Colored curable resin composition
A technology of curable resin and composition, applied in nonlinear optics, instruments, photosensitive materials for opto-mechanical equipment, etc., can solve the problem of satisfactory contrast of color filters, and achieve high contrast effect
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[0389] Hereinafter, the colored curable resin composition of the present invention will be described in more detail by way of examples.
[0390] Unless otherwise specified, "%" and "part" in an example are mass % and a mass part.
[0391] In the following synthesis examples, compounds were identified by elemental analysis (VARIO-EL: (manufactured by Alementar Co., Ltd.)).
Synthetic example 1
[0393] In the flask that has condensing tube and stirrer, drop into the mixture (commercial name ChugaiAminol Fast Pink R of the compound shown in formula (A0-1) and the compound shown in formula (A0-2; ChugaiAminol Fast Pink R; Chugai Huacheng manufactures) 15 parts , 150 parts of chloroform and 8.9 parts of N,N-dimethylformamide were added dropwise to 10.9 parts of thionyl chloride while maintaining the temperature below 20°C under stirring. After completion|finish of dripping, it heated up to 50 degreeC, maintained at this temperature for 5 hours, made it react, and cooled to 20 degreeC after that. While maintaining the cooled reaction solution at 20° C. or lower while stirring, a mixed solution of 12.5 parts of 2-ethylhexylamine and 22.1 parts of triethylamine was added dropwise. Thereafter, the mixture was stirred at the temperature for 5 hours to make it react. Next, the solvent was distilled off from the obtained reaction mixture with a rotary evaporator, and then a sm...
Synthetic example 2
[0397] 20 parts of the compound represented by the formula (1x) and 200 parts of N-ethyl-o-toluidine (manufactured by Wako Pure Chemical Industries, Ltd.) were mixed under light-shielding conditions, and the resulting solution was stirred at 110° C. for 6 hours. After cooling the obtained reaction solution to room temperature, it was added to a liquid mixture of 800 parts of water and 50 parts of 35% hydrochloric acid, and stirred at room temperature for 1 hour, as a result, crystals were deposited. The precipitated crystals were collected as a suction-filtered residue and dried to obtain 24 parts of the compound represented by the formula (1-30). The yield is 80%.
[0398]
[0399] The structure of the compound represented by the formula (1-30) was confirmed by mass spectrometry (LC: 1200 type manufactured by Agilent, MASS: LC / MSD type manufactured by Agilent).
[0400] (Mass spectrometry) ionization mode = ESI+; m / z = [M+H] + 603.4
[0401] Exact Mass: 602.2
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