory capability
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[0021] The preparation method and steps of the titanium-zirconium-niobium-tin high-temperature shape memory alloy material of the present invention are as follows:
[0022] (1) According to the chemical composition ratio of TiZrNbSn, the titanium with a purity of 99.9%, the zirconium with a purity of 99.9%, the niobium (Nb) with a purity of 99.9% and the tin with a purity of 99.9% are weighed;
[0023] (2) Put the above-mentioned titanium, zirconium, niobium and tin raw materials into a non-consumable vacuum electric arc furnace, and evacuate to 2×10 -3 Pa~5×10 -3 Pa, filled with high-purity argon to 1.01×10 5 Pa, and then smelted into TiZrNbSn ingots at 1700 ° C ~ 2000 ° C;
[0024] (3) Put the above-mentioned obtained TiZrNbSn ingot into a vacuum heat treatment furnace for heat treatment. -3 Pa~5×10 -3 Pa, heat treatment temperature 850°C-900°C for 1-2 hours, then quenching in water to obtain the titanium-zirconium-niobium-tin high-temperature shape memory alloy material...
Embodiment 1
[0030] Example 1: Ti 54 Zr 32 Nb 10 sn 4 Alloy materials
[0031] (1) Press Ti 54 Zr 32 Nb 10 sn 4 The ingredients are titanium with a purity of 99.9%, zirconium with a purity of 99.9%, niobium with a purity of 99.9% and tin with a purity of 99.9%;
[0032] (2) Put the above-mentioned titanium, zirconium, niobium and tin block raw materials into a non-consumable vacuum electric arc furnace, and evacuate to 5×10 -3 Pa, filled with high-purity argon to 1.01×10 5 Pa, and then smelted into TiZrNbSn ingots above 1800°C;
[0033] (3) Put the above-mentioned obtained TiZrNbSn ingot into the vacuum heat treatment furnace for heat treatment, at a vacuum degree of 5×10 -3 Pa, after heat treatment at 900°C for 1 hour, quenching in water, the Ti required by the present invention can be obtained. 54 Zr 32 Nb 10 sn 4 High temperature shape memory alloy materials.
[0034] Using the wire cutting method, the Ti obtained above 54 Zr 32 Nb 10 sn4 The cutting size of the alloy...
Embodiment 2
[0035] Example 2: Ti 60 Zr 31 Nb 2 sn 7 Alloy materials
[0036] (1) Press Ti 60 Zr 31 Nb 2 sn 7 The ingredients are titanium with a purity of 99.9%, zirconium with a purity of 99.9%, niobium with a purity of 99.9% and tin with a purity of 99.9%;
[0037] (2) Put the above-mentioned titanium, zirconium and tin block raw materials into a non-consumable vacuum electric arc furnace, and vacuumize to 5×10 -3 Pa, filled with high-purity argon to 1.01×10 5 pa, and then smelted into TiZrNbSn ingot at 2000℃;
[0038] (3) Put the above-mentioned obtained TiZrNbSn ingot into the vacuum heat treatment furnace for heat treatment, at a vacuum degree of 5×10 -3 Pa, after heat treatment at 900°C for 1 hour, quenching in water, the Ti required by the present invention can be obtained. 60 Zr 31 Nb 2 sn 7 High temperature shape memory alloy materials.
[0039] Performance testing method is identical with embodiment 1, Ti 60 Zr 31 Nb 2 sn 7 The stress-strain curve of the hig...
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