Method for using metal-organic framework material to purify water, exchange ions with water or magnetize water
An organic framework and ion exchange technology, applied in ion exchange water/sewage treatment, magnetic field/electric field water/sewage treatment, adsorbed water/sewage treatment, etc.
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Embodiment 1
[0054] Embodiment 1 (preparation of bio-MOF-1)
[0055]
[0056]
[0057] The above-mentioned raw materials, 13.5ml of N,N-dimethylformamide (DMF) as a solvent, and 1ml of water were sequentially put into a 20ml autoclave lined with polytetrafluoroethylene. Heat at 130°C for 24 hours. And gradually cooled to room temperature to obtain rod-shaped colorless crystals. The crystals were rinsed three times with DMF (3 ml). Then dry under argon atmosphere for 30 minutes.
[0058] The resulting products were then characterized by X-ray powder diffraction measurements. The resulting product exhibits the figure 1 The X-ray powder diffraction pattern shown is consistent with that of bio-MOF-1.
Embodiment 2
[0059] Embodiment 2 (ion exchange of bio-MOF-1)
[0060] Weigh 0.35g of bio-MOF-1 obtained in Example 1 and add it to 20ml of 0.1mol / L lithium nitrate in EtOH / H2O (15ml / 5ml) solution, soak at room temperature for 48h, and change the fresh solution every 24 hours , and then rinsed with ethanol several times to wash away the lithium nitrate on the surface, and dried naturally to obtain the Li ion-exchanged bio-MOF-1.
[0061] The purification method involved in the present invention uses metal-organic framework materials to absorb smell, taste, chroma, chlorinated organic substances, pesticides, radioactive organic substances and other artificially synthesized organic substances in water to purify water bodies; and by means of ion exchange, The hardness of water is reduced, which can meet the special use and treatment effect requirements of tap water purification process for water purification materials.
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