Preparation and application of solvent-free spraying polyurethane pipeline mending coating
A polyurethane and solvent-free technology is applied in the field of preparation of solvent-free spray-type polyurethane pipe patching coatings, which can solve the problems of insignificant effect, high overhaul cost, and difficulty in guaranteeing construction quality.
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Embodiment 1
[0038] Synthesize 37.5 parts of MDI-50, 37.5 parts of MDI-100, and 25.0 parts of aminoethylaminopropyl polydimethylsiloxane according to the process of the present invention to obtain a prepolymer with an NCO% of 24.5%, which is A components. The R component is composed of 18.7 parts of hydroxyl-terminated cross-linking agent triethanolamine, 156.3 parts of polyoxypropylene ether triol TMN3050, 190 parts of filler ultrafine barium sulfate, 5 parts of water-absorbing agent A3, 0.5 parts of organic tin catalyst T-12, 2.0 parts Composed of defoamer BYK-530, 2.0 parts of anti-settling agent BYK-306 and 1.0 parts of leveling agent BYK-361N. A and R components are sprayed on the surface of the substrate according to 1:2.5 (volume ratio).
Embodiment 2
[0040]Synthesize 41.0 parts of MDI-50, 41.0 parts of MDI-100, and 18.0 parts of aminoethylaminopropyl polydimethylsiloxane according to the process of the present invention to obtain a prepolymer with an NCO% of 27.0%, which is Group A point. The R component is composed of 21.5 parts of hydroxyl-terminated cross-linking agent triethanolamine, 153.5 parts of polyoxypropylene ether triol TMN3050, 190 parts of superfine barium sulfate filler, 5 parts of water-absorbing agent A3, 0.5 parts of organotin catalyst T-12, 2.0 parts Composed of defoamer BYK-530, 2.0 parts of anti-settling agent BYK-306 and 1.0 parts of leveling agent BYK-361N. A and R components are sprayed on the surface of the substrate according to 1:2.5 (volume ratio).
Embodiment 3
[0042] Synthesize 44.5 parts of MDI-50, 44.5 parts of MDI-100, and 11.0 parts of aminoethylaminopropyl polydimethylsiloxane according to the process of the present invention to obtain a prepolymer with an NCO% of 29.8%, which is A components. The R component is composed of 24.7 parts of hydroxyl-terminated cross-linking agent triethanolamine, 150.3 parts of polyoxypropylene ether triol TMN3050, 190 parts of filler superfine barium sulfate, 5 parts of water-absorbing agent A3, 0.5 parts of organotin catalyst T-12, 2.0 parts Composed of defoamer BYK-530, 2.0 parts of anti-settling agent BYK-306 and 1.0 parts of leveling agent BYK-361N. A and R components are sprayed on the surface of the substrate according to 1:2.5 (volume ratio).
[0043] The performance comparison of implementation cases 1-3 is shown in Table 1.
[0044] Table 1 Performance comparison of implementation cases 1 to 3
[0045]
[0046] It can be seen from Table 1 that with the increase of NCO%, the hardnes...
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Abstract
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