Novel efficient grapheme loaded nano-iron material for adsorbing phosphorus in water

A nano-iron and graphene technology, applied in the direction of adsorption water/sewage treatment, water/sewage treatment, water/sludge/sewage treatment, etc., can solve the problem of nano-iron stability decline

Inactive Publication Date: 2013-04-03
TSINGHUA UNIV
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  • Abstract
  • Description
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  • Application Information

AI Technical Summary

Problems solved by technology

Although the stability of nano-iron has been enhanced to a certain extent after being loaded on these materials, and the efficiency of removing pollu

Method used

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  • Novel efficient grapheme loaded nano-iron material for adsorbing phosphorus in water
  • Novel efficient grapheme loaded nano-iron material for adsorbing phosphorus in water

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] In a 200ml Erlenmeyer flask, add 100ml concentration of 4mg / L phosphate root solution, and add 500mg nano-iron adsorption material accounting for 20% of the total weight of the material. Put the Erlenmeyer flask into a shaker with a speed of 30 rpm and a temperature of 25 °C. After 10 minutes, the graphene-loaded nano-iron adsorbed 80% of the phosphate.

Embodiment 2

[0031] In a 200ml Erlenmeyer flask, add 100ml of a phosphate solution with a concentration of 4mg / L, and add 250mg of an adsorption material in which nano-iron accounts for 40% of the total weight of the material. Put the Erlenmeyer flask into a shaker with a speed of 30 rpm and a temperature of 25 °C. After 10 minutes, the graphene-supported nano-iron adsorbed 73% of the phosphate.

Embodiment 3

[0033] Add 100ml concentration of 4mg / L phosphate root solution in a 200ml Erlenmeyer flask, and add 160mg of adsorption material whose nano-iron accounts for 60% of the total weight of the material. Put the Erlenmeyer flask into a shaker with a speed of 30 rpm and a temperature of 25 °C. After 10 minutes, the graphene-supported nano-iron adsorbed 70% of the phosphate.

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Abstract

The invention relates to a novel efficient grapheme loaded nano-iron material for adsorbing phosphorus in water. The grapheme loaded nano-iron material is composed of nano-iron and grapheme, wherein the nano-iron accounts for 10-70 percent of the total weight of the material. The macrostructure of the material is powder-shaped, and as for the microstructure, the grapheme adopts a sheet-shaped structure, the nano-iron is uniformly dispersed on the surface of the grapheme, when the nano-iron accounts for 30 percent or less than 30 percent of the total weight of the material, the nano-iron adopts a dot-shaped structure, and when the nano-iron accounts for more than 30 percent of the total weight of the material, the nano-iron adopts a chain structure; the particle diameter of nano-iron is 50-70 nm; the nano-iron is loaded on grapheme, firstly, elemental iron reacts with hydrogen ions to generate ferrous iron, and then ferrous iron, phosphate radical and water molecules are reacted to quickly generate hydrated ferrous phosphate or hydrated iron phosphate; and under the condition that the initial concentration of phosphate radical in water is less than 4 mg/L, the grapheme loaded nano-iron can remove over 99 percent of phosphate radical, so that the effluent concentration of phosphate radical is under 0.02 mg/L, as a result, when the concentration of phosphate radical in inflow water quality of lakes is less than 0.02 mg/L, eutrophication cannot occur.

Description

technical field [0001] The invention relates to a material for adsorbing phosphorus in water, in particular to a novel graphene-supported nano-iron material for efficiently adsorbing phosphorus in water. Background technique [0002] Eutrophication is an environmental problem that the world is concerned about today. Many lakes in the world have suffered from eutrophication. Eutrophication can cause many problems, for example, it can reduce the light transmission of the lake, lead to the reduction of biomass in the lake and the bloom of blue-green algae and so on. The excess of nutrients, especially the excessive concentration of phosphorus, is the main factor causing eutrophication. As an essential nutrient element for algae, phosphorus plays a vital role in the process of eutrophication. One of the keys to control eutrophication is to control the concentration of phosphorus in water. In order to better control the concentration of phosphorus in water, a lot of research h...

Claims

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Application Information

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IPC IPC(8): C02F1/28C02F1/58B01J20/20
Inventor 左剑恶刘峰林王佩杨波谢帮蜜
Owner TSINGHUA UNIV
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