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Composite scale and corrosion inhibitor and application thereof in water circulating cooling system

A technology of scale and corrosion inhibitors and circulating cooling water, which is applied in the field of anti-corrosion and scaling, can solve the problems of large sewage discharge, large consumption of chemicals and supplementary water, and pH value lower than 8.5 in the circulating cooling water system, and achieve good anti-corrosion Corrosion and scale inhibition effect, wide application range, good coordination effect

Active Publication Date: 2015-01-21
CHANGSHA RES INST OF MINING & METALLURGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

There are many types of scale and corrosion inhibitors used in industrial circulating cooling water systems, but a single scale and corrosion inhibitor has problems such as low concentration and pH value below 8.5; compound scale and corrosion inhibitors cannot compare It is best to operate at a higher concentration multiple, so that the circulating cooling water system has a large amount of sewage discharge, and the consumption of chemicals and supplementary water are too large

Method used

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  • Composite scale and corrosion inhibitor and application thereof in water circulating cooling system
  • Composite scale and corrosion inhibitor and application thereof in water circulating cooling system
  • Composite scale and corrosion inhibitor and application thereof in water circulating cooling system

Examples

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preparation example Construction

[0037] The present invention has no special limitation on the preparation method of the composite scale and corrosion inhibitor, and the composite scale and corrosion inhibitor can be obtained after uniformly mixing the components described in the above technical solution. In the present invention, it is preferred to mix the components described in the above technical solution in a reactor, and stir evenly to obtain a composite scale and corrosion inhibitor. The present invention has no special limitation on the method of stirring, and the technical solution of stirring well-known to those skilled in the art can be adopted, such as manual stirring, or mechanical stirring, which can make the above-mentioned components mix uniformly.

[0038] The composite scale and corrosion inhibitor provided by the present invention is suitable for use under the conditions of high hardness, pH range of 7.0-9.5 or natural balance of pH value, and has excellent corrosion inhibition effect on equ...

Embodiment 1

[0046] 10kg (10.0wt%) cycloalkylimidazoline, 17kg (17wt%) hydroxyethylidene diphosphonic acid, 15kg (15wt%) β-cyclodextrin, 53.8kg (53.8wt%) water, 3kg (3wt%) ) hydrochloric acid and 1.2kg (1.2wt%) benzotriazole were stirred evenly in a reaction kettle to prepare a composite scale and corrosion inhibitor.

[0047] The present invention adds the compound antiscaling and corrosion inhibitor that this embodiment makes in circulating cooling water, keeps the concentration of compound antiscaling and corrosion inhibitor in circulating water as 10mg / L, detects the performance of this compound antiscaling and corrosion inhibitor, the result is as follows As shown in Table 1, Table 1 is the test results obtained in Example 1 of the present invention.

[0048] Table 1 Embodiment 1 of the present invention obtains detection result

[0049]

[0050]

[0051] As can be seen from Table 1, the scale and corrosion inhibitors prepared in Example 1 are used in circulating cooling water,...

Embodiment 2

[0053] 13kg (13wt%) 1-(2-hydroxyethyl)-1-benzyl-2-tridecyl imidazoline, 20kg (20wt%) amino trimethylene phosphonic acid (ATMP), 10kg (10wt%) β -Cyclodextrin, 1.5kg (1.5wt%) 8-hydroxy-quinoline, 4kg (4wt%) N-methylpyrrolidone and 51.5kg (51.5wt%) water were stirred evenly in a reactor to prepare a composite resistor Scale corrosion inhibitor.

[0054] Add the composite scale and corrosion inhibitor prepared in this example to the circulating cooling water of the simulated nuclear power plant, and keep the concentration of the composite scale and corrosion inhibitor in the circulating water at 50 mg / L. The performance of the composite scale and corrosion inhibitor was tested, and the results are shown in Table 2. Table 2 shows the test results obtained in Example 2 of the present invention.

[0055] Table 2 The detection results obtained in Example 2 of the present invention.

[0056]

[0057] It can be seen from Table 2 that the scale and corrosion inhibitor prepared in th...

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Abstract

The invention provides a composite scale and corrosion inhibitor. The composite scale and corrosion inhibitor comprises the following components: 10wt%-40wt% of imidazoline compounds, 5wt%-35wt% of phosphonic compounds, 10wt%-15wt% of cyclodextrine compounds, 0wt%-5wt% of a copper corrosion inhibition additive and 50wt%-75wt% of auxiliaries. In the invention, the cyclodextrine compounds, the imidazoline compounds and the phosphonic compounds achieve the effect in a synergistic manner, so that obtained composite scale and corrosion inhibitor has higher coordinating effect, and has good corrosion prevention and scale inhibition effect in the water circulating system under a condition that a concentration multiple is large and a pH value is high. Moreover, the composite scale and corrosion inhibitor provided by the invention is wider in scope of application, further can be used in ore pulp water of a concentrating mill, and has better corrosion prevention and scale inhibition effect on an ore pulp water sieve mesh device.

Description

technical field [0001] The invention relates to the technical field of corrosion and scale inhibition, in particular to a composite scale and corrosion inhibitor and its application in a circulating cooling water system. Background technique [0002] The establishment of nuclear power plants is a good way to develop clean energy. Nuclear power plants consume a lot of circulating cooling water. Inland nuclear power plants are the largest water consumers in inland industrial enterprises. The water used for circulating cooling systems accounts for more than 95% of the total water consumption of nuclear power plants. In the prior art, the technical way to reduce the loss of circulating water is to increase the concentration ratio of the circulating cooling water system, but the continuous concentration of circulating cooling water will easily cause scaling and corrosion in the system. When the system is scaled or corroded, it will cause the heat exchange efficiency of the water...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F5/10C02F5/14
Inventor 肖国光曾娟杨国超余侃萍
Owner CHANGSHA RES INST OF MINING & METALLURGY