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Sustained-release water reducing agent for cement concrete and method for preparing same

A technology for cement concrete and water reducing agent, which is applied in the field of powdered water reducing agent with slow release effect and its preparation field, can solve the problems that liquid water reducing agent is not easy to store, affects concrete early strength, concrete slump loss and the like, Achieve the effect of solving slump loss, restraining dissolution time and reducing transportation cost

Inactive Publication Date: 2009-01-07
SOUTHWEAT UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the prior art, the water reducer used in cement concrete generally adopts liquid naphthalene-based water-reducer or polycarboxylate-based water-reducer. During the use of these water-reducers, the following problems often occur: pumping difficulties and Concrete slump loss is too fast and rapid hardening
The most commonly used method to control slump loss is to rely on the addition of retarders, but the addition of retarders will affect the development of early strength of concrete, which is very unfavorable in many occasions
In addition, since liquid water reducers are not easy to store, especially for engineering construction in remote areas, long-distance transportation will greatly increase transportation costs, and the practicability is poor

Method used

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  • Sustained-release water reducing agent for cement concrete and method for preparing same
  • Sustained-release water reducing agent for cement concrete and method for preparing same

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0044] A preparation method of a slow-release water reducer for cement concrete, comprising the following steps:

[0045] a, preparation of layered double metal hydroxide:

[0046] According to Mg(NO 3 ) 2 ·6H 2 O:Al(NO 3 ) 3 9H 2 The molar ratio of O is 2:1 and Mg(NO 3 ) 2 ·6H 2 O and Al(NO 3 ) 3 9H 2 O, get urea at a molar ratio of 1:3 by urea: the sum of nitrate ions is placed in a reactor, and then add distilled water at a mass ratio of 1:2 by a solid-to-liquid ratio; in an oil bath at 95 to 120°C, Stir the reaction for 12 hours, stop stirring; then put the reaction material in a water bath at 85-95°C for 12 hours; filter, wash the solid with distilled water until pH<8, and dry at 80°C for 8 hours to obtain a layered MgAl bimetallic hydroxide;

[0047] b. Preparation of double metal oxides:

[0048] Calcining the obtained layered MgAl double metal hydroxide at a temperature of 450-550° C. for 2 hours to obtain a MgAl double metal oxide;

[0049] c. Preparati...

Embodiment 2

[0054] A preparation method of a slow-release water reducer for cement concrete, comprising the following steps:

[0055] a, preparation of layered double metal hydroxide:

[0056] According to Mg(NO 3 ) 2 ·6H 2 O:Al(NO 3 ) 3 9H 2 The molar ratio of O is 2:1 and Mg(NO 3 ) 2 ·6H 2 O and Al(NO 3 ) 3 9H 2 O, get urea at a molar ratio of 1:5 by urea: the sum of nitrate ions is all placed in the reactor, and then add distilled water at a mass ratio of 1:5 by solid-to-liquid ratio; in an oil bath at 95 to 120°C, Stir the reaction for 48 hours, stop stirring; then put the reaction material in a water bath at 85-95°C for 48 hours; filter, wash the solid with distilled water until pH<8, and dry at 80°C for 12 hours to obtain a layered MgAl bimetallic hydroxide;

[0057] b. Preparation of double metal oxides:

[0058] Calcining the obtained layered MgAl double metal hydroxide at a temperature of 450-550° C. for 4 hours to obtain a MgAl double metal oxide;

[0059] c. Prep...

Embodiment 3

[0064] A preparation method of a slow-release water reducer for cement concrete, comprising the following steps:

[0065] a, preparation of layered double metal hydroxide:

[0066] According to Mg(NO 3 ) 2 ·6H 2 O:Al(NO 3 ) 3 9H 2 The molar ratio of O is 2:1 and Mg(NO 3 ) 2 ·6H 2 O and Al(NO 3 ) 3 9H 2 O, get urea at a molar ratio of 1:4 by urea: the sum of nitrate ions is all placed in the reactor, and then add distilled water at a mass ratio of 1:3.5 by the solid-to-liquid ratio; in an oil bath at 95 to 120°C, Stir the reaction for 24 hours, stop stirring; then put the reaction material in a water bath at 85-95°C for 24 hours; filter, wash the solid with distilled water until pH<8, and dry at 80°C for 10 hours to obtain a layered MgAl bimetallic hydroxide;

[0067] b. Preparation of double metal oxides:

[0068] Calcining the obtained layered MgAl double metal hydroxide at a temperature of 450-550° C. for 3 hours to obtain a MgAl double metal oxide;

[0069] c...

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Abstract

The invention provides a cement concrete slowly-released water reducer. The cement concrete slow-released water reducer is characterized in that the water reducer consists of bimetal hydrate, and a cement concrete used water reducer dispersed in the stratiform bimetal hydrate; the stratiform bimetal hydrate is stratiform MgAl bimetal hydrate or stratiform CaAl bimetal hydrate; the water reducer is a water reducer of naphthalene series or a water reducer of poly carboxylic acid series; the preparation method of the slowly-released water reducer comprises the steps of preparing the stratiform bimetal hydrate, preparing a bimetal oxide and preparing the slowly-released water reducer and so on. In the invention, the roasted product of the stratiform bimetal hydrate, namely, the bimetal oxide, is added to the solution containing the water reducer which enters the layers during the reconstruction of the stratiform structure, thus preparing the powdered water reducer. When the water reducer having the slow release performance is added to and mixed in the concrete at one time, the water reducer is released slowly, thus effectively reducing the loss of the slump constant of concrete; the transportation cost of the powdered slowly-released water reducer can be significantly reduced.

Description

technical field [0001] The invention belongs to organic-inorganic materials as effective components of concrete and its preparation method, and relates to a slow-release water reducer for cement concrete and its preparation method, in particular to a powdered water reducer with slow release effect and its preparation method . Background technique [0002] Since the British Joseph Aspdin (Joseph Aspdin) invented Portland cement in 1824, the production and application technology of concrete has developed rapidly, the amount of concrete has increased sharply, and the scope of use has expanded day by day. At present, concrete has become one of the most important engineering materials. The development of modern concrete water reducing agent technology is the key to the development of modern concrete technology and plays a decisive role in the development of concrete technology. The innovation and development of concrete water reducing agent technology has always been Emphasis an...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B22/06C04B103/30
CPCC04B2103/308C04B24/2641C04B2103/302C04B24/226
Inventor 严云王素娟胡志华卢忠远
Owner SOUTHWEAT UNIV OF SCI & TECH
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