Liquid-crystal display element and substrate used in same
A technology of liquid crystal display elements and substrates, which can be used in liquid crystal materials, applications, household appliances, etc., and can solve problems such as increased driving voltage and critical voltage
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[0498] The following examples illustrate the present invention in more detail, but the present invention is not limited thereto.
[0499] In this specification, I represents a non-liquid crystal isotropic phase, N represents a nematic phase, N* represents a chiral nematic phase, BP represents a blue phase, and BPX represents an optically isotropic liquid crystal phase that does not observe more than two colors of diffracted light, and Sometimes the I-N phase transition point is called N-I point, the I-N* phase transition point is called N*-I point, and the I-BP phase transition point is called BP-I point.
[0500] In the examples and the like in this specification, the measurement and calculation of physical property values and the like are carried out by the methods described later, and most of them are the methods described in the Japan Electronic Machinery Manufacturers Association standard EIAJ-ED-2521A or methods obtained by modifying the methods.
[0501] Determination...
example 11
[0547] After the glass substrate is cleaned, the surface is modified by ozone treatment. The glass substrate and organosilane coupling agent SE (n-octadecyltrimethoxysilane, Gelest Inc.) were sealed in a TeflonTM airtight container under atmospheric pressure, and then the airtight container was placed in a heating electric furnace It was left to stand for a certain period of time (about 3 hours) to manufacture an organosilane film-coated substrate SE1. Organosilane film-coated substrate SE2 was also produced using organosilane coupling agent SE for a glass substrate (Alone Co., Ltd., chromium-attached electrode substrate) on which comb-shaped electrodes were arranged on one surface.
[0548] Substrates SA1 and SA2 (Example 7) and substrates SB1 and SB2 (Example 8) were produced under the same conditions as substrates SE1 and SE2 (Example 11), except that organosilane coupling agents SA to SD or SF were used instead of organosilane coupling agent SE. , substrates SC1 and S...
example 16
[0610] The rubbed liquid crystal cell of Example 16 easily exhibited a monochromatic blue phase.
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