A kind of Toosendan extract and its application
A technology of toosendan extract, applied in the field of toosendan extract, achieves low energy consumption, high efficiency, and economical and reasonable effects
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Embodiment 1
[0029] The preparation of embodiment 1 toosendan extract
[0030] Take 4 kg of Toosendan medicinal material, crush it into coarse powder, reflux extract with 50 L of 75% ethanol for 3 times, each time for 2 hours, combine the extracts, recover the solvent under reduced pressure, and obtain 550 g of Toosendan extract, disperse it with 4 L of water, and disperse it with acetic acid The ethyl acetate was shaken and extracted 4 times, 4 L each time, the ethyl acetate extracts were combined, and the solvent was recovered under reduced pressure to obtain Toosendan extract (180 g).
Embodiment 2
[0031] The separation and identification of chemical constituents in the extract of Toosendan in embodiment 2
[0032] Take Toosendan extract (100 g) obtained in Example 1, perform normal-pressure silica gel column chromatography, and gradient elution with petroleum ether (60-90° C.)-ethyl acetate system to obtain 140 fractions, which were detected by TLC and combined There are 10 components (F1~10). Compound 1 was isolated from F6 (Fr87-92) by using various adsorption materials such as silica gel, reversed-phase silica gel, and gel, and through various separation methods such as atmospheric pressure column chromatography, medium pressure column chromatography, and high-pressure liquid phase preparation technology. (51 mg) and compound 2 (14 mg); compound 3 (22 mg) was obtained from F5 (Fr73-86); compound 4 (300 mg) was obtained from F8 (Fr98-109).
[0033] The MS, NMR and other data of compounds 1, 2 and 4 were confirmed as Nimbolin A (NimbolinA), Nimbolin B (Nimbolinin B) a...
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