Aminoalkyl glucoside graft copolymer and preparation method thereof, and drilling fluid
A technology of graft copolymer and amino alkyl sugar, which is applied in the field of amino alkyl glycoside graft copolymer and its preparation, and drilling fluid, and can solve the problems of limited popularization and application, poor compatibility, and poor environmental performance. , to achieve the effect of simple operation steps, mild reaction conditions and good inhibition performance
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[0046] The invention provides a kind of preparation method of amino alkyl glycoside graft copolymer, comprises the following steps:
[0047] (1) reacting alkyl glycosides, epoxides, chlorides and acidic catalysts to obtain the first intermediate product;
[0048] (2) reacting the first intermediate product with the fatty amine to obtain the second intermediate product;
[0049] (3) Under the action of an initiator, react the second intermediate product, acrylamide and 2-acrylamide-2-methylpropanesulfonic acid to obtain an amino alkyl glycoside graft copolymer.
[0050] In the step (1) of the present invention, under the action of an acidic catalyst and a chloride, the alkyl glycoside is modified by using an epoxide. In the present invention, the reaction temperature in the step (1) is preferably 40-80°C, more preferably 50-70°C, most preferably 55-65°C. In the present invention, the reaction time in the step (1) is preferably 0.5-3 hours, more preferably 1-2.5 hours, most pr...
Embodiment 1
[0112] Add 40 parts of methyl glucoside, 8 parts of propylene oxide, 9 parts of thionyl chloride and 0.8 parts of hydrofluoric acid into the high-temperature and high-pressure reaction kettle by weight, and use nitrogen to purge the air in the kettle, and use nitrogen to raise the temperature. When the pressure reaches 1.0 MPa, start stirring, raise the temperature to 40°C and react for 0.5 hours to obtain the first intermediate product; add 50 parts of water and 10 parts of ethylenediamine to the first intermediate product, stir and mix evenly, and raise the temperature to 180°C to react 2 Hours, the second intermediate product was obtained; 20 parts of acrylamide and 10 parts of 2-acrylamide-2-methylpropanesulfonic acid were added to the second intermediate product, stirred and dissolved completely, the pH value was adjusted to 8, and 0.3 parts of ammonium sulfate was added The initiator was reacted at 40° C. for 4 hours to obtain the crude product of aminomethyl glycoside gr...
Embodiment 2
[0116] Add 50 parts of ethyl glucoside, 9 parts of butylene oxide, 10 parts of sulfuryl chloride and 1.0 part of tartaric acid into the high-temperature and high-pressure reaction kettle by weight, use nitrogen to purge the air in the kettle, and use nitrogen to raise the pressure to 2.0MPa, and start stirring , raising the temperature to 50°C for 1 hour to obtain the first intermediate product; adding 60 parts of water and 11 parts of diethylenetriamine to the first intermediate product, stirring and mixing evenly, raising the temperature to 190°C for 3 hours to obtain The second intermediate product; add 24 parts of acrylamide and 12 parts of 2-acrylamide-2-methylpropanesulfonic acid to the second intermediate product, stir and dissolve completely, adjust the pH value to 9, and add 0.4 parts of potassium permanganate The initiator was reacted at 50° C. for 5 hours to obtain the crude product of aminoethylglycoside graft copolymer.
[0117] Wash and filter the crude aminoethy...
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