Congealing stone gelled material with ferro-silico-manganese alloy slag as principal raw material

A technology of silicon-manganese ferroalloy and cementitious materials, applied in the field of gelatinous cementitious materials, can solve problems such as polluted water sources, dust noise, social environment and ecological environment damage, and achieve excellent performance, environmental protection and energy saving effects

Inactive Publication Date: 2009-06-24
TSINGHUA UNIV +1
1 Cites 5 Cited by

AI-Extracted Technical Summary

Problems solved by technology

For a long time, ferroalloy slag has been discharged as solid waste, occupying a large amount of land, destroying surface vegetation and landscapes, aggravating soil erosion, dust noise, polluting wate...
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Abstract

The invention discloses a glued stone gel material taking ferrosilicomanganese slag as the main raw material, which belongs to the technical field of building material. The glued stone gel material adopts the raw materials of ferrosilicomanganese slag, cement clinker, gypsum, burnt coal waste residue and a rock forming agent. The raw materials have the following weight percentage: 60 to 90 percent of ferrosilicomanganese slag, 0 to 30 percent of cement clinker, 2 to 10 percent of gypsum, 0 to 30 percent of burnt coal waste residue, and 0.5 to 10 percent of rocking forming agent. The ferrosilicomanganese slag is taken as the main raw material to produce the glued stone gel material, thereby not only making use of solid wastes, but also saving energy resources and protecting the environment. Simultaneously, the material has better performance than the ordinary Portland cement.

Application Domain

Technology Topic

Portland cementFerric +11

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  • Congealing stone gelled material with ferro-silico-manganese alloy slag as principal raw material

Examples

  • Experimental program(4)

Example Embodiment

[0019] Example 1
[0020] A cementitious material using ferrosilicon manganese alloy slag as the main raw material. The cement cementing material uses ferrosilicon manganese alloy slag, cement clinker, gypsum, coal burning waste slag and diagenetic agent as raw materials, and the content is percentage by weight Is, silico-manganese ferroalloy slag: 60%, cement clinker: 15%, gypsum (the gypsum is natural anhydrous gypsum): 6%, coal-fired waste slag: 18%, diagenetic agent (the diagenetic agent is condensate A Diagenesis): 1%.
[0021] The chemical composition of the silico-manganese-iron alloy slag is in weight percentage, Al 2 O 3 : 16.18%, SiO 2 : 39.12%, MgO: 14.53%, CaO: 29.32%, Fe 2 O 3 : 0.15%, MnO: 0.2%, ignition loss material: 0.5%.
[0022] The coal-fired waste slag is circulating fluidized bed slag and fly ash, wherein the weight percentage of circulating fluidized bed slag accounts for 10% of the cementitious material, and the weight percentage of fly ash accounts for the cementitious material Of 8%.
[0023] The weight percentage of the chemical composition of the circulating fluidized bed slag is, Al 2 O 3 : 19.34%, SiO 2 : 49.62%, MgO: 7.98%, CaO: 14.86%, Fe 2 O 3 : 5.63%, burning loss material: 2.57%.
[0024] Weigh the raw materials according to the above ratio and use The 500×500mm experimental small grinder firstly grinds the ferrosilico-manganese alloy slag and cement clinker to a specific surface area of ​​400m 2 /kg, then add circulating fluidized bed slag, fly ash, natural anhydrous gypsum and conglomerate A diagenetic agent, and mix and grind together to a specific surface area of ​​500m 2 /kg, to obtain the cemented stone material.
[0025] The achievable performance of this material according to the GB175-2007 standard for strength and stability testing is shown in Table 1. It can be seen from the table that the prepared gelatinous material has good compressive and flexural strength, and the stability test is qualified.

Example Embodiment

[0026] Example 2
[0027] A cementitious material using ferrosilicon manganese alloy slag as the main raw material. The cement cementing material uses ferrosilicon manganese alloy slag, cement clinker, gypsum, coal burning waste slag and diagenetic agent as raw materials, and the content is percentage by weight Are: silico-manganese ferro-alloy slag: 68%, cement clinker: 15%, gypsum (the gypsum is dihydrate gypsum): 6%, coal-fired waste slag: 10%, diagenetic agent (the diagenetic agent is calcite A Agent): 1%.
[0028] The chemical composition of the silico-manganese-iron alloy slag is in weight percentage, Al 2 O 3 : 27.97%, SiO 2 : 29.87%, MgO: 3.59%, CaO: 27.65%, Fe 2 O 3 : 2.97%, MnO: 4.12%, ignition loss material: 3.83%.
[0029] The coal-burning waste slag is circulating fluidized bed slag.
[0030] The weight percentage of the chemical composition of the circulating fluidized bed slag is, Al 2 O 3 : 29.98%, SiO 2 : 29.97%, MgO: 6.92%, CaO: 13.21%, Fe 2 O 3 : 9.95%, burning loss material: 9.97%.
[0031] Weigh the raw materials according to the above ratio and use A 500×500mm experimental small grinding mill will mix and grind ferrosilicon-manganese alloy slag, cement clinker, circulating fluidized bed slag, dihydrate gypsum and conglomerate A diagenetic agent together to a specific surface area of ​​550m 2 /kg, to obtain the cemented stone material.
[0032] The achievable performance of this material according to the GB175-2007 standard for strength and stability testing is shown in Table 1. It can be seen from the table that the prepared gelatinous material has good compressive and flexural strength, and the stability test is qualified.

Example Embodiment

[0033] Example 3
[0034] A cementitious material with ferro-silico-manganese alloy slag as the main raw material. The cement-silico-manganese material uses ferro-silico-manganese alloy slag, gypsum, coal-fired waste slag and diagenetic agent as raw materials, and the content by weight percentage is as follows: Ferroalloy slag: 70%, gypsum (the gypsum is phosphogypsum): 8%, coal-fired waste slag: 19%, and diagenetic agent (the diagenetic agent is a conglomerate C diagenetic agent): 3%.
[0035] The chemical composition of the silico-manganese-iron alloy slag is in weight percentage, Al 2 O 3 : 26.96%, SiO 2 : 37.89%, MgO: 11.96%, CaO: 17.52%, Fe 2 O 3: 1.86%, MnO: 1.65%, ignition loss material: 2.16%.
[0036] The coal burning waste residue is fly ash and light burned coal gangue.
[0037] The weight percentage of the fly ash accounts for 9% of the cementitious material, and the weight percentage of light burned coal gangue accounts for 10% of the cementitious material.
[0038] Weigh the raw materials according to the above ratio and use The 500×500mm experimental small grinding machine firstly grinds the ferrosilicon-manganese alloy slag to a specific surface area of ​​400m 2 /kg, then add fly ash, light burned coal gangue, phosphogypsum and conglomerate C diagenetic agent, and mix and grind together to a specific surface area of ​​580m 2 /kg, to obtain the cemented stone material.
[0039] The achievable performance of this material according to the GB175-2007 standard for strength and stability testing is shown in Table 1. It can be seen from the table that the prepared gelling stone material has good compressive and flexural strength, and the stability test is qualified.
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