Aminoalkyl glucoside graft copolymer and preparation method thereof, and drilling fluid

A technology of graft copolymer and amino alkyl sugar, which is applied in the field of amino alkyl glycoside graft copolymer and its preparation, and drilling fluid, and can solve the problems of limited popularization and application, poor compatibility, and poor environmental performance. , to achieve the effect of simple operation steps, mild reaction conditions and good inhibition performance

Inactive Publication Date: 2018-05-01
中石化石油工程技术服务有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0002] In recent years, with the increasing number of deep wells, ultra-deep wells, highly deviated wells, and horizontal wells in the field of oil drilling, deep and ultra-deep wells in deep wells and ultra-deep wells with high formation temperature are prone to collapse The problem of wellbore instability during drilling cannot be well solved
The use of oil-based drilling fluid can solve the problem of wellbore instability to a certain extent, but oil-based drilling fluid has the problems of high preparation cost and poor environmental performance
Usually, strong amine-based inhibitors are used as the core main agent of drilling fluid, and other treatment agents are used together to prepare water-based drilling fluid with better inhibitory performance. This water-based drilling fluid has the performance of oil-based drilling fluid, but the amine-based The poor compatibility of inhibitors and other treatment agents makes it difficult to control the stability of water-based drilling fluids, which limits their promotion and application
[0003] In terms of modification of strong amine-based inhibitors, an alkyl glycoside oil-based drilling fluid was proposed abroad in the 1990s. This oil-based drilling fluid has good environmental performance, but due to the inhibitory properties of alkyl glycosides and The high temperature resistance is poor, and it needs to add more than 35% in the drilling fluid to fully exert its inhibitory performance, which increases the production cost of the drilling fluid

Method used

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  • Aminoalkyl glucoside graft copolymer and preparation method thereof, and drilling fluid
  • Aminoalkyl glucoside graft copolymer and preparation method thereof, and drilling fluid
  • Aminoalkyl glucoside graft copolymer and preparation method thereof, and drilling fluid

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preparation example Construction

[0046] The invention provides a kind of preparation method of amino alkyl glycoside graft copolymer, comprises the following steps:

[0047] (1) reacting alkyl glycosides, epoxides, chlorides and acidic catalysts to obtain the first intermediate product;

[0048] (2) reacting the first intermediate product with the fatty amine to obtain the second intermediate product;

[0049] (3) Under the action of an initiator, react the second intermediate product, acrylamide and 2-acrylamide-2-methylpropanesulfonic acid to obtain an amino alkyl glycoside graft copolymer.

[0050] In the step (1) of the present invention, under the action of an acidic catalyst and a chloride, the alkyl glycoside is modified by using an epoxide. In the present invention, the reaction temperature in the step (1) is preferably 40-80°C, more preferably 50-70°C, most preferably 55-65°C. In the present invention, the reaction time in the step (1) is preferably 0.5-3 hours, more preferably 1-2.5 hours, most pr...

Embodiment 1

[0112] Add 40 parts of methyl glucoside, 8 parts of propylene oxide, 9 parts of thionyl chloride and 0.8 parts of hydrofluoric acid into the high-temperature and high-pressure reaction kettle by weight, and use nitrogen to purge the air in the kettle, and use nitrogen to raise the temperature. When the pressure reaches 1.0 MPa, start stirring, raise the temperature to 40°C and react for 0.5 hours to obtain the first intermediate product; add 50 parts of water and 10 parts of ethylenediamine to the first intermediate product, stir and mix evenly, and raise the temperature to 180°C to react 2 Hours, the second intermediate product was obtained; 20 parts of acrylamide and 10 parts of 2-acrylamide-2-methylpropanesulfonic acid were added to the second intermediate product, stirred and dissolved completely, the pH value was adjusted to 8, and 0.3 parts of ammonium sulfate was added The initiator was reacted at 40° C. for 4 hours to obtain the crude product of aminomethyl glycoside gr...

Embodiment 2

[0116] Add 50 parts of ethyl glucoside, 9 parts of butylene oxide, 10 parts of sulfuryl chloride and 1.0 part of tartaric acid into the high-temperature and high-pressure reaction kettle by weight, use nitrogen to purge the air in the kettle, and use nitrogen to raise the pressure to 2.0MPa, and start stirring , raising the temperature to 50°C for 1 hour to obtain the first intermediate product; adding 60 parts of water and 11 parts of diethylenetriamine to the first intermediate product, stirring and mixing evenly, raising the temperature to 190°C for 3 hours to obtain The second intermediate product; add 24 parts of acrylamide and 12 parts of 2-acrylamide-2-methylpropanesulfonic acid to the second intermediate product, stir and dissolve completely, adjust the pH value to 9, and add 0.4 parts of potassium permanganate The initiator was reacted at 50° C. for 5 hours to obtain the crude product of aminoethylglycoside graft copolymer.

[0117] Wash and filter the crude aminoethy...

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Abstract

The invention provides a preparation method for an aminoalkyl glucoside graft copolymer. The preparation method comprises the following steps: (1) subjecting alkyl glucoside, epoxide, chloride and anacidic catalyst to a reaction so as to obtain a first intermediate; (2) reacting the first intermediate with alicyclic amine so as to obtain a second intermediate; and (3) under the action of an initiator, subjecting the second intermediate, acrylamide and 2-acrylamide-2-methylpropanesulfonic acid to a reaction so as to obtain the aminoalkyl glucoside graft copolymer. With the method provided by the invention, the aminoalkyl glucoside graft copolymer with a specific structure is prepared and has good inhibition performance, lubrication performance, filtrate loss reducing performance, and resistance to contamination by saturated salts and composite salts. Moreover, the aminoalkyl glucoside graft copolymer is free of biological toxicity. The invention also provides the aminoalkyl glucoside graft copolymer and a drilling fluid.

Description

technical field [0001] The invention relates to the technical field of drilling, in particular to an amino alkyl glycoside graft copolymer, a preparation method thereof and a drilling fluid. Background technique [0002] In recent years, with the increasing number of deep wells, ultra-deep wells, highly deviated wells, and horizontal wells in the field of oil drilling, deep and ultra-deep wells in deep wells and ultra-deep wells with high formation temperature are prone to collapse The problem of wellbore instability during drilling cannot be solved well. Using oil-based drilling fluid can solve the problem of wellbore instability to a certain extent, but oil-based drilling fluid has the problems of high preparation cost and poor environmental performance. Usually, strong amine-based inhibitors are used as the core main agent of drilling fluid, and other treatment agents are used together to prepare water-based drilling fluid with better inhibitory performance. This water-b...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07H15/08C07H1/00C08F220/56C08F220/58C09K8/035C09K8/12
CPCC07H1/00C07H15/08C08F283/06C08G65/2624C08G65/333C09K8/035C09K8/12C09K2208/34C08F220/56
Inventor 司西强王中华樊好福雷祖猛吕跃滨谢俊
Owner 中石化石油工程技术服务有限公司
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