Functional material for removing nitrogen from wastewater and method of preparing same

A functional material, denitrification technology, applied in chemical instruments and methods, biological water/sewage treatment, water/sludge/sewage treatment, etc. The denitrification ability is stable and durable, the effect of strengthening stable adsorption and increasing roughness

Active Publication Date: 2010-03-17
JIANGSU SUJING GROUP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

According to a survey conducted by my country's environmental monitoring department, the type of water pollution in rivers across the country is eutrophication, and the main nutritional pollutants are ammonia nitrogen and total nitrogen. In sewage treatment, microorganisms are generally used for denitrification treatment. The functional materials used in fillers are used as the carrier of microorganisms. Their materials and manufacturing processes have a direct impact on the efficiency, energy consumption, stability and reliability of the wastewater treatment process. The existing There are many functional materials, such as polyvinyl alcohol, polypropylene, etc., but they have the disadvantages of poor hydrophilicity, difficulty in microbial attachment, poor denitrification ability, and low strength and easy fracture.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Dimethylsulfoxide 62%

[0023] Acrylonitrile 14%

[0024] Acrylonitrile 10%

[0025] Methyl methacrylate 4%

[0026] Sodium acrylate sulfonate 3%

[0027] Azobisisobutyronitrile 0.05%

[0028] Dodecanethiol 0.5%

[0029] Sodium Lauryl Sulfate 1.45%

[0030] Montmorillonite 6%

[0031] Add acrylonitrile, crotononitrile, methyl methacrylate, sodium acrylate sulfonate, dimethyl sulfoxide, and sodium dodecyl sulfonate into the reaction kettle according to the above ratio, and control the reaction temperature at 60-70°C , adding azobisisobutyronitrile to initiate the polymerization reaction, adding dodecanethiol after 10 minutes, adding nano-montmorillonite powder after 1 hour, and then polymerizing for about 6 to 10 hours, a colorless transparent viscous liquid can be obtained as Spinning stock solution for use.

[0032] Put the spinning stock solution into the material kettle of the spinning machine to start spinning, and then weave and shape the fibers to obtain t...

Embodiment 2

[0034] Dimethylformamide 60%

[0035] Acrylonitrile 20%

[0036] Methyl crotonate 4%

[0037] Ethyl Acrylate 3%

[0038] Sodium Methacrylate Sulfonate 3%

[0039] Potassium persulfate 0.05%

[0040] Dodecanethiol 0.5%

[0041] Triethylhexyl Phosphate 1.45%

[0042] Kaolin 8%

[0043] Add butene nitrile, methyl crotonate, ethyl acrylate, sodium methacrylate sulfonate, dimethylformamide, and triethylhexyl phosphoric acid into the reaction kettle according to the above ratio, and control the reaction temperature at 60-70 , adding potassium persulfate to initiate the polymerization reaction, adding dodecyl mercaptan after 10 minutes, adding nano-kaolin powder after 1 hour, and then polymerization time is about 10 hours, and a yellowish viscous liquid can be obtained as a spinning stock solution for later use.

[0044] Put the spinning stock solution into the material kettle of the spinning machine to start spinning, and then weave and shape the fibers to obtain the finished p...

Embodiment 3

[0046] Dimethylacetamide 48%

[0047] Dimethylsulfoxide 10%

[0048] Acrylonitrile 13%

[0049] Acrylonitrile 10%

[0050] Ethyl crotonate 4%

[0051] Acrylic 2%

[0052] Sodium Methacrylate Sulfonate 4%

[0053] Azobisisobutyronitrile 0.05%

[0054] Dodecanethiol 0.5%

[0055] Sodium Lauryl Sulfate 1.45%

[0056] Polyacrylamide 1%

[0057] Diatomaceous earth 6%

[0058] Add acrylonitrile, crotonitril, ethyl crotonate, acrylic acid, sodium methacrylic acid sulfonate, dimethylacetamide, dimethyl sulfoxide, sodium dodecyl sulfonate and polyacrylamide in the above ratio In the reaction kettle, when the reaction temperature is controlled at 60-70°C, add azobisisobutyronitrile to initiate the polymerization reaction, add dodecanethiol after 10 minutes, add nano-diatomite powder after 1 hour, and then polymerize for 10 hours Left and right, a white viscous liquid can be obtained as a spinning dope for future use. Put the spinning stock solution into the material kettle of...

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PUM

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Abstract

The invention discloses functional material for removing nitrogen from wastewater and a method of preparing the same. The functional material comprises hydrophilic resin and inorganic nano-powder which is adhered to the hydrophilic resin. The functional material is prepared by first synthesizing the hydrophilic resin, and then adding and stirring the inorganic nano-powder to the hydrophilic resin.The inorganic nano-powder accounts for 5-20 percent of the total functional material by weight. The surface of the hydrophilic resin is provided with hydrophilic groups so that the microorganisms canbe adsorbed on the surface of the functional material easily and can not fall off from the surface of the functional material, and the nitrogen removing ability of the microorganisms can be kept fora long time. Because the functional material comprises the inorganic nano-powder which can increase the roughness of the surface of the functional material, the microorganisms can be steadily adsorbedon the surface of the functional material, and because the inorganic nano-powder is adhered to the hydrophilic resin, the gaps formed in the functional material is small, and accordingly the change of the stress of the functional material is slowed down when the functional material is impacted by the water flow and the breaking strength of the functional material is improved.

Description

technical field [0001] The invention relates to a functional material for denitrification of wastewater, and also relates to a preparation method of the functional material. Background technique [0002] my country's water resources are relatively poor, and the per capita amount of water is only 25% of the world's per capita amount. However, the pollution of water resources is becoming more and more serious. According to a survey conducted by my country's environmental monitoring department, the type of water pollution in rivers across the country is eutrophication, and the main nutritional pollutants are ammonia nitrogen and total nitrogen. In sewage treatment, microorganisms are generally used for denitrification treatment. The functional materials used in fillers are used as the carrier of microorganisms. Their materials and manufacturing processes have a direct impact on the efficiency, energy consumption, stability and reliability of the wastewater treatment process. The...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L33/18C08L33/20C08L33/22C08L33/02C08L33/14C08L33/06C08K3/34C08F220/42C08F220/44C08F220/50C08F220/06C08F220/04C08F220/14C08F220/18C08F220/38C08F8/12C02F3/34
Inventor 刘景明乔淑媛王红专徐岩刘慧徐春浩
Owner JIANGSU SUJING GROUP
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