Reaction device for preparing low carbon olefin from methanol or dimethyl ether

A technology of low-carbon olefins and reaction devices, applied in the field of reaction devices, can solve the problems of low yield of low-carbon olefins, achieve the effects of improving selectivity, shortening residence time, and reducing impact

Active Publication Date: 2008-12-31
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0007] The technical problem to be solved by the present invention is the low yield of low-carbon olefins in the

Method used

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  • Reaction device for preparing low carbon olefin from methanol or dimethyl ether

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Effect test

Embodiment 1

[0017] in such as figure 1 In the reaction device shown, the average temperature of the first reaction zone 2 is 470°C, the average temperature of the second reaction zone 3 is 530°C, the pressure at the top of the separation zone 7 of the reactor is 0.14MPa in gauge pressure, and the pure methanol feed , the feed is 2 kg / h, the superficial linear velocity of gas in the first reaction zone 2 is 1.1 m / s, the catalyst is modified SAPO-34, and the lifting medium of the regenerated catalyst circulation pipe 15 is unreacted methanol and dimethylformamide Ether, the heat exchange medium between the heat extractor 11 outside the reactor and the unborn catalyst is water vapor. The ratio of the diameter of the second reaction zone 3 and the first reaction zone 2 is 1.2: 1; the ratio of the diameter of the gas-solid rapid separation device 5 and the diameter of the second reaction zone 3 is 0.3: 1; The gas-solid cyclone separator 6 has two stages. The average catalyst carbon deposit i...

Embodiment 2

[0019] According to the conditions described in Example 1, the superficial linear velocity of gas in the first reaction zone 2 is 2.0 m / s, the ratio of the diameter of the second reaction zone 3 to the first reaction zone 2 is 2.0:1, and the gas-solid separation is rapid. The ratio of the diameter of the equipment 5 to the diameter of the second reaction zone 3 is 0.15:1, the lifting medium of the regenerated catalyst circulation pipe 15 is water vapor, and the yield of light olefins reaches 84.32% by weight.

Embodiment 3

[0021] According to the conditions described in Example 1, the hydrocarbons above C4 separated by the product separation section are divided into two parts, one part is used as the lifting medium of the regenerated catalyst circulation pipe 15, and the other part passes through the feedstock at the axial position of the second reaction zone 3. The mouth enters the second reaction zone, and the number of feed inlets is two, which is a counter-spray type, and the distance between the feed inlet position and the distribution plate 4 is 1 / 4 of the height of the second reaction zone 3 . Change the average temperature of the first reaction zone 2 to 500°C, the ratio of the diameter of the second reaction zone 3 to the first reaction zone 2 is 1.4:1; The ratio is 0.5:1; the gas-solid cyclone separator 6 in the separation zone 7 of the reactor has three stages, and the yield of light olefins reaches 88.43% by weight.

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Abstract

The invention relates to a reaction device which uses methanol or dimethyl ether to prepare low-carbon olefin, mainly to solve the problem of low low-carbon olefin production rate in the prior art. The reaction device which uses methanol or dimethyl ether to prepare low-carbon olefin mainly comprises a first reaction zone 2, a second reaction zone 3, a catalyst circulation zone and a reactor separation zone 7; a material inlet 1 is arranged at the lower part of the first reaction zone 2; the upper part of the first reaction zone is connected with the second reaction zone 3; a gas-solid cyclone separator 6 is arranged inside the reactor separation zone 7; the upper part of the reactor separation zone 7 is provided with a product outlet 8; three catalyst outlets are arranged at the lower part of the reactor separation zone 7, wherein, the first catalyst outlet is connected with the first reaction zone 2 through an external circulation inclined tube 13 of the reactor; the second catalyst outlet is connected with a regenerator through a spent catalyst circulation inclined tube 9; the third catalyst outlet is connected with a heater 11 outside the reactor; the bottom part of the heater 11 outside the reactor is connected with the first reaction zone 2; the regenerated catalyst returns to the second reaction zone 3 through a regenerated catalyst circulation tube 15; a distribution board 4 is arranged at the bottom part of the second reaction zone 3; a gas-solid rapid separation equipment 5 is arranged at the upper part of the second reaction zone 3. Such a technical proposal solves all the problems and the device can be used for low-carbon olefin industrial production.

Description

technical field [0001] The invention relates to a reaction device for preparing light olefins from methanol or dimethyl ether. technical background [0002] Low-carbon olefins, namely ethylene and propylene, are two important basic chemical raw materials, and their demand is increasing. Generally, ethylene and propylene are produced through petroleum routes, but due to the limited supply and high price of petroleum resources, the cost of producing ethylene and propylene from petroleum resources continues to increase. In recent years, people have begun to vigorously develop the technology of converting alternative raw materials into ethylene and propylene. Among them, an important class of alternative raw materials for the production of light olefins are oxygenates, such as alcohols (methanol, ethanol), ethers (dimethyl ether, methyl ethyl ether), esters (dimethyl carbonate, methyl formate Esters), etc., these oxygenated compounds can be converted from coal, natural gas, bi...

Claims

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Application Information

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IPC IPC(8): C07C1/20C07C11/02B01J29/85B01J29/90
CPCY02P20/584
Inventor 齐国祯钟思青金永明刘国强
Owner CHINA PETROLEUM & CHEM CORP
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