Maleic anhydride grafted polypropylene material

A technology for grafting polypropylene and maleic anhydride is applied in the field of maleic anhydride grafting polypropylene materials, and can solve problems such as insignificant experimental results, production safety problems, and lack of theoretical basis.

Active Publication Date: 2013-02-13
HUANGSHAN BANNER TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Such as Chinese patent literature "Polypropylene grafted maleic anhydride compatibilizer" (CN1456430A), "A preparation method of a maleic anhydride grafted polypropylene resin graft" (CN101724128A), "A maleic anhydride grafted Branched polypropylene material and its preparation method" (CN101357968A), "A melt-extruded low-odor PP grafted maleic anhydride and its preparation method" (CN101942061A) respectively recorded the use of adding oleic acid, styrene, acrylic acid, acrylic acid Esters, etc., are used as the second mon

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] Weigh the raw materials in the following parts by weight:

[0022] Polypropylene: 95 parts by weight; Maleic anhydride: 1.0 parts by weight; 2,5-dimethyl-2,5-bis(tert-butylperoxy)hexane: 0.3 parts by weight; 1,3,5-tri Triallyl polycyanate: 3.0 parts by weight; antioxidant 1010: 0.2 parts by weight.

[0023] Melt and stir maleic anhydride, initiator, auxiliary grafting monomer and antioxidant at 50°C to form a mixed liquid, and take the weighed polypropylene and mixed liquid from the feeding port and liquid feeding port of the extruder respectively The product can be obtained by extruding and granulating under the condition of 165°C.

Embodiment 2

[0025] Weigh the raw materials in the following parts by weight:

[0026] Polypropylene: 90 parts by weight; maleic anhydride: 4 parts by weight; 2,5-dimethyl-2,5-bis(tert-butylperoxy)hexane: 1 part by weight; diallyldiethoxy Base silane: 0.5 parts by weight; antioxidant 1010: 2 parts by weight.

[0027] Melt and stir maleic anhydride, initiator, auxiliary grafting monomer and antioxidant at 60°C to form a mixed liquid, and take the weighed polypropylene and mixed liquid from the feeding port and liquid feeding port of the extruder respectively The finished product can be obtained by extruding and granulating under the condition of 210°C.

Embodiment 3

[0029] Weigh the raw materials in the following parts by weight:

[0030] Polypropylene: 95 parts by weight; maleic anhydride: 2.0 parts by weight; 2,5-dimethyl-2,5-bis(tert-butylperoxy)hexane: 0.8 parts by weight; triallylisocyanurate Ester: 1.5 parts by weight; antioxidant 1076: 1.0 parts by weight.

[0031] Melt and stir maleic anhydride, initiator, auxiliary grafting monomer and antioxidant at 55°C to form a mixed liquid, and take the weighed polypropylene and mixed liquid from the feeding port and liquid feeding port of the extruder respectively Adding, extruding and granulating under the condition of 180°C, the finished product can be obtained.

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Abstract

The invention discloses a maleic anhydride grafted polypropylene material. Maleic anhydride, polypropylene and an assistant grafting monomer are grafted under the effects of an initiator and an antioxidant to obtain the maleic anhydride grafted polypropylene material. The used assistant grafting monomer can play a role of increasing the grafting ratio and inhibiting the polypropylene to be degraded, and therefore the grafting ratio is effectively increased. Meanwhile, a new initiator is introduced to reduce the pungent smell of the maleic anhydride grafted polypropylene material, and the degree of grafting reaction and the degree of copolymerization of the assistant monomer are enhanced, so that the prepared product has a high grafting ratio and low pungent smell.

Description

technical field [0001] The invention relates to the field of polymer materials, in particular to a maleic anhydride grafted polypropylene material. Background technique [0002] With the development of domestic polypropylene modified materials, there are more and more studies on compatibilizers used in polypropylene modified materials. Since the polypropylene material itself is a non-polar material, its miscibility with polar materials such as fillers and glass fibers is relatively poor. The easiest way to improve the miscibility is to add a compatibilizer. At present, the most commonly used compatibilizer is maleic anhydride grafted polypropylene, which can effectively improve the compatibility between polypropylene materials and polar materials. [0003] The production methods of maleic anhydride grafted polypropylene mainly include melt extrusion grafting method, solution grafting method, solid phase grafting method and suspension grafting method. The most commonly used...

Claims

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Application Information

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IPC IPC(8): C08F255/02C08F222/06C08F228/02C08F222/02C08F216/36C08F212/14C08F212/32C08F230/08C08F226/06C08F4/34C08F4/36
Inventor 袁宗伟胡恩谓汪义辉陈鸣芳曹拥民
Owner HUANGSHAN BANNER TECH
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