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Cu-Fe-Ni-Cr austenite alloy for oil bushing

An oil casing and alloy technology, applied in the field of iron-nickel-chromium alloys, can solve the problems of high oilfield exploitation cost, high alloy cost, inability to satisfy corrosion resistance, etc. The effect of improving the corrosion resistance of elemental sulfur

Inactive Publication Date: 2012-08-29
BAOSHAN IRON & STEEL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

These alloys can be used in high temperature, high pressure, high CO 2 、H 2 Production of S partial pressure and high salinity oil and gas wells, but the Ni content in it is more than 30%, the alloy cost is high, resulting in high oil field production costs
[0004] US4840768 discloses an iron-nickel-chromium alloy that can be used as oil well pipe fittings, which has good corrosion resistance, but cannot meet the requirements of corrosion resistance in the presence of elemental sulfur

Method used

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  • Cu-Fe-Ni-Cr austenite alloy for oil bushing
  • Cu-Fe-Ni-Cr austenite alloy for oil bushing
  • Cu-Fe-Ni-Cr austenite alloy for oil bushing

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Embodiment Construction

[0031] The features and effects of the present invention are described below through specific examples.

[0032] Table 2 shows the chemical composition of the steel grades of the embodiments of the present invention, wherein 1-7 is the steel grades of the present invention, and the alloys of comparative examples 8 and 9 are equivalent to commercial UNS N08904 oil casing (ASTM B677-05) alloys, and their alloy content It is basically the same as the alloy of the present invention, so the cost of the alloy is also basically the same. The alloys of comparative examples 10 and 11 are equivalent to the commercial UNS N08135 oil casing (ASTM B622-06) alloy, and the Ni and Mo contents in the alloy are higher than the alloy of the present invention, especially The Ni content is as high as about 10%.

[0033] Table 2 The chemical composition of the embodiment alloy of the present invention and comparative example alloy, wt%

[0034]

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Abstract

The invention relates to an austenite alloy which comprises the following chemical constituents by weight percent: 0 to 0.03% of C, 0 to 0.015% of P, 0 to 0.01% of S, 0 to 0.5% of Si, 0.5 to 2.0% of Mn, 25 to 27% of Ni, 24 to 26% of Cr, 3 to 4% of Mo, 3 to 5% of Cu, 0.1 to 0.3% of Al, 0.001 to 0.2% of V, and Fe in balancing amount. A manufacturing method of an oil bushing comprises the steps as follows: smelting is conducted in an electric arc furnace and an argon-oxygen decarburization furnace; a steel ingot is formed by casting and then is subjected to electroslag remelting and forging to obtain a hot extrusion ingot blank; the preheating temperature of the hot extrusion ingot blank ranges from 850 to 1100 DEG C; the ingot blank heat preservation time is 1 to 5 minutes per one-centimetre-thick piece of the ingot blank; and extruded tube blank is immersed in water to be cooled to below 50 DEG C and is cooled to below 100 DEG C with one minute; solution treatment is conducted at 1000 to 1120 DEG C, the heat preservation time is 1 to 5 minutes per one-millimeter-thick piece of the tube blank; then the tube blank is immersed in water and is cooled to below 100 DEG C within one minute; and finally cold rolling deformation is conducted, the cross section reduction deformation is controlled within 25 to 45 percent according to the grade requirements of steel. The alloy has excellent pitting corrosion resistance and stress corrosion resistance.

Description

technical field [0001] The present invention relates to an iron-nickel-chromium alloy, in particular to a copper-containing iron-nickel-chromium alloy with high strength and corrosion resistance, which is especially suitable for manufacturing stress corrosion cracking-resistant oil casings for acid wells containing elemental sulfur . Background technique [0002] With the continuous increase of energy demand and the continuous reduction of exploitable oil and gas resources, the exploitation of oil and gas resources has to turn to deep wells, ultra-deep wells and highly corrosive wells. This type of oil and gas well is characterized by high temperature, high pressure, and high CO 2 、H 2 S partial pressure, containing elemental sulfur and high salinity. In order to meet the production and development needs of such oil and gas wells, more and more ultra-high alloy oil casing products have been developed, especially iron-nickel-based alloy and nickel-based alloy oil casing. ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C38/58C22C38/46
Inventor 张春霞张忠铧
Owner BAOSHAN IRON & STEEL CO LTD