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Photosensitive resin composition, printing plate precursor and flexographic printing plate

A technology of photosensitive resin and composition, applied in printing, printing plate, printing process and other directions, can solve the problems of not satisfying water developability, dryness and image reproducibility at the same time, time-consuming development process, low image reproducibility, etc. Achieving the effect of excellent image reproducibility, excellent image reproducibility, and excellent image reproducibility

Active Publication Date: 2012-11-21
SUMITOMO RIKO CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] However, the photosensitive resin composition of Patent Document 1 has a problem that the developing process takes a long time because there are many components with low water solubility and / or water permeability.
The long development time is not only a problem of workability, but also the surface of the original printing plate is rubbed by the brush for a long time in order to remove the unhardened part during development, so the image reproducibility is low due to the loss of fine dots, etc.
[0009] In addition, Patent Document 2 contains a surfactant in the photosensitive resin composition in order to shorten the developing time, although this is effective for shortening the developing time, however, since the main component of the photosensitive resin composition is water-soluble or water-swellable polymer matter, so the drying time after water development is too long, so the practicality is low
[0010] Furthermore, if the surfactant of the composition disclosed in Patent Document 2 is simply added to the water-dispersible latex, the photopolymerizable monomer, the rubber, and the photopolymerization initiator of the composition disclosed in Patent Document 1, fine grains on the negative film can be reproduced. Image reproducibility of screen dots may decrease
[0011] Therefore, conventional photosensitive resin compositions do not satisfy water developability, dryness, and image reproducibility at the same time.

Method used

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  • Photosensitive resin composition, printing plate precursor and flexographic printing plate
  • Photosensitive resin composition, printing plate precursor and flexographic printing plate
  • Photosensitive resin composition, printing plate precursor and flexographic printing plate

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0090]

[0091] Mix 45.5 parts by mass of water-dispersible latex (25 parts by mass of solid polymer), 15 parts by mass of acrylic modified liquid BR, and 5 parts by mass of acrylic monomers, heat at 120°C and evaporate water in a dryer After 2 hours, a mixture of a polymer obtained from a water-dispersible latex and a photopolymerizable monomer was obtained. This mixture was kneaded with 30 parts by mass of NBR and 2 parts by mass of surfactant in a kneader for 45 minutes. Then, add 0.2 parts by mass of thermal polymerization inhibitor, 1 part by mass of photopolymerization initiator, and 0.03 parts by mass of ultraviolet absorber into the mixer, and knead for 5 minutes to obtain the photosensitive resin composition of Example 1 .

[0092]

[0093] The photosensitive resin composition obtained above is sandwiched between a 125 μm thick PET film substrate coated with an adhesive in advance on one side and a 100 μm thick PET film protective film coated with an anti-adhesiv...

Embodiment 2~11

[0096] (Examples 2-11, Comparative Examples 1-4)

[0097] From the components shown in Table 1 or Table 2, a photosensitive resin composition was prepared in the same manner as in Example 1, and then a printing plate precursor and a flexographic printing plate were produced in the same manner as in Example 1.

Embodiment 12

[0101]

[0102] Using the components shown in Table 1, the photosensitive resin composition of Example 12 was prepared in the same manner as in Example 1.

[0103]

[0104] Using blade stirring, 28.8 parts by mass of carbon black (manufactured by Mitsubishi Chemical Corporation, trade name: MA8), 28.8 parts by mass of acrylic resin (manufactured by Negami Industry Co., Ltd., trade name: HIPER M4501) and 4.5 parts by mass Parts of plasticizer (produced by Wako Pure Pharmaceutical Co., Ltd., acetyl tributyl citrate), mixed with 105.2 parts by mass of methyl isobutyl ketone. The obtained liquid mixture was dispersed with a triple roll mill, and methyl isobutyl ketone having a solid state of 15% by mass was added to obtain a dope. Then, it was coated on a 100 μm thick PET film with a dried coating film thickness of 2 μm using a bar coater, and dried at 120° C. for 5 minutes to obtain an infrared ablation layer / protective film laminated structure.

[0105]

[0106] In the pr...

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Abstract

Disclosed is a photosensitive resin composition that is superior in water developability, drying characteristics, and image reproducibility. The photosensitive resin composition comprises a water dispersible latex (A), a rubber (B), a surfactant (C), a photopolymerizable monomer (D), and a photoinitiator (E). The mass percent of the aforementioned (C) component is within the range of 0.1-20% of the combined mass of the aforementioned (A) component, the aforementioned (B) component, and the aforementioned (C) component. The mass percent of the aforementioned (A) component is within the range of 20-90% of the combined mass of the aforementioned (A) component and the aforementioned (B) component. The size in the dispersal phase, in which the aforementioned (B) component is the principal component, is less or equal to 10 [mu]m.

Description

technical field [0001] The invention relates to a photosensitive resin composition, a printing plate precursor, and a flexographic printing plate. Background technique [0002] Conventionally, letterpress printing, gravure printing, or lithographic printing have been performed on objects to be printed such as packaging materials, labels, magazines, and the like using printing plates. Among them, letterpress printing is performed using a letterpress. In the letterpress, a flexographic printing plate can be used for various objects to be printed, including objects to be printed made of soft materials. [0003] The original plate of the flexographic printing plate includes a photosensitive layer made of a photosensitive resin composition on a substrate of PET resin or the like. In the flexographic printing plate, the photosensitive layer is irradiated with ultraviolet light through the negative film that is in contact with the photosensitive layer, and the uncured part is rem...

Claims

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Application Information

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IPC IPC(8): G03F7/00B41N1/12G03F7/004
CPCG03F7/033G03F7/032Y10T428/24479
Inventor 井上大辅松冈甲树
Owner SUMITOMO RIKO CO LTD
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