Low-fogging polyurethane composition and preparation method thereof

A technology of polyurethane and composition is applied in the field of preparation of low-atomization polyurethane composition, which can solve the problems of genotoxicity and irritation, and achieve the effects of low VOC value, high environmental protection, and ensuring comfort.

Active Publication Date: 2011-08-03
SHANDONG INOV POLYURETHANE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

TVOCs can be smelly, irritating, and some compounds are genotoxic

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] A component material:

[0040] 330N(Y): 60

[0041] POP40: 35

[0042] DEOA: 1.0

[0043] h 2 O: 2.0

[0044] DC2525: 1.0

[0045] DV-625: 1.0

[0046] B component material:

[0047] 330N(Y): 20

[0048] Pure MDI: 20

[0049] MDI-50: 10

[0050] Liquefied MDI: 5.0

[0051] Polymerized MDI: 45

[0052] Phosphoric acid: 10ppm

[0053] Preparation of component A materials: Put the measured 330N (Y), POP40, DEOA, H2O, DC2525, DV-625 into the reaction kettle, stir at room temperature for 3-4 hours, and then fill the barrel.

[0054] Preparation of component B materials: Put 330N (Y) based on the formula into the reaction kettle at room temperature, raise it to 80-100°C, stir, vacuumize (≤-0.098MPa) for dehydration and degassing for 2-3 hours, and cool down to 10- Add pure MDI, MDI-50, and liquefied MDI at 40°C, react at 80-85°C for 2-3 hours, cool down to 10-40°C, add polymeric MDI and phosphoric acid, stir well, and pack into barrels.

[0055] When using, m...

Embodiment 2

[0057]A component material:

[0058] GEP-330N: 53

[0059] POP36 / 30: 40

[0060] TEA: 1.7

[0061] H2O: 3.0

[0062] L-3415: 1.5

[0063] DV-625: 0.8

[0064] B component material:

[0065] GEP-330N: 5.0

[0066] Pure MDI: 25

[0067] MDI-50: 40

[0068] Polymerized MDI: 30

[0069] Phosphoric acid: 10ppm

[0070] Preparation of component A materials: Put the measured GEP-330N, POP36 / 30, TEA, H2O, L-3415, DV-625 into the reaction kettle, stir at room temperature for 3-4 hours, and then fill the barrel.

[0071] Preparation of component B materials: Put the GEP-330N based on the formula into the reaction kettle at room temperature, raise it to 80-100°C, stir, vacuumize (≤-0.098MPa) for dehydration and degassing for 2-3 hours, and cool down to 10-40°C Add pure MDI and MDI-50 at ℃, react at 80-85℃ for 2-3 hours, cool down to 10-40℃, add polymeric MDI and phosphoric acid, stir well, and load into barrels.

[0072] When using, mix A and B component materials according t...

Embodiment 3

[0074] A component material:

[0075] FA-703: 65

[0076] POP40: 30

[0077] DEOA: 0.7

[0078] H2O: 2.5

[0079] DC2525: 0.5

[0080] DC6070: 0.3

[0081] DV-625: 1.0

[0082] B component material:

[0083] FA-703: 10

[0084] Pure MDI: 20

[0085] MDI-50: 20

[0086] Polymerized MDI: 50

[0087] Benzoyl chloride: 10ppm

[0088] Preparation of component A materials: Put the measured FA-703, POP40, DEOA, H2O, DC2525, DC6070, DV-625 into the reaction kettle, stir at room temperature for 3-4 hours, and then fill the barrel.

[0089] Preparation of component B materials: Put FA-703 based on the formula amount into the reaction kettle at room temperature, raise it to 80-100°C, stir, vacuumize and dehydrate and degas for 2-3 hours, cool down to 10-40°C and add pure MDI and MDI -50, react at 80-85°C for 2-3 hours, cool down to 10-40°C, add polymeric MDI and benzoyl chloride, stir well, and pack into barrels.

[0090] When using, mix A and B component materials according...

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PUM

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Abstract

The invention discloses a low-fogging polyurethane composition, which consists of a component A and a component B, wherein the component A consists of polyether polyol, polymer polyol, a cross-linking agent, a foaming agent, a foam stabilizer and a catalyst; and the component B consists of polyether polyol, isocyanate and a prepolymer made from a storage stabilizer. When the low-fogging polyurethane composition is used, the component A and the component B are mixed according to the isocyanate index of 1.05 for injection molding, and mold opening is performed within 4-6 minutes. A product produced from the polyurethane composition is widely applied to the industries of automobiles, furniture, toys and the like by virtue of the advantages of high environmental friendliness, low VOC (Volatile Organic Compound) value and comfortableness.

Description

technical field [0001] The invention provides a method for preparing a low-atomization polyurethane composition. The polyurethane composition is widely used in industries such as automobiles, furniture, and toys because of its excellent environmental protection, low VOC value, and comfort. Background technique [0002] Total volatile organic compounds (TVOC) refer to organic compounds whose saturated vapor pressure exceeds 133.32 Pa at room temperature, whose boiling point is below 250°C, and which can evaporate in the air at room temperature. It is toxic, irritating, and carcinogenic Sex and special odor, will affect the skin and mucous membranes, and cause acute damage to the human body. The World Health Organization (WHO), the National Academy of Sciences / National Research Council (NAS / NRC) and other institutions have always emphasized that TVOC is an important class of air pollutants. [0003] Government agencies around the world are now developing various independent p...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G18/76C08G18/66C08G18/48C08G18/32C08G18/16C08J9/08C08J9/14C08G101/00
Inventor 栾森孙清峰贾雪芹陈伟
Owner SHANDONG INOV POLYURETHANE
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