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Dendrimer and sodium polyepoxysuccinate composite scale inhibitor for inhibiting silica scale deposition in water

A technology of sodium polyepoxysuccinate and composite antiscalant, which is applied in the fields of descaling and water softening, chemical instruments and methods, water/sludge/sewage treatment, etc., and can solve the poor effect of silicon dioxide scale and silicon inhibition and other problems, to achieve the effect of reducing the total concentration of chemicals used, good effect, and high-efficiency silica scale deposition

Active Publication Date: 2012-12-05
TONGJI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0013] One of the purposes of the present invention is to provide a kind of dendritic polymer and sodium polyepoxysuccinate composite antiscalant that suppresses silica scale deposition in water, to overcome existing organic phosphine antiscalant and anionic polymer antiscaling dispersant The problem of poor silicon resistance to silica scale

Method used

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  • Dendrimer and sodium polyepoxysuccinate composite scale inhibitor for inhibiting silica scale deposition in water
  • Dendrimer and sodium polyepoxysuccinate composite scale inhibitor for inhibiting silica scale deposition in water
  • Dendrimer and sodium polyepoxysuccinate composite scale inhibitor for inhibiting silica scale deposition in water

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Effect test

Embodiment 1

[0043] Embodiment 1: This embodiment is the preparation of the composite antiscalant of PAMAM-0G and PESA

[0044] Preparation process: 150 g of PAMAM-0G methanol solution with an effective content of 20% was evaporated to remove methanol with a vacuum rotary evaporator at a temperature of less than 50° C. to obtain about 30 g of viscous PAMAM-0G. Then add 25g of polyepoxysuccinate sodium (PESA) with a solid content of 40% and 45g of deionized water, and stir evenly to obtain 100.00 g of a composite silicon and scale inhibitor with a solid content of 40%. In the prepared composite silicon scale inhibitor, the effective concentration of PAMAM-0G is 30%, and the effective concentration of sodium polyepoxysuccinate is 10%.

[0045] The compound antiscalant prepared above was subjected to the performance test of static silica scale inhibition. After the experiment, the solution was clear and transparent without white flocculent deposits. The soluble silica content is shown in Tabl...

Embodiment 2

[0046] Embodiment 2: This embodiment is the composite antiscalant preparation of PAMAM-0G and PESA

[0047]Preparation process: 137.5 g of PAMAM-0G methanol solution with an effective content of 20% was evaporated to remove methanol with a vacuum rotary evaporator at a temperature of less than 50° C. to obtain about 27.5 g of viscous PAMAM-0G. Then add 31.25g of polyepoxysuccinate sodium (PESA) with a solid content of 40% and 41.25 g of deionized water, and stir evenly to obtain 100.00 g of a composite silicon and scale inhibitor with a solid content of 40%. In the prepared composite silicon scale inhibitor, the effective concentration of PAMAM-0G is 27.5%, and the effective concentration of sodium polyepoxysuccinate is 12.5%.

[0048] The compound antiscalant prepared above was subjected to the performance test of static silica scale inhibition. After the experiment, the solution was clear and transparent without white flocculent deposits. The soluble silica content is shown ...

Embodiment 3

[0049] Embodiment 3: This embodiment is the composite scale inhibitor preparation of PAMAM-0G and PESA

[0050] Preparation process: 125g of PAMAM-0G methanol solution with an effective content of 20% was evaporated to remove methanol at a temperature of less than 50°C with a vacuum rotary evaporator to obtain about 25g of viscous PAMAM-0G. Then add 37.5 g of polyepoxysodium sodium epoxysuccinate (PESA) with a solid content of 40% and 37.5 g of deionized water, and stir evenly to obtain 100.00 g of the required composite silicon and scale inhibitor with a solid content of 40%. In the prepared composite silicon scale inhibitor, the effective concentration of PAMAM-0G is 25%, and the effective concentration of sodium polyepoxysuccinate is 15%.

[0051] The compound antiscalant prepared above was subjected to the performance test of static silica scale inhibition. After the experiment, the solution was clear and transparent without white flocculent deposits. The soluble silica co...

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Abstract

The invention belongs to the technical field of industrial water treatment, in particular to a dendrimer and sodium polyepoxysuccinate composite scale inhibitor for inhibiting silica scale deposition in water. The composite scale inhibitor is compounded by dendrimer and sodium polyepoxysuccinate, wherein the dendrimer used by the composite scale inhibitor is 0 to 2 generations of product of polyamide-amine polymer and has obvious performance of preventing silica scale deposition in water; and the sodium polyepoxysuccinate used by the composite scale inhibitor can obviously improve the silica scale preventing performance of polyamide-amine and can effectively disperse the white floccus of the polyamide-amine generated in the process of preventing the silica scale. The composite scale inhibitor can effectively prevent the silica scale deposition, is easy to compound, does not contain phosphorus, is biodegradable, can reduce water eutrophication pollution and contributes to environmentalprotection.

Description

technical field [0001] The invention belongs to the technical field of industrial water treatment, and in particular relates to a composite scale inhibitor of a dendritic polymer and sodium polyepoxysuccinate for inhibiting the deposition of silica scale in water. Background technique [0002] In the field of industrial water treatment, raw water usually contains a large amount of alkaline earth metal cations such as Ca 2+ , Mg 2+ 、Ba 2+ etc. and anionic groups such as CO 3 3- , SO 4 2- and PO 4 3- etc., and soluble silica. Under certain conditions (such as evaporation, concentration, etc.), these cations and anions are easily combined to form CaCO 3 , CaSO 4 , BaSO 4 , Ca 3 (PO 4 ) and other inorganic salt scales, silica will aggregate to form insoluble colloidal silica scales, which are deposited on the surface of water treatment pipes and equipment to cause harm. However, silica scale is different from inorganic salt scale. Once formed, silica scale is diffi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G69/00C08L79/00C02F5/10
Inventor 张冰如李风亭
Owner TONGJI UNIV