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Intumescent flame retardant (IFR) material containing metal oxygenation substances and preparation method thereof

An intumescent flame retardant and oxygen compound technology, applied in the field of flame retardant polymers, can solve the problems of product performance deterioration, poor flame retardant effect, large addition amount, etc., achieve low production cost, good flame retardant effect, and improve flame retardant efficiency effect

Active Publication Date: 2012-08-22
卢忠远
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Halogen flame retardants have developed into mainstream products in the flame retardant market due to their low dosage, high flame retardant efficiency and wide adaptability. However, halogen flame retardants generate a lot of smoke and toxic and corrosive gases during combustion. Gas can cause corrosion of circuit system switches and other metal objects and environmental pollution that cannot be caused by fire alone. The European Union's "Restriction of Hazardous Substances Directive (RoHS) Directive clearly states that, Electrical products put on the EU market after July 1, 2006 must not contain harmful halogenated flame retardants such as polybrominated biphenyls
Therefore, the development of inorganic flame retardants to replace halogen flame retardants has become a trend in the field of flame retardants in the world. Inorganic flame retardants (Al(OH) 3 , Mg(OH) 2 etc.) Although the source is rich, halogen-free and non-toxic, its flame retardant effect is poor, and the addition amount is large, which will deteriorate the performance of the product. Therefore, the development of efficient, low-cost, halogen-free and non-toxic inorganic flame retardant has become the One of the hot spots of flame retardant research

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0014] Example 1 Intumescent flame retardant material containing metal oxygenate and its preparation method, each component is proportioned according to the following weight percentage:

[0015] Resin matrix 70℅,

[0016] Zinc Oxide 3℅,

[0017] Melamine Pyrophosphate 20℅,

[0018] Pentaerythritol 7℅;

[0019] Add 1.5% of resin weight curing agent to the above mixture, add 6% of resin weight anti-shrinkage agent, add 2% of mixture weight thickener, add 1% of mixture weight internal release agent, 30-50 ℃ Knead evenly, knead during kneading, then crush the kneaded premix, extrude and granulate through an extruder, and then injection mold through an injection molding machine. The combustion phenomenon detected by the experiment in this embodiment shows that there is no droplet, the carbon layer expands obviously, and there is no collapse; its oxygen index (LOI) / % is 29.0. According to the test results, only adding IFR(2 # ) The limiting oxygen index (LOI) of the base materi...

Embodiment 2

[0020] Example 2 Intumescent flame retardant material containing metal oxygenate and its preparation method, each component is proportioned according to the following weight percentages:

[0021] Resin matrix 70℅,

[0022] Aluminum Oxide 5℅,

[0023] Melamine Pyrophosphate 18℅,

[0024] Pentaerythritol 7℅;

[0025] The preparation method is to knead the above-mentioned components with good ratio in kneading, then break the kneaded premix, extrude and granulate through an extruder, and then shape it by hot pressing. The experimental detection of this embodiment shows that there is no molten droplet and the charcoal layer is dense; its oxygen index (LOI) / % is 29.4. According to the test results, only adding IFR(2 # ) The limiting oxygen index (LOI) of the substrate of the flame retardant system is 25.0%.

Embodiment 3

[0026] Example 3 Intumescent flame retardant material containing metal oxygenate and its preparation method, each component is proportioned according to the following weight percentage:

[0027] Resin matrix 70℅,

[0028] Zeolite 5℅,

[0029] Melamine Pyrophosphate 18℅,

[0030] Pentaerythritol 7℅;

[0031] The preparation method is to knead the above-mentioned well-proportioned components in kneading, then crush the kneaded premix, extrude and granulate through an extruder, and then injection molding or hot-press molding by an injection molding machine. The experimental detection of this embodiment shows that there is no molten droplet, and the charcoal layer is dense and firm; its oxygen index (LOI) / % is 29.6. According to the test results, only adding IFR(2 # ) The limiting oxygen index (LOI) of the substrate of the flame retardant system is 25.0%.

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Abstract

The invention provides a flame retardant polymer, in particular to an intumescent flame retardant (IFR) material containing metal oxygenation substances and a preparation method thereof, which is characterized in that the intumescent flame retardant (IFR) material comprises the following components by weight percent: 60-70% of resin matrix, 1-5% of metal oxide, 15-30% of melamine pyrophosphate and 6-10% of pentaerythritol. The preparation method is as follows: milling the well-proportioned components in kneading; crushing the well-kneaded premix; extruding by an extruder and pelletizing; and performing injection molding by an injection molding machine or hot-press forming. The invention improves the flame retardant efficiency for materials, has good flame retardant effect, meets the requirement on environment protection, and has low production cost, no byproduct generation and simple production process.

Description

technical field [0001] The invention relates to a flame-retardant polymer, especially an expanded flame-retardant polymer containing metal oxygenate and a preparation method thereof. Background technique [0002] At present, polymer materials have been widely used in vehicles, chemical equipment, household appliances, etc. However, most of these polymer products are flammable (LOI is 17-20%), and the fires caused by polymer fires every year It has brought huge losses to people's lives and properties. There are about 5,000 people in Europe every year, and more than 4,000 people in the United States die in fires every year. The total loss reaches 1% of the total output value of the national economy. Fires are also emerging in an endless stream in our country. In 2007 alone, there were 159,000 fires in our country, more than 1,400 people were killed, more than 800 people were injured, and the direct property loss was 990 million yuan. Nowadays, countries all over the world pay...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/06C08L67/06C08K3/22C08K5/52C08K5/053C08K3/34
Inventor 卢忠远杨凯宋丽贤
Owner 卢忠远
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