combination
A composition, polymer technology, applied in the field of new materials for injection-molded products, which can solve problems such as negative gloss, taste and odor, negative effects on haze properties, and increased surface viscosity
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[0139] Propylene polymers are prepared. Propylene polymer 1 (Table 1) used in the present invention was prepared by the following procedure.
[0140] polymerization
[0141] Polymer 1 was prepared in a pilot plant in which a loop reactor and a fluidized bed gas phase reactor were connected in series. Catalyst, cocatalyst and donor (donor, donor) are fed into the loop reactor. Before the solid polymer containing active catalyst enters the gas phase reactor, the reactor medium is flashed off.
[0142] A prepolymerized Ti supported catalyst (ZN104 from Basell) was used for the polymerization. The cocatalyst was triethylaluminum (TEAL 93% from SigmaAldrich), while the external donor was dicyclopentyldimethoxysilane (DCPDMS (99%) from WackerChemie). The TEAL / donor ratio (g / g) was 3 and the TEAL / C3 ratio was 0.23 g / kg.
[0143] The PP homopolymer matrix (polymer A) is prepared in the first stage (loop reactor) and the polymerization continues in the second stage (gas phase reacto...
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