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Water treatment method for ultrasonically improving oxidation of pollutant with permanganate

A technology of permanganate and ultrasonic enhancement, applied in the field of water treatment, can solve the problems of poor dispersion of nascent nano-manganese dioxide, slow oxidation speed of permanganate, unstable treatment effect, etc. The effect is stable and easy to transform

Inactive Publication Date: 2012-07-04
HARBIN INST OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The purpose of the present invention is to solve the problems of slow permanganate oxidation speed, unstable treatment effect, easy penetration, and poor dispersion of newborn nano-manganese dioxide in the oxidation process of permanganate and permanganate compound agents used in existing urban water supply plants. , slow catalytic speed, and easy to clog the filter, and provide a water treatment method that utilizes ultrasound to strengthen permanganate oxidation of pollutants

Method used

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Experimental program
Comparison scheme
Effect test

specific Embodiment approach 1

[0011] Specific embodiment 1: This embodiment uses ultrasound to enhance the water treatment method of permanganate oxidation pollutants according to the following steps: 1. The water to be treated enters the pretreatment unit, and the permanganate and The inducer reacts; 2. The effluent of the pretreatment unit flows into the mixing tank, and the coagulant is added, mixed and stirred, and then flows into the flocculation tank for flocculation, and then flows into the sedimentation tank; 3. The effluent of the sedimentation tank is filtered and enters the clean tank for disinfection After that, the water treatment using ultrasound to enhance the permanganate oxidation of pollutants is completed; among them, the pretreatment unit in step 1 uses pipelines or separate pools as reactors. When the pipeline is used as the reactor, the flow rate is 1 to 1.5m / s. When a separate tank is used as the reactor, the tank is connected to the mixing tank; the dosage of permanganate in step 1 is...

specific Embodiment approach 2

[0013] Specific embodiment two: this embodiment is different from specific embodiment one in that the dosage of permanganate in step one is 0.1mg / L, the ratio of inducer to permanganate is 1:10, and the ultrasonic power density is 1W / cm 2 , Ultrasonic action time is 5min. Other steps and parameters are the same as in the first embodiment.

specific Embodiment approach 3

[0014] Specific embodiment three: this embodiment is different from specific embodiment one in that the dosage of permanganate in step one is 10mg / L, the ratio of inducer to permanganate is 1:1, and the ultrasonic power density is 200W / cm 2 , The ultrasound action time is 10s. Other steps and parameters are the same as in the first embodiment.

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PUM

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Abstract

The invention relates to a water treatment method, particularly a water treatment method for ultrasonically improving oxidation of pollutants with permanganates, and aims to solve the problems in the prior art the speed of oxidation with permanganates is slow, the treatment effect is not stable, the dispersion of produced manganese dioxide nanoparticles is poor and the catalytic rate is low. The method has three forms. The first form comprises the following steps of: pre-treating water; feeding the effluent into a mixing pond, a flocculation pond and a precipitation pond in sequence; filtering the effluent; feeding to a clear water pond and sterilizing. The second form comprises the following steps of: feeding the water into a mixing pond and then pre-treating the water, feeding the effluent to a flocculation pond and then a precipitation pond, filtering the effluent, feeding to a clear water pond and sterilizing. The third form comprises the following steps of: feeding the water intoa mixing pond; adding permanganates, inducers and coagulants under ultrasonic action; feeding the effluent to a flocculation pond and then a precipitation pond; filtering the effluent; feeding to a clear water pond and sterilizing. The method has stable operating effects, is favorable for the dispersion of manganese dioxide nanoparticles which are used as the reduction product of permanganates, improves the catalytic ability of manganese dioxide in oxidation of permanganates, and promotes the decomposition of permanganates to produce highly-active intermediate-state manganese.

Description

Technical field [0001] The invention relates to a water treatment method. Background technique [0002] Toxic and harmful pollutants (such as persistent pollutants, endocrine disruptors, medicines and personal care products, etc.) introduced in the process of human production and life pose a serious potential threat to the quality of urban drinking water. Conventional water treatment processes cannot meet the new "Sanitary Standards for Drinking Water", and new technologies are urgently needed to ensure water quality and safety. Existing urban water supply plants generally use permanganate and permanganate composite chemical oxidation process, which has been widely used in water plants in my country, which can remove odor, color, turbidity, algae toxins, and disinfection by-products in water The precursor can control the growth of algae and stabilize the effluent quality. At the same time, the process also has the problems of slow permanganate oxidation speed, unstable treatment...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F9/08
Inventor 马军杨晶晶赵吉江进
Owner HARBIN INST OF TECH
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