Method for reducing oilseed acid value

A technology of oil acid value and oil, which is applied in the direction of fatty acid esterification, etc., can solve the problems of difficult recovery of glycerin, cumbersome process operation, and large material loss, so as to be beneficial to environmental protection and subsequent processing, simplify operation steps, and reduce oil acid value effect

A technology of oil acid value and oil, which is applied in the direction of fatty acid esterification, etc., can solve the problems of difficult recovery of glycerin, cumbersome process operation, and large material loss, so as to be beneficial to environmental protection and subsequent processing, simplify operation steps, and reduce oil acid value effect

CN101469293AActive Publication Date: 2009-07-01CHINA PETROLEUM & CHEM CORP +1

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] Provide acidified oil with an acid value of 140mgKOH / g and methanol into the tubular reactor, and the liquid hourly space velocity of the acidified oil is 0.6h -1 , the molar ratio of alcohol to oil is 5.8, the temperature in the reactor is 246°C, the pressure is 0.7MPa, and the acid value of the oil after reaction is 17.6mgKOH / g.

Embodiment 2

[0026] Provide acidified oil with an acid value of 152mgKOH / g and methanol into the tubular reactor, and the hourly space velocity of the acidified oil is 0.6h -1 , the molar ratio of alcohol to oil is 5.8, the temperature in the reactor is 213° C., the pressure is 2.5 MPa, and the acid value of the oil after reaction is 16.9 mgKOH / g.

Embodiment 3

[0028] Food waste oil and methanol with an acid value of 87mgKOH / g are used as raw materials and supplied to the tubular reactor, and the hourly space velocity of the waste oil is 0.6h -1 , the molar ratio of alcohol to oil is 5.8, the temperature in the reactor is 262°C, the pressure is 0.7MPa, and the acid value of the oil after reaction is 3.5mgKOH / g.

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PUM

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Abstract

The invention provides a method for reducing the acid value of oil materials, which comprises: reacting the oil materials of which the acid value is to be reduced and C1-C6 monobasic alcohol in a reactor, and collecting oil materials of which the acid value is reduced, wherein the temperature in the reactor is between 100 and 330 DEG C, and the pressure in the reactor is between 0.1 and less than 5 MPa. The method not only can effectively reduce the acid value of the oil materials but also can make the reaction continuously performed, does not generate waste acid, basically does not generate wastewater, and is favorable for environmental protection and subsequent processing.

Description

technical field [0001] The invention belongs to a method for processing oil, in particular to a method for reducing the acid value of oil. Background technique [0002] Oils and fats are generally derived from vegetable oils and animal oils, and the main component is glycerides. In addition, it also contains phosphoglycerides, fatty acids, fatty alcohols, vitamins, sterols, pigments, etc. Generally, the content of fatty acids in refined oils is very low, but the acid value of unprocessed and refined oils (commonly known as crude oil), used waste oils, and various fractions (such as deodorized distillates) produced during processing High, even very high, is not conducive to further processing and utilization. [0003] For example, crude oil and waste fats and oils can be used to produce biodiesel; biodiesel can be produced by transesterification of fats and oils with monoalcohols. Before using oil with high acid value to prepare biodiesel, it is generally necessary to reduc...

Claims

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Application Information

Patent Timeline
01 Jul 2009
Publication
CN101469293A
IPC
C11C3/04
Inventors
王海京; 杜泽学