Method for extracting vanadium from molten iron
A technology for molten iron and vanadium oxidation, which is applied in the field of vanadium extraction and can solve the problems of low vanadium recovery rate and low vanadium
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[0033] Example 1
[0034] This example is used to illustrate the method for extracting vanadium from molten iron provided by the present invention.
[0035] Blast furnace molten iron composition: C 4.49 wt%, Si 0.31 wt%, Mn 0.23 wt%, P 0.071 wt%, S 0.059 wt%, V 0.313 wt%, Ti 0.25 wt%, and the balance is iron.
[0036] Inject 141 tons of the above-mentioned blast furnace molten iron into a molten iron tank, inject a desulfurizer into the molten iron in a spray desulfurization device, and add 1134 kg of desulfurizer to desulfurize for 19 minutes (the content of CaO in the desulfurizer is 85 wt%, Na 2 CO 3 The content is 2.5% by weight, CaC 2 The content is 12.5% by weight). Sampling composition of molten iron after desulfurization and slagging: C 4.40% by weight, Si 0.20% by weight, S 0.006% by weight, and V 0.308% by weight. The ratio of Si / V in molten iron decreased from 0.99 before desulfurization to 0.65 after desulfurization. The molten iron after desulfurization was injected i...
Example Embodiment
[0041] Example 2
[0042] This example is used to illustrate the method for extracting vanadium from molten iron provided by the present invention.
[0043] Blast furnace molten iron composition: C 4.86% by weight, Si 0.20% by weight, Mn 0.17% by weight, P 0.068% by weight, S 0.120% by weight, V 0.295% by weight, Ti 0.22% by weight, the balance being iron.
[0044] Inject 145 tons of the above blast furnace molten iron into a molten iron tank, spray a desulfurizer into the molten iron in a spray desulfurization device, and add 1700 kg of desulfurizer to desulfurize for 28 minutes (the content of CaO in the desulfurizer is 78.5% by weight, Na 2 CO3 content is 6% by weight, CaC 2 The content is 15.5% by weight). Sampling composition of molten iron after desulfurization and slagging: C 4.86%, Si 0.16%, S 0.012%, V 0.283%, the ratio of Si / V of molten iron decreased from 0.68 before desulfurization to 0.57. The molten iron after desulfurization was mixed into a 120-ton vanadium extractio...
Example Embodiment
[0046] Example 3
[0047] This example is used to illustrate the method for extracting vanadium from molten iron provided by the present invention.
[0048] Blast furnace molten iron composition: C 4.62% by weight, Si 0.24% by weight, Mn 0.15% by weight, P 0.075% by weight, S 0.082% by weight, V 0.291% by weight, Ti 0.09% by weight, and the balance is iron.
[0049] Inject 137 tons of the above blast furnace molten iron into a molten iron tank, spray a desulfurizer into the molten iron in a blow desulfurization device, and add 1274 kg of desulfurizer to desulfurize for 23 minutes (the content of CaO in the desulfurizer is 73.2% by weight, Na 2 CO 3 The content is 4.3% by weight, CaC 2 The content is 22.5% by weight). Sampling composition of molten iron after desulfurization and slag removal: C 4.61%, Si 0.18%, S 0.011%, V 0.278%, and the Si / V ratio of molten iron decreased from 0.82 before desulfurization to 0.65. The molten iron after desulfurization was converted into a 120-ton va...
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