Chlorin iron (iii) chelate with plant growth regulating activity and its application as plant growth regulator
A plant growth regulator, plant growth regulation technology, applied in plant growth regulators, plant growth regulators, applications, etc., can solve problems such as poor solubility, chlorophyllase inhibitors that have not been reported, and products that are easy to decompose and fail
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Embodiment 1
[0062]Embodiment 1: the preparation of chloride pyropheophorbide-a iron (compound I-1), with the hydrochloride of 2.0 grams of pyropheophorbide-a and 7.4 grams of iron as raw material, according to literature (Journal of ChromatographyA, 721 (1996) 350-354; Chinese Pharmaceutical Journal, 2002, 37 (1) 64-65) method makes 1.27 gram compound I-1, purity 98.0% (HPLC), Fe%: 9.13% (theory Value: 8.95%), decomposed by heating at 188-201°C, UV: λ max 402nm (ε4.5×10 4 ); MS m / z: 588 ([M-CI] + ); IR(CsI)cm -1 : 373 (Fe-Cl).
Embodiment 2
[0063] Example 2: Basically the same as Example 1, but using 0.2 gram of pyropheophorbide-a methyl ester as raw material (while adjusting the ratio of other raw materials), 0.10 gram of compound I-2 was obtained with a purity of 96.0% (HPLC) , decomposed by heating at 191-203°C, UV: λ max 403nm (ε4.5×10 4 ); MS m / z: 602 ([M-CI] + ); IR(CsI)cm -1 : 372 (Fe-Cl).
Embodiment 3
[0064] Example 3: Basically the same as Example 1, but using 0.2 gram of pyropheophorbide-a ethyl ester as raw material (while adjusting the ratio of other raw materials), 0.08 gram of compound I-3 was obtained, with a purity of 96.0% (HPLC) , decomposed by heating at 198-209°C, UV: λ max 403nm (ε4.4×10 4 ); MS m / z: 616 ([M-CI] + ); IR(CsI)cm -1 : 373 (Fe-Cl).
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