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Secondary battery porous film slurry, secondary battery porous film, secondary battery electrode, secondary battery separator and secondary battery

A secondary battery and porous membrane technology, applied in the field of secondary battery porous membrane slurry, can solve problems such as explosion, positive and negative short circuits, etc., and achieve excellent flexibility, improved cycle characteristics, excellent dispersibility and coating properties Effect

Active Publication Date: 2016-08-10
ZEON CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

As a result, there may be a short circuit between the positive and negative electrodes, an explosion due to the release of electric energy, etc.

Method used

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  • Secondary battery porous film slurry, secondary battery porous film, secondary battery electrode, secondary battery separator and secondary battery

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0257]

[0258] 100 parts of styrene, 1.0 parts of sodium dodecylbenzenesulfonate, 100 parts of ion-exchanged water, and 0.5 parts of potassium persulfate were placed in a reactor equipped with a stirrer, and polymerized at 80° C. for 8 hours. Thus, an aqueous dispersion of seed polymer particles A having an average particle diameter of 60 nm was obtained.

[0259]

[0260] 2 parts of aqueous dispersion of the seed polymer particles A obtained in the step (1) (based on the solid content, that is, based on the weight of the seed polymer particles A), 12 parts in a reactor equipped with a stirrer 0.2 parts of sodium alkylbenzenesulfonates, 0.5 parts of potassium persulfate, and 100 parts of ion-exchanged water were mixed to obtain a mixture, and the temperature was raised to 80°C. On the other hand, in another container, 97 parts of styrene, 3 parts of methacrylic acid, 4 parts of t-dodecyl mercaptan, 0.5 parts of sodium dodecylbenzenesulfonate, and 100 parts of ion-exchange...

Embodiment 2

[0288] Instead of the non-conductive organic particles obtained in steps (1) to (3) of Example 1, the following non-conductive organic particles were used. Moreover, instead of the binder for porous membranes obtained in the process (4) of Example 1, the following binder for porous membranes was used. Using the non-conductive organic particles and the binder for the porous film to produce a porous film slurry, except that, the same operation as in Example 1 was carried out to obtain an organic separator with a porous film and a secondary battery, and carried out evaluate. The results are shown in Table 1.

[0289]

[0290] 10 parts of the aqueous dispersion of the seed polymer particles B obtained in step (2) (based on the solid content, that is, based on the weight of the seed polymer particles B), monomer Mixture (mixture of divinylbenzene and ethylvinylbenzene, monomer mixing ratio: divinylbenzene / ethylvinylbenzene=60 / 40, manufactured by Nippon Steel Chemical Co., produ...

Embodiment 3

[0300] Instead of the non-conductive organic particles obtained in steps (1) to (3) of Example 1, the following non-conductive organic particles were used. Moreover, instead of the binder for porous membranes obtained in the process (4) of Example 1, the following binder for porous membranes was used. Using the non-conductive organic particles and the binder for the porous film to produce a porous film slurry, except that, the same operation as in Example 1 was carried out to obtain an organic separator with a porous film and a secondary battery, and carried out evaluate. The results are shown in Table 1.

[0301]

[0302] 10 parts of the aqueous dispersion of the seed polymer particles B obtained in step (2) (based on the solid content, that is, based on the weight of the seed polymer particles B), monomer Mixture (mixture of divinylbenzene and ethylvinylbenzene, monomer mixing ratio: divinylbenzene / ethylvinylbenzene=60 / 40, manufactured by Nippon Steel Chemical Co., Ltd.,...

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PUM

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Abstract

The object of the present invention is to provide a secondary battery porous membrane manufactured using a secondary battery porous membrane slurry with excellent coating properties and excellent dispersibility of non-conductive organic particles. The secondary battery porous membrane can make the resulting secondary battery The cycle characteristics are improved, its softness is high, it can prevent powder falling, and it contains less water. In addition, the object of the present invention is to provide non-conductive organic particles which contain less metal impurities and are suitable for porous membranes of secondary batteries. To this end, the present invention provides a secondary battery porous membrane slurry, which contains: a binder comprising a polymerized unit of a vinyl monomer having a thermally crosslinkable group; Non-conductive organic particles with cross-linked functional groups, and solvents.

Description

technical field [0001] The present invention relates to a slurry for a porous membrane of a secondary battery, and more specifically, relates to a slurry that is used to manufacture an electrode or a separator surface formed in a lithium ion secondary battery, has high flexibility, and can contribute to the cycle characteristics of the battery. Improved secondary battery porous membrane slurry for secondary battery porous membrane. In addition, the present invention relates to a secondary battery electrode, a secondary battery separator, and a secondary battery including such a secondary battery porous membrane. Background technique [0002] Among the batteries that have been put into practical use, lithium-ion secondary batteries show the highest energy density, and are especially used for small electronic devices. In addition, in addition to small applications, it is also expected to expand to the automotive field. Among them, a longer life and further improvement in saf...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M2/16H01M4/02H01M4/04H01M4/13H01M4/139H01M10/04H01M10/058H01M10/0566
CPCH01M2004/021Y02E60/10H01M50/446H01M50/46Y02P70/50H01M4/13H01M50/414H01M50/443H01M50/491H01M50/403H01M10/0525
Inventor 金田拓也松村卓
Owner ZEON CORP