Polymeric composition for cellulosic materials binding and modification
A composition and polymer technology, applied in the direction of polymer impregnation, thin material treatment, wood treatment, etc.
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Embodiment 1
[0030] 5.0 kg of butane tetracarboxylic acid, 20.0 kg of citric acid and 15.6 kg of maltodextrin were mixed with 80.0 kg of water until the solution became clear and a mixed composition was formed. Some poplar solid wood planks were placed in an autoclave, which was then evacuated to about 80% vacuum. The mixed composition was then transferred to an autoclave. When the autoclave was filled with the mixed composition liquid, the system was pressurized and maintained for about 3 hours. The impregnated wood boards were dried in an oven heated to 100°C for about 24 hours to allow the mixed composition to react to form a cross-linked polymer. The resulting treated wood had a specific gravity of about 0.6 g / ml compared to a corresponding untreated wood of about 0.32 g / ml. The treated wood exhibits enhanced mechanical properties.
Embodiment 2
[0032] 5kg of butane tetracarboxylic acid, 20kg of citric acid, 1kg of itaconic acid, 18kg of maltodextrin and 5kg of 20% by weight of polyvinyl alcohol 5000 in water, and 0.5kg of zinc acetate, 0.4kg of Boric acid and 80 kg of water were mixed to form a mixed composition. Some solid radiata pine planks were placed in an autoclave, which was then evacuated to a vacuum of about 80%. The mixed composition was then transferred to an autoclave. When the autoclave was filled with the mixed composition liquid, the system was pressurized and maintained for 3 hours. The impregnated wood boards were dried in an oven and heated to about 100°C for about 24 hours. The resulting treated wood had a specific gravity of about 0.7 g / ml compared to a corresponding untreated wood of about 0.45 g / ml. The Janka hardness of the treated wood reaches about 1600 pound-force.
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