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Electrode material of drainage rechargeable and dischargeable lithium ion and aqueous solution rechargeable and dischargeable lithium ion battery

A lithium-ion battery and aqueous solution technology, which is applied in battery electrodes, secondary batteries, circuits, etc., can solve problems such as potential safety hazards, high production costs of organic electrolyte batteries, and restrictions on the application of large-scale batteries, achieving high safety and wide practicality Value and market prospects, the effect of low production costs

Active Publication Date: 2014-08-06
ZHENGZHOU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, despite the excellent performance of organic lithium-ion batteries, the toxicity and flammability of organic electrolytes lead to serious safety hazards in improper operations such as overcharging or short-circuiting of lithium-ion batteries.
In addition, the ionic conductivity of non-aqueous electrolytes is two orders of magnitude lower than that of corresponding aqueous electrolytes, and the fabrication cost of organic electrolyte batteries is correspondingly much higher.
Considering the cost, safety and cycle life, these disadvantages limit the application of large batteries

Method used

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  • Electrode material of drainage rechargeable and dischargeable lithium ion and aqueous solution rechargeable and dischargeable lithium ion battery
  • Electrode material of drainage rechargeable and dischargeable lithium ion and aqueous solution rechargeable and dischargeable lithium ion battery
  • Electrode material of drainage rechargeable and dischargeable lithium ion and aqueous solution rechargeable and dischargeable lithium ion battery

Examples

Experimental program
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Effect test

Embodiment 1

[0032] The prepared carbon-coated Li 2 FeSiO 4 Material as the negative electrode active material, LiNi 1 / 3 co 1 / 3 mn 1 / 3 o 2 as a positive electrode active material. They are respectively mixed with acetylene black, polytetrafluoroethylene, and sodium carboxymethyl cellulose in a mass ratio of 85:10:4:5, and ethanol is used as a dispersant. After 12 hours, the corresponding negative and positive pole pieces can be obtained. The negative electrode and positive electrode sheet prepared by the above process were separated by polypropylene triacetate cellulose separator (the capacity of the cut positive electrode sheet was much larger than that of the negative electrode), and 1M Li 2 SO 4 As the electrolyte, the stainless steel shell is used as the shell, and assembled into a CR2016 button battery. The aqueous lithium ion assembled by the above process was subjected to a constant current charge and discharge test with a current of 10 mA / g in the potential range of 0.5-1.6...

Embodiment 2

[0034] The prepared carbon-coated Li 2 FeSiO 4 Material as the negative electrode active material, LiNi 1 / 3 co 1 / 3 mn 1 / 3 o 2 as a positive electrode active material. They are respectively mixed with acetylene black, polytetrafluoroethylene, and sodium carboxymethyl cellulose in a mass ratio of 85:10:4:5, and ethanol is used as a dispersant. After 12 hours, the corresponding negative and positive pole pieces can be obtained. The negative electrode and positive electrode sheet prepared by the above process are separated by polypropylene triacetylcellulose separator (wherein, the capacity of the cut positive electrode sheet is much larger than that of the negative electrode), and 2M LiNO 3 As the electrolyte, the stainless steel shell is used as the shell, and assembled into a CR2016 button battery. The aqueous lithium ion assembled by the above process was subjected to a constant current charge and discharge test with a current of 10 mA / g in the potential range of 0.5-1....

Embodiment 3

[0036] The prepared carbon-coated Li 2 FeSiO 4 Material as the negative electrode active material, LiNi 1 / 3 co 1 / 3 mn 1 / 3 o 2 as a positive electrode active material. They are respectively mixed with acetylene black, polytetrafluoroethylene, and sodium carboxymethyl cellulose in a mass ratio of 85:10:4:5, and ethanol is used as a dispersant. After 12 hours, the corresponding negative and positive pole pieces can be obtained. The negative electrode and positive electrode piece prepared by the above process are separated by polypropylene triacetate cellulose diaphragm (the capacity of the cut positive electrode piece is much larger than that of the negative electrode), 2M NaCl is used as the electrolyte, and the stainless steel shell is used as the outer shell. Assembled into a CR2016 button battery. The lithium ion aqueous solution assembled by the above process was subjected to a constant current charge and discharge test with a current of 10 mA / g in the potential range...

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Abstract

The invention belongs to the field of chemical power sources, and relates to an electrode material capable of charging and discharging lithium ions in a water system and a lithium ion battery capable of charging and discharging an aqueous solution. The battery uses Li2FeSiO4 and its doped and coated modified products as the negative electrode material, the positive electrode is lithium intercalation active materials (LiNi1 / 3Co1 / 3Mn1 / 3O2, LiMn2O4, LiFePO4, LiCoO2, etc.), and the electrolyte is an aqueous solution of soluble lithium salts. The invented Li2FeSiO4 has the advantages of good cycle performance, high specific energy, low price, safety and environmental friendliness as the negative electrode material of the aqueous solution lithium ion battery. The invented aqueous solution lithium ion battery containing the negative electrode material is more green and environment-friendly, has simple preparation, low production cost, higher safety and better cycle stability. This new type of aqueous lithium-ion battery system will have broad practical value and market prospects.

Description

technical field [0001] The invention belongs to the field of chemical power sources, and in particular relates to a negative electrode material of a novel aqueous solution lithium ion battery and an aqueous solution lithium ion battery containing the negative electrode material. Background technique [0002] At present, lithium-ion batteries have become a research hotspot for power systems used in green vehicles such as electric vehicles due to their high specific energy and long cycle life. However, despite the excellent performance of organic lithium-ion batteries, the toxicity and flammability of organic electrolytes lead to serious safety hazards in improper operations such as overcharging or short-circuiting of lithium-ion batteries. In addition, the ionic conductivity of non-aqueous electrolytes is two orders of magnitude lower than that of corresponding aqueous electrolytes, and the fabrication cost of organic electrolyte batteries is correspondingly much higher. Con...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M4/58H01M10/36
CPCY02E60/10
Inventor 陈卫华张建民兰梦米立伟李绍王翠莲薛尚儒
Owner ZHENGZHOU UNIV