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Composition for forming black matrix, black matrix, display substrate and modification method

A composition and black matrix technology, applied in chemical instruments and methods, dyeing organosilicon compound treatment, nonlinear optics, etc., can solve problems such as uneven friction, complex material composition, and increased gaps on the surface of display substrates, and achieve Enhance the bonding strength, improve the dispersion effect, improve the effect of the display effect

Inactive Publication Date: 2016-06-22
BOE TECH GRP CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the currently used black matrix generally has the following two problems: on the one hand, if figure 1 As shown, carbon black 1 particles are easy to agglomerate to form large aggregate particles with larger particle size (the particle size is generally distributed between 1-10 μm) (such as figure 2 shown), so it is usually necessary to add a dispersant to the material forming the black matrix 3, which not only increases the material cost of the black matrix 3, but also makes the composition of the material forming the black matrix 3 more complicated, and the dispersion effect of carbon black 1 is also far away. It is far from the ideal level, which will directly lead to the uneven shading effect of the black matrix 3
[0005] Nowadays, in order to meet the requirements for the shading performance of the black matrix, it is mainly achieved by increasing the amount of carbon black in the black matrix or increasing the thickness of the black matrix. The direct consequence of this is that the surface gap of the display substrate where the black matrix is ​​located increases. The increase of the surface gap will cause a series of problems, such as the control of the position accuracy of the spacer in the display panel, the friction unevenness caused by the gap when the alignment film is formed by rubbing, etc.
On the other hand, in the reliability test of the display panel, it is found that when the test electrode is peeled off, the black matrix and the display substrate (glass substrate) where the black matrix is ​​located are usually separated under the peeling force, which shows that the black matrix Insufficient bond strength with the glass substrate on which it is placed

Method used

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  • Composition for forming black matrix, black matrix, display substrate and modification method
  • Composition for forming black matrix, black matrix, display substrate and modification method
  • Composition for forming black matrix, black matrix, display substrate and modification method

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Embodiment 1

[0040] This embodiment provides a composition for forming the black matrix 3, such as image 3 As shown, carbon black 1 is included. The surface of carbon black 1 has active groups, and the active groups can convert carbon black 1 from an aggregate state to a monodispersed state of nanoparticles.

[0041] Such as Figure 4 As shown, the size range of nanoparticles is 10-100nm.

[0042] In this embodiment, carbon black 1 is modified by a modifier to make its surface carry active groups, and the modifier includes oxidizing acids. Among them, the oxidizing acid is nitric acid, such as Figure 5 As shown, the active groups include carboxyl and nitrate groups. Nitric acid can oxidize carbon black 1, so that the surface of carbon black 1 has carboxyl groups (-COOH) and a small amount of nitrate NO 3 - , The carboxyl group is easy to ionize in water, the carboxyl group can make the surface of carbon black 1 have COO after ionization - Bond, due to COO - Key and NO 3 - They are all negative...

Embodiment 2

[0059] This embodiment provides a composition for forming a black matrix. The difference from Embodiment 1 is that the oxidizing acid is ammonium persulfate and / or sulfuric acid. In this embodiment, such as Figure 7 As shown, the oxidizing acid is sulfuric acid, and the active groups include carboxyl and sulfate groups. Sulfuric acid can oxidize carbon black 1, so that the surface of carbon black 1 has carboxyl groups (COOH) and sulfate groups (SO 4 2- ), the carboxyl group can make the surface of carbon black 1 have COO after ionization - .

[0060] Due to COO - Bond and SO 4 2- They are all negatively charged, so the surface of carbon black 1 can be negatively charged. Based on the principle of mutual repulsion of same-same charges, carbon black 1 can be formed from large-sized micron aggregates under the action of the repulsive force of same-sex charges. The state is converted to a nano-monodispersed state with a smaller particle size, so that the dispersion effect of the car...

Embodiment 3

[0064] This embodiment provides a composition for forming a black matrix. The difference from embodiment 1-2 is that the modifier only includes oxidizing acids and does not include silane coupling agents.

[0065] In this embodiment, although the silane coupling agent is no longer used to modify the carbon black, as long as the carbon black is modified by an oxidizing acid, the surface of the carbon black can carry sufficient charges of the same sex. The carbon black can be converted from the aggregate state to the monodispersed state of nanoparticles, thereby enhancing the dispersion effect of the carbon black in the composition forming the black matrix, and thereby making the light shielding effect of the black matrix more uniform.

[0066] Correspondingly, in the method of modifying carbon black, the modifier also includes only oxidizing acids.

[0067] The other components of the composition and other steps of the modification method in this embodiment are the same as those in Em...

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Abstract

The invention provides a composition for forming a black matrix, the black matrix, a display substrate and a modification method. The composition forming the black matrix comprises carbon black, wherein active groups are formed on the surface of the carbon black and can enable the carbon black to be converted from an aggregation state to a monodisperse state of nanoparticles. According to the composition provided by the invention, by means of the active groups on the surface of the carbon black, the carbon black can be converted into the monodisperse state from the aggregation state, thus the dispersion effect of the carbon black in the composition for forming the black matrix is greatly promoted, and further the light shading effect of the black matrix is more uniform; in addition, the adhesion strength between the black matrix and a glass substrate is greatly enhanced by means of the improved carbon black. According to the composition for forming the black matrix, a dispersing agent and other coupling agents are not needed to be added, and thus the working procedures are reduced and the cost is saved.

Description

Technical field [0001] The present invention relates to the field of display technology, in particular to a black matrix forming composition, a black matrix, a display substrate and a modification method. Background technique [0002] After decades of development, the thin film transistor liquid crystal display (TFT-LCD) has matured in technology and craftsmanship. It has replaced cold cathode diode (CCFL) displays and has become a mainstream product in the display field. [0003] In the TFT-LCD display panel, due to the chaotic electric field at the metal leads (such as gate lines and data lines), thin film transistors, etc., the light transmission is not controlled and cannot be used for display. Therefore, the light at these positions must be blocked. It is necessary to set the black matrix at these positions. [0004] Since carbon black has good light-shielding properties, it is widely used as the main material for forming the black matrix. However, the black matrix currently u...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09C1/48C09C3/06C09C3/12G02F1/1335
Inventor 周永山李建丁金波
Owner BOE TECH GRP CO LTD