Composition for forming black matrix, black matrix, display substrate and modification method
A composition and black matrix technology, applied in chemical instruments and methods, dyeing organosilicon compound treatment, nonlinear optics, etc., can solve problems such as uneven friction, complex material composition, and increased gaps on the surface of display substrates, and achieve Enhance the bonding strength, improve the dispersion effect, improve the effect of the display effect
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Embodiment 1
[0040] This embodiment provides a composition for forming the black matrix 3, such as image 3 As shown, carbon black 1 is included. The surface of carbon black 1 has active groups, and the active groups can convert carbon black 1 from an aggregate state to a monodispersed state of nanoparticles.
[0041] Such as Figure 4 As shown, the size range of nanoparticles is 10-100nm.
[0042] In this embodiment, carbon black 1 is modified by a modifier to make its surface carry active groups, and the modifier includes oxidizing acids. Among them, the oxidizing acid is nitric acid, such as Figure 5 As shown, the active groups include carboxyl and nitrate groups. Nitric acid can oxidize carbon black 1, so that the surface of carbon black 1 has carboxyl groups (-COOH) and a small amount of nitrate NO 3 - , The carboxyl group is easy to ionize in water, the carboxyl group can make the surface of carbon black 1 have COO after ionization - Bond, due to COO - Key and NO 3 - They are all negative...
Embodiment 2
[0059] This embodiment provides a composition for forming a black matrix. The difference from Embodiment 1 is that the oxidizing acid is ammonium persulfate and / or sulfuric acid. In this embodiment, such as Figure 7 As shown, the oxidizing acid is sulfuric acid, and the active groups include carboxyl and sulfate groups. Sulfuric acid can oxidize carbon black 1, so that the surface of carbon black 1 has carboxyl groups (COOH) and sulfate groups (SO 4 2- ), the carboxyl group can make the surface of carbon black 1 have COO after ionization - .
[0060] Due to COO - Bond and SO 4 2- They are all negatively charged, so the surface of carbon black 1 can be negatively charged. Based on the principle of mutual repulsion of same-same charges, carbon black 1 can be formed from large-sized micron aggregates under the action of the repulsive force of same-sex charges. The state is converted to a nano-monodispersed state with a smaller particle size, so that the dispersion effect of the car...
Embodiment 3
[0064] This embodiment provides a composition for forming a black matrix. The difference from embodiment 1-2 is that the modifier only includes oxidizing acids and does not include silane coupling agents.
[0065] In this embodiment, although the silane coupling agent is no longer used to modify the carbon black, as long as the carbon black is modified by an oxidizing acid, the surface of the carbon black can carry sufficient charges of the same sex. The carbon black can be converted from the aggregate state to the monodispersed state of nanoparticles, thereby enhancing the dispersion effect of the carbon black in the composition forming the black matrix, and thereby making the light shielding effect of the black matrix more uniform.
[0066] Correspondingly, in the method of modifying carbon black, the modifier also includes only oxidizing acids.
[0067] The other components of the composition and other steps of the modification method in this embodiment are the same as those in Em...
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Abstract
Description
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