Preparation technology of polyether polyol for polyurethane rigid foam with polyr alcohol as initiator
A technology of polyether polyol and rigid foam, which is applied in the field of chemical synthesis of polyether polyol and the preparation of polyether polyol, to achieve the effect of convenient operation, less impurities and reasonable method
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[0016] The preparation process adopts a batch process (reaction process and refining process), which is divided into two steps, that is, the reaction process and the refining process.
[0017] 1. Reaction process: Put a specified amount of starter poly-R alcohol and catalyst potassium hydroxide into the stainless steel high-pressure reactor, stir, pass low-pressure saturated steam into the jacket, and heat the material in the reactor to 100°C. Vacuum dehydration for 0.5h, the vacuum degree reaches 750mmHg, start to add polypropylene oxide under vacuum, control the temperature at 110±5°C and add polypropylene oxide dropwise, the feeding speed is 3-4g / min, and the reaction is cooled with jacket water The heat is removed to keep the temperature at 110±5°C and the pressure ≤0.44mPa. After feeding the polypropylene oxide, carry out the internal pressure reaction with a reaction pressure of ≤0.4mPa for 3 hours, then remove the monomers in a vacuum for 0.5 hours, and control the temp...
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