Photosensitive composition, phososensitive film, photosensitive laminated body, permanent pattern forming method and printed substrate
A technology of photosensitive composition and compound, which is applied in the direction of printed circuit, microlithography exposure equipment, and photosensitive material used in optomechanical equipment, etc. It can solve the problem of insufficient storage stability of sensitive material, significant coloring of adhesive resin, Solve problems such as poor color and taste of sensitive materials, achieve high efficiency and stability over time, reduce coloring, and inhibit color and taste from deteriorating
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[0316] Hereinafter, the present invention will be further specifically described using examples, but the present invention is not limited thereto.
Synthetic example 1
[0318] — Synthesis of Adhesive 1 —
[0319] 159 g of 1-methoxy-2-propanol was charged into a 1,000 mL three-necked flask, and heated to 85° C. under a nitrogen stream. A 159 g 1-methoxy-2-propanol solution of 63.4 g of benzyl methacrylate, 72.3 g of methacrylic acid, and 3.0 g of V-601 (manufactured by Wako Pure Chemical Industries) was added dropwise thereto over 2 hours. After completion of the dropwise addition, the mixture was further heated for 5 hours to allow a reaction. Heating was then stopped to obtain a copolymer of benzyl methacrylate / methacrylic acid (30 / 70 mol % ratio).
[0320] Next, 120.0 g of the copolymer solution was transferred to a 300 mL three-necked flask, 16.6 g of glycidyl methacrylate and 0.16 g of p-methoxyphenol were added, and stirred to dissolve. After dissolution, 3.0 g of triphenylphosphine was added while blowing air, and heated to 100° C. After 20 minutes, glycidyl methacrylate was added to perform an addition reaction. The disappearance of...
Synthetic example 2
[0334] — Synthesis of Adhesive 2 —
[0335] Synthesis was carried out in the same manner as in Synthesis Example 1, except that the elapsed time after addition of triphenylphosphine was 25 minutes. The value of the residual TPP amount was 600 ppm in terms of solid content relative to the solid content of the binder.
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