Method for preparing functional carbon fiber composite electrothermal paper

A functionalized carbon and fiber composite technology, which is applied in the direction of synthetic cellulose/non-cellulose material pulp/paper, fiber raw material treatment, papermaking, etc., can solve problems such as low Internet access rate, functional powder shedding and loss, and large water pollution , to achieve excellent wet strength and dry strength, large quantitative adjustment range, and stable electrothermal performance

Active Publication Date: 2013-05-15
DONGHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The advantages of these methods are that they are simple and easy to operate, and have good functionalization effects; but their disadvantages are also very obvious, for example, the method of filling functional powder may lead to the decline of the mechanical properties of carbon fiber electric heating paper, and at the same time, the functional filler and fiber There is only a physical connection between them, so the functional powder will gradually fall off and lose over time, resulting in a decline in the functionalization effect. In addition, the particle size of the functional filling powder is small, and the netting rate is low in the process of wet papermaking. Seriously, huge waste will be generated in the preparation process; another example is that after impregnating carbon fiber electric heating paper with heat-resistant and flame-retardant resin, although it has good flame-retardant performance, it loses the original light and soft characteristics of the paper
[0007] In addition, in the existing wet papermaking process of carbon paper, due to the need to use a large amount of fiber dispersant and wet strengthening agent in the slurry preparation process, it will not only cause large water pollution, but also have a large amount of additives. , serious waste, it is difficult to adapt to the requirements of green and energy-saving circular economy development

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] (1) Activate the surface of carbon fiber by plasma surface treatment to obtain activated carbon fiber, and carry the functional body on the surface of the activated carbon fiber, the functional body is a far-infrared emitter; the carbon fiber is a PAN-based carbon fiber;

[0044] (2) Perform conventional sizing treatment on the activated carbon fibers with a functional sizing agent, the functional sizing agent is an aqueous solution of a carbon fiber dispersant, wherein the concentration of the carbon fiber dispersant is 5wt%, and the carbon fiber dispersant is polyacrylamide;

[0045] (3) Chopping the carbon fibers loaded with functional bodies on the surface to prepare functionalized carbon fibers, the length of the functionalized carbon fibers is 2 mm;

[0046] (4) Uniformly dispersing the functionalized carbon fiber in water to form a carbon fiber dispersion, wherein the content of the functionalized carbon fiber is 0.5wt‰, and the balance is water;

[0047] (5) U...

Embodiment 2

[0053] (1) Using KOH as an activator, surface activation treatment is carried out on the carbon fiber to obtain activated carbon fiber, and the functional body is carried on the surface of the activated carbon fiber, and the functional body is a phase change material microcapsule; the carbon fiber is pitch-based carbon fiber;

[0054] (2) Perform conventional sizing treatment on the activated carbon fibers with a functional sizing agent, the functional sizing agent is an aqueous solution of a carbon fiber dispersant, wherein the concentration of the carbon fiber dispersant is 30wt%, and the carbon fiber dispersant is polyethylene oxide;

[0055] (3) Chopping the carbon fibers loaded with functional bodies on the surface to prepare functionalized carbon fibers, the length of the functionalized carbon fibers is 10mm;

[0056] (4) Uniformly dispersing the functionalized carbon fiber in water to form a carbon fiber dispersion, wherein the content of the functionalized carbon fibe...

Embodiment 3

[0063] (1) Use NaOH as the activator to activate the surface of carbon fibers to obtain activated carbon fibers, and load functional bodies on the surface of the activated carbon fibers, the functional bodies are flame retardants; the carbon fibers are asphalt base carbon fiber;

[0064] (2) Perform conventional sizing treatment on the activated carbon fibers with a functional sizing agent, the functional sizing agent is an aqueous solution of a carbon fiber dispersant, wherein the concentration of the carbon fiber dispersant is 10wt%, and the carbon fiber dispersant Combination of polyacrylamide and polyethylene oxide;

[0065] (3) Chopping the carbon fiber with the functional body on the surface to prepare functionalized carbon fiber, the length of the functionalized carbon fiber is 7 mm;

[0066] (4) Uniformly disperse the functionalized carbon fiber in water to form a carbon fiber dispersion, wherein the content of the functionalized carbon fiber is 1wt‰, and the balance ...

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Abstract

The invention relates to a method for preparing functional carbon fiber composite electrothermal paper. The method comprises the following steps of: (1) preparing functional carbon fibers; (2) preparing papermaking slurry; (3) making paper; and (4) performing post-treatment. The functional carbon fibers are prepared by carrying a functional body on the surface of an activated carbon fiber; wet papermaking is executed, so that functionalization of the functional carbon fiber composite electrothermal paper is realized; compared with the conventional functionalization method for the carbon fiber composite electrothermal paper, the method has the advantages that the problems of large using amount of functional powder bodies and high waste during preparation are solved; during preparation, the problems of large using amount of wet papermaking technological auxiliaries and severe water pollution are solved; the method is environment-friendly and energy-saving; and the prepared functional carbon fiber composite electrothermal paper has the advantages of high functionalization efficiency, obvious effect, durability and stability.

Description

technical field [0001] The invention relates to a preparation method of carbon fiber composite electric heating paper, in particular to a preparation method of functionalized carbon fiber composite electric heating paper. Background technique [0002] Carbon fiber paper is a functional paper with special properties produced by using carbon fiber or activated carbon fiber and carbon fiber or activated carbon fiber mixed with other plant or non-plant fibers. Carbon fiber paper has many excellent properties, such as electrical conductivity, thermal conductivity, porosity, adsorption, etc., so it is widely used in energy, military, environmental protection, civil engineering, electronic appliances, heating and other fields. [0003] In recent years, with the continuous reduction of the cost of carbon fiber, the excellent electrical conductivity and electrothermal properties of carbon fiber paper have attracted more and more attention in the field of civil electric heating. The ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D21H13/50
Inventor 王彪施云舟王华平
Owner DONGHUA UNIV
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