Parallel direct fuel cell energy storage and supply system based on liquid hydrogen storage material

A hydrogen storage material and fuel cell technology, applied in fuel cells, fuel cell additives, circuits, etc., can solve the problems of reducing concentration, unsuitable working medium, increasing dehydrogenation discharge energy loss, etc., to improve safety and simplify devices. , the effect of device simplification

Active Publication Date: 2012-11-28
WUHAN HYNERTECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although some solids can be dissolved in a certain solvent, the solvent will reduce its concentration on the electrode surface, such as solids such as phenanthrene and anthracene, and volatile liquids such as benzene cannot be used as their working medium;
[0011] 2) The dehydrogenation temperature of the hydrogenation molecule should not be too high. For example, the dehydrogenation temperature of cyclohexane, a hydrogenation molecule of benzene, is higher than 300°C, which is far beyond the working temperature of the battery and should not be used as a working medium; at the same time, if the dehydrogenation temperature High, the polarization of the anode of the battery is serious, which increases the energy loss in the dehydrogenation discharge
In addition, unstable molecules such as vinyl alcohol cannot be used as a working medium

Method used

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  • Parallel direct fuel cell energy storage and supply system based on liquid hydrogen storage material
  • Parallel direct fuel cell energy storage and supply system based on liquid hydrogen storage material
  • Parallel direct fuel cell energy storage and supply system based on liquid hydrogen storage material

Examples

Experimental program
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Effect test

Embodiment 1

[0037] A parallel direct fuel cell energy storage energy supply system based on liquid hydrogen storage materials, which includes a fuel cell unit 16 and an electrochemical hydrogenation device unit 17, and the electrochemical hydrogenation unit unit 17 passes through the first AC / DC conversion circuit The fuel cell unit 16 is connected to the load through the second AC / DC conversion circuit; the water inlet 22 on the electrochemical hydrogenation device unit 17 is connected to one end of the water inlet pipe 19, and the other end of the water inlet pipe 19 is connected to the water inlet pipe 19. The bottom of the tank 20 is connected, and the water pump 18 is provided on the water inlet pipe 19; the first water and gas outlet 24 on the electrochemical hydrogenation device monomer 17 is connected with the water tank 20 by the first water outlet pipe 23, and the water tank 20 is provided with Vent (or claim vent) 21; The hydrogen storage material input port 13 on the electroche...

Embodiment 2

[0042] It is basically the same as Example 1, except that the multi-component mixed liquid unsaturated heterocyclic aromatic hydrocarbon is specifically a binary mixed hydrogen storage material of quinoline and N-ethylcarbazole, and the mass ratio of the two components is quinoline Phenyl:N-ethylcarbazole=4:3, and its hydrogen storage capacity is 6.0wt%.

Embodiment 3

[0044] It is basically the same as Example 1, except that the multi-component mixed liquid unsaturated heterocyclic aromatic hydrocarbon is specifically a ternary mixed hydrogen storage material of N-methylcarbazole, quinoline and N-ethylcarbazole, three The mass ratio of the components is N-methylcarbazole:quinoline:N-ethylcarbazole=2:3:1, and its hydrogen storage capacity is 4.9wt%.

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Abstract

The invention relates to a direct fuel cell energy storage and supply system, and in particular relates to a parallel direct fuel cell energy storage and supply system based on a liquid hydrogen storage material. The system comprises a fuel cell single unit and an electrochemical hydrogenation device single unit and is characterized in that a water inlet on the electrochemical hydrogenation device single unit is connected with one end of a water inlet pipe; a hydrogen storage material input hole on the electrochemical hydrogenation device single unit is communicated with the bottom of a hydrogen storage material tank by a hydrogen storage material input pipe; a hydrogen storage material hydride outlet on the electrochemical hydrogenation device single unit is communicated with a hydrogen storage material hydride tank by a hydrogen storage material hydride output pipe; a hydrogen storage material outlet on the fuel cell single unit is communicated with the hydrogen storage material tank by a hydrogen storage material output pipe; a hydrogen storage material hydride input hole on the fuel cell single unit is communicated with the hydrogen storage material hydride tank by a hydrogen storage material hydride input pipe; and the hydrogen storage material tank is filled with the hydrogen storage material which is multi-element mixed liquid unsaturated heterocyclic aromatic hydrocarbon. The system not only simplifies the devices (has simple structure) but also greatly improves the safety.

Description

technical field [0001] The invention relates to hydrogen energy utilization technology in the field of clean energy and new energy. Specifically, it is an energy optimization utilization technology centered on the storage of hydrogen energy and the mutual conversion technology of hydrogen energy and electric energy. That is, electrochemical hydrogenation is performed on a specific reversible hydrogen storage material to achieve electrical energy storage, and the hydrogen energy in the hydrogen storage material hydride is converted into electrical energy through a direct fuel cell. It specifically relates to a parallel direct fuel cell energy storage energy supply system based on liquid hydrogen storage materials. Background technique [0002] Energy is the basis for the survival and development of modern society. The supply capacity of energy is closely related to the sustainable development of the national economy and is one of the strategic foundations of national securit...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M8/06H01M8/04C07D209/86C07D215/04C07D209/08
CPCY02E60/50
Inventor 程寒松倪刚杨明韩超群韩波王圣平吴金平
Owner WUHAN HYNERTECH CO LTD
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