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Formulation process for synthesis of gasoline with methanol

A methanol synthesis and gasoline technology, which is applied in the petroleum industry, liquid carbon-containing fuels, fuels, etc., can solve the problems of affecting the use effect, low calorific value of methanol, corrosion and swelling, etc., and achieve improved thermal efficiency, excellent power performance, and extended service life. Effect

Inactive Publication Date: 2009-01-14
王飞
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Methanol gasoline is such a new energy source, which has certain applications in daily life, but the existing methanol gasoline is simply mixed with a certain proportion of methanol in gasoline, which is in the case of a low proportion of 3-5%. However, with the increase of the proportion of methanol, many problems such as low heating value of methanol, lack of power, high fuel consumption, difficult cold start, high temperature air resistance, poor stability, corrosion and swelling, and miscibility with gasoline will occur. Exposed one by one, seriously affecting the use effect

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] Embodiment one: provide a kind of preparation process of methanol synthetic gasoline, it is mixed by the raw material of following weight percent:

[0036] Industrial Methanol 68%

[0037] GB gasoline 30%

[0038] Solubilizing denaturant 2%

[0039] Compound functional agent 0.1%

[0040] Its preparation process is as follows: under the conditions of normal temperature, normal pressure, no spark, fire prevention and explosion protection, first add the solubilizing denaturant into industrial methanol, after stirring for 5-10 minutes, add the composite functional agent, and then stir for 5-10 minutes, Add national standard gasoline or base gasoline or a mixture of the two in any proportion, and continue stirring for 5 minutes to complete the preparation.

[0041] The industrial methanol is crude alcohol with a methanol content of more than 80%.

[0042] Described national standard gasoline is national standard 90#.

[0043] Described solubilizing denaturant is mixed ...

Embodiment 2

[0063] Embodiment two: provide a kind of preparation process of methanol synthetic gasoline, it is mixed by the raw material of following weight percent:

[0064] Industrial Methanol 47%

[0065] GB gasoline 50%

[0066] Solubilizing denaturant 2.5%

[0067] Compound functional agent 0.15%

[0068] Its preparation process is identical with embodiment one.

[0069] The industrial methanol is crude alcohol with a methanol content of more than 80%.

[0070] Described national standard gasoline is national standard 90#.

[0071] Described solubilizing denaturant is mixed at normal temperature by the raw material of following percentage by weight:

[0072] Methyl formate or ethyl formate or benzoic acid, or

[0073] Mixture of two or more of them in any proportion 20-35%

[0074] Mixed C6 Alcohol 25-40%

[0075] Fatty acids 20-25%

[0076] Silicoaluminophosphate or Sodium Dihydrogen Phosphate 2-8%

[0077] Iron Naphthenate 4-6%

[0078] Diisopropyl ether 1-1.5%

[0079]...

Embodiment 3

[0091] Embodiment three: provide a kind of preparation process of methanol synthetic gasoline, it is mixed by the raw material of following weight percent:

[0092] Industrial Methanol 50%

[0093] Base Gasoline 47%

[0094] Solubilizing denaturant 3%

[0095] Compound functional agent 0.15%

[0096] Its preparation process is identical with embodiment one.

[0097] The industrial methanol is crude alcohol with a methanol content of more than 80%.

[0098] The base gasoline is condensed gasoline.

[0099] Described solubilizing denaturant is mixed at normal temperature by the raw material of following percentage by weight:

[0100] Methyl formate or ethyl formate or benzoic acid, or

[0101] Mixture of two or more of them in any proportion 20-35%

[0102] Mixed C6 Alcohol 25-40%

[0103] Fatty acids 20-25%

[0104] Silicoaluminophosphate or Sodium Dihydrogen Phosphate 2-8%

[0105] Iron Naphthenate 4-6%

[0106] Diisopropyl ether 1-1.5%

[0107] Toluene, xylene or ...

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Abstract

The invention discloses a preparation process for methanol synthetic gasoline which is mixed by the following raw materials, in weight percentage: 40 percent to 95 percent of industrial methanol; national standard gasoline or basic gasoline or a mixture thereof in random proportion, or 0 percent to 70 percent of mixture of two or more basic gasoline in random proportion; 2 percent to 5 percent of fluxing denaturant; and 0.1 percent to 0.5 percent of composite functional agent. The preparation process adopts the steps: firstly the fluxing denaturant is added into the industrial methanol for stirring for 5 minutes to 10 minutes under the conditions of normal temperature, atmospheric pressure, no spark, fire prevention and explosion protection, the composite functional agent is then added thereto for the agitation for 5 minutes to 10 minutes, then the national standard gasoline or the basic gasoline or the mixture thereof in random proportion is added thereto for being continuously stirred for 5 minutes, finally completing the preparation. The methanol synthetic gasoline prepared by the process is to add inexpensive combustible liquid methanol and other liquid combustible substances with relatively large reserves in great proportions into the traditional gasoline, the substitution rate of the petroleum composition is extremely high, the energy can be saved, the national petroleum import pressure can be reduced, massive foreign exchange disbursement can be saved, and the socioeconomic performance is good, meanwhile, the process has technical advantages of environmental protection, good power performance, corrosion resistance, extensive use scope, stable quality and simple and convenient production, and being worth wide promotion.

Description

technical field [0001] The invention relates to the technical field of new energy, in particular to a process for preparing methanol-synthesized gasoline. technical background [0002] The development of environmentally friendly new energy as an alternative fuel is the need of the national energy strategy and environmental strategy, as well as the need of the sustainable development of my country's industry and even the entire society. Methanol gasoline is such a new energy source, which has certain applications in daily life, but the existing methanol gasoline is simply mixed with a certain proportion of methanol in gasoline, which is in the case of a low proportion of 3-5%. However, with the increase of the proportion of methanol, many problems such as low heating value of methanol, lack of power, high fuel consumption, difficult cold start, high temperature air resistance, poor stability, corrosion and swelling, and miscibility with gasoline will occur. One by one expose...

Claims

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Application Information

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IPC IPC(8): C10L1/02C10L1/30C10L1/188C10L1/26C10L1/185C10L1/16C10L1/04
Inventor 王飞
Owner 王飞
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