Flame-retardant thermoplastic starch material, bio composite, and method for manufacturing the same

A thermoplastic starch and flame retardant technology, used in the field of flame retardant thermoplastic starch, can solve the problems of flame retardants such as high temperature resistance, poor processability, and inability to form, and achieve increased toughness, excellent mechanical properties and flame retardant properties. , the effect of improving the overall physical properties

Active Publication Date: 2014-01-15
IND TECH RES INST
View PDF9 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The flame retardants used in the above technologies have problems such as expansion, explosion or deterioration, or poor processability because they are not resistant to high temperature operating environments, while phosphate esters have the problem of being unable to form although they can withstand high temperatures

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Flame-retardant thermoplastic starch material, bio composite, and method for manufacturing the same
  • Flame-retardant thermoplastic starch material, bio composite, and method for manufacturing the same
  • Flame-retardant thermoplastic starch material, bio composite, and method for manufacturing the same

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0031]The invention provides a method for preparing a flame-retardant thermoplastic starch-based biomass composite material. According to the method of the invention, firstly, (A1) 100 parts by weight of starch, (A2) 5-75 parts by weight of plasticizer, and ( A3) 5-30 parts by weight of organophosphorus-based flame retardants are mixed and subjected to a kneading and plasticizing process at 60-100° C., preferably 70-90° C., to form a flame-retardant thermoplastic starch material (A).

[0032] Next, mix (A) 5-40 parts by weight of the above-mentioned flame-retardant thermoplastic starch material, (B) 60-90 parts by weight of thermoplastic polymer, and (C) 3-10 parts by weight of toughening agent at 170-260 °C, preferably at 190-240 °C to perform a kneading process to form a flame-retardant thermoplastic starch-based biocomposite.

[0033] The flame-retardant thermoplastic starch-based biomass composite material of the present invention includes: (A) 5-40 parts by weight of flam...

Embodiment 1~17

[0040] The preparation methods of the flame-retardant thermoplastic starch-based biomass composites of Examples 1-17 are as follows, and the types and detailed addition ratios of each material component are shown in Table 2 and Table 3.

[0041] 100 parts by weight of starch, 30-70 parts by weight of water, 5-30 parts by weight of glycerin, and 5-30 parts by weight of flame retardants, including organic phosphorus flame retardants (Chemguard-1045, ORGANIC PHOSPHONATE, constant Bridge Industry Co., Ltd., Chembridge International Corp.), triphenyl phosphate (triphenyl phosphate, TPP), phosphate ester flame retardant (Resorcinol bis(dixylenyl phosphate), PX- 200), or the combination of the above, mixed according to the ratio shown in Table 2 and Table 3;

[0042] Chemguard-1045 (CG-1045)

[0043]

[0044] where n is 1.

[0045] Then put the mixed materials into a kneader at 60-100° C. for 30-80 minutes for plasticization and then granulate with a granulator to form a flame-r...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

In one embodiment, A flame-retardant thermoplastic starch material, including (A1) 100 parts by weight of starch; (A2) 5 to 75 parts by weight of plasticizer; and (A3) 5 to 30 parts by weight of organic phosphonate flame-retardant, wherein the organic phosphonate flame-retardant has the following formula (I): wherein X is a trivalent aliphatic hydrocarbon radical containing 3 to 12 carbon atoms; R1 and R2 are independently C1 to C8 alkyl; and n is 0 or 1.

Description

technical field [0001] The invention relates to a flame-retardant thermoplastic starch material (Flame-retardant thermo plastic starch material), its bio-composite and a method for preparing the bio-composite. Background technique [0002] Starch is the main form of energy stored in plants and is found in cereals, legumes and tubers. It is cheap and one of the most abundant natural materials in the earth. It has been widely used in different industrial applications such as food, paper making, textile and adhesives. Native starch is partially crystallized micron-sized particles. The particles are formed by the huge hydrogen bond force between starch molecules to form extended network micelles to form a huge aggregation, making it difficult to melt process, so it cannot be used like ordinary plastic plastic materials. thermoplastic processing. In the past, starch was often used as a plastic filler (Filler), which was added to general plastics to reduce costs and increase the...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C08L3/02C08L3/06C08L3/08C08L69/00C08L55/02C08L67/02C08K5/5357
CPCC08L69/00C08K13/02C09K21/12C08L67/02C08L47/00C08K3/32C08K5/0016C08K5/053C08K5/523C08K5/5357C08L3/02C08L51/06C08L51/085C08L55/02C08L2201/02C08K3/016C08L3/00C08L3/06C08L3/08
Inventor 廖圣茹张志仁钟曜竹简福明陈建明
Owner IND TECH RES INST
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap