Insulation stretch resistant coating, preparation method and application thereof
A technology of anti-stretching and coating, applied in the direction of polyester coating, coating, etc., can solve the problems of affecting production yield, substandard tensile performance, and insufficient withstand voltage performance
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Embodiment 1
[0044] (1) Preparation of polyester resin A:
[0045] ①Under the condition of nitrogen protection, add 9g of bisphenolic acid, 46g of acetic anhydride and 0.1g of pyridine in sequence in the reaction flask equipped with electromagnetic stirring, thermometer and condenser tube, stir and mix evenly, after the bisphenolic acid is completely dissolved, Heated to 80°C to obtain solution A; under stirring conditions, keep solution A warm for 30 minutes, then pour solution A into hot water at 70°C, wash with hot water repeatedly, and vacuum dry in a vacuum oven at 15999Pa and 70°C for 9.5h. Obtain the bisphenolic acid acetate of white powder;
[0046] ②In the reaction flask equipped with electric stirring, thermometer and vacuum decompression device, add the bisphenolic acid acetate prepared in step ①, 9g of bisphenolic acid, 16g of 1,4-cyclohexanedimethanol and 20g of terephthalic acid Mix formic acid evenly, heat to 200°C, start the decompression device to carry out melt polymeriz...
Embodiment 2
[0052] (1) Preparation of polyester resin A:
[0053] ①Under nitrogen protection, add 13.5g of bisphenolic acid, 41g of acetic anhydride and 0.15g of pyridine in sequence in a reaction flask equipped with electromagnetic stirring, a thermometer, and a condenser, stir and mix evenly, and wait until the bisphenolic acid is completely dissolved , heated to 75°C to obtain solution A; under stirring conditions, keep solution A warm for 40 minutes, then pour solution A into hot water at 82°C, wash with hot water repeatedly, and dry in a vacuum oven at 15999Pa and 75°C for 9 hours. Obtain the bisphenolic acid acetate of white powder;
[0054] ②In the reaction flask equipped with electric stirring, thermometer and vacuum decompression device, add bisphenolic acid acetate prepared in step ①, 13.5g bisphenolic acid, 26g 1,4-cyclohexanedimethanol and 16g p-benzene Diformic acid, mixed evenly, heated to 180°C, and started the decompression device to carry out melt polymerization for 2.5 ...
Embodiment 3
[0060] (1) Preparation of polyester resin A:
[0061] ①Under the condition of nitrogen protection, add 11.5g of bisphenolic acid, 41g of acetic anhydride and 0.2g of pyridine in sequence to the reaction flask equipped with electromagnetic stirring, thermometer and condenser, stir and mix evenly, and wait until the bisphenolic acid is completely dissolved , heated to 80°C to obtain solution A; under stirring conditions, keep solution A warm for 30 minutes, then pour solution A into hot water at 70°C, wash with hot water repeatedly, and dry in a vacuum oven at 15999Pa and 70°C for 9.5 hours , to obtain bisphenolic acid acetate of white powder;
[0062] ②In the reaction flask equipped with electric stirring, thermometer and vacuum decompression device, add bisphenolic acid acetate prepared in step ①, 11.5g bisphenolic acid, 16g 1,4-cyclohexanedimethanol and 20g p-benzene Diformic acid, mixed evenly, heated to 200°C, and started the decompression device to carry out melt polymeri...
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