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Reflow sn plated member

一种构件、基材的技术,应用在回焊镀Sn构件领域,能够解决焊料湿润性、接触电阻劣化、接触电阻劣化等问题,达到降低插拔力、抑制晶须产生的效果

Active Publication Date: 2012-09-12
JX NIPPON MINING & METALS CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In particular, there are reports that with the overseas transfer of the manufacturing plant of the connector manufacturer, the components after plating are stored in high-temperature and high-humidity areas overseas for a long time, or are heated inside the mounting furnace during soldering, resulting in deterioration of solder wettability and contact resistance. Case
Furthermore, since the Sn-plated material is exposed to high temperatures such as the engine compartment of an automobile, copper may diffuse from the copper base to the Sn-plated layer, or the Sn-plated layer may be oxidized, resulting in deterioration of contact resistance.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0051] On one side of the base material (Cu-1.6%Ni-0.4%Si alloy with a plate thickness of 0.3 mm), Cu plating with a thickness of 0.5 μm and Sn plating with a thickness of 1.0 μm were respectively performed by electroplating under the conditions shown in Table 1. Reflow processing to obtain reflow Sn-plated components.

[0052] As the Cu plating bath, a copper sulfate bath with a sulfuric acid concentration of 60 g / L, a copper sulfate concentration of 200 g / L, and a bath temperature of 50° C. was used, and silica gel ("Snowtex O" manufactured by Nissan Chemical Industries, Ltd.) was added at the ratio shown in Table 1. , specific gravity: 1.12, and silica content rate 20wt%, silica particle size: 10-20 nm) and / or chloride ion (potassium chloride). Set the current density of Cu plating to 5 A / dm 2 , while agitating the plating bath with a stirring blade whose rotation speed was 200 rpm, plating was performed.

[0053] The Sn plating bath used a bath of 80 g / L of methanesulfon...

Embodiment 2

[0074] After performing Ni plating with a thickness of 0.3 μm by electroplating on one surface of the base material, Cu plating with a thickness of 0.5 μm and Sn plating with a thickness of 1.0 μm were respectively performed in the same manner as in Example 1. Thereafter, reflow treatment was performed under the conditions shown in Table 2 to obtain reflow Sn-plated members.

[0075] As the Ni plating bath, nickel sulfate: 250 g / L, nickel chloride: 45 g / L, boric acid: 30 g / L, and a bath temperature of 50° C. were used. Set the current density of Ni plating to 5 A / dm 2 , while agitating the plating bath with a stirring blade at a rotation speed of 200 rpm, plating was performed.

Embodiment 3

[0077] Ni plating, Cu plating, and Sn plating were performed in the same manner as in Example 1 and Example 2, respectively, except that the thicknesses of Ni plating, Cu plating, and Sn plating were changed as shown in Table 3. Thereafter, a reflow treatment was performed under the condition of 550° C. × 15 sec to obtain a reflow Sn-plated member. As a Cu plating bath, a sulfuric acid concentration of 60 g / L, a copper sulfate concentration of 200 g / L, and a copper sulfate bath of 50° C. were used, and further, 15 mL / L of silica gel (manufactured by Nissan Chemical Industry Co., Ltd. “Snowtex O”) was added (expressed as specific gravity: 1.12g / m 3 And the silica content rate is 20wt% of the volume of silica gel, silica particle size: 10-20 nm) and chloride ion (potassium chloride) 25mg / L. Set the current density of Cu plating to 5A / dm 2 , while agitating the plating bath with a stirring blade at a rotation speed of 200 rpm, plating was performed.

[0078] The obtained resul...

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Abstract

Disclosed is a reflow Sn plated member wherein the occurrence of whiskers is suppressed, and which has reduced insertion / removal force. A reflow Sn layer is formed on the surface of base material comprising Cu or a Cu-based alloy, and the orientation index of the (101) plane of the surface of said reflow Sn layer is at least 2.0 and no more than 5.0.

Description

technical field [0001] The present invention relates to a reflow-plated Sn member suitable for conductive spring materials such as connectors, terminals, relays, and switches, and having a reflow Sn layer formed on the surface of a base material made of Cu or a Cu-based alloy. Background technique [0002] Plated members plated with copper alloys are used in conductive parts such as connectors, terminals, and relays. Among them, Sn-plated materials obtained by plating copper alloys with Sn are often used in connectors for automobiles. The in-vehicle connector tends to be multi-polarized due to the increase in in-vehicle electrical components, and the insertion and withdrawal force increases when the connectors are mated. Usually, since the fitting of the connectors is performed manually, there is a problem that the operation load increases. [0003] On the other hand, the Sn plating material is also required not to generate whiskers and not to deteriorate solder wettability...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C25D7/00C25D5/50H01R13/03
CPCC25D5/10C25D5/12C25D3/38C25D7/00H01R13/035C25D5/505Y10T428/12715Y10T428/1291Y10T428/12722Y10S428/929H01R13/03C25D5/611
Inventor 前田直文
Owner JX NIPPON MINING & METALS CORP