Unlock instant, AI-driven research and patent intelligence for your innovation.

Composition for forming black matrix, black matrix, display substrate and modification method

A composition and black matrix technology, applied in chemical instruments and methods, dyed organosilicon compound treatment, nonlinear optics, etc., can solve the problems of increased surface discontinuity of display substrates, complex material composition, uneven friction, etc. Improved display effect, uniform shading effect, and enhanced bonding strength

Inactive Publication Date: 2014-07-16
BOE TECH GRP CO LTD +1
View PDF17 Cites 6 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the currently used black matrix generally has the following two problems: on the one hand, if figure 1 As shown, the carbon black 1 particles are easy to agglomerate to form large aggregate particles with large particle size (the particle size is generally distributed between 1-10 μm) (such as figure 2 shown), so it is usually necessary to add a dispersant to the material forming the black matrix 3, which not only increases the material cost of the black matrix 3, but also makes the composition of the material forming the black matrix 3 more complicated, and the dispersion effect of carbon black 1 is also far away. It is far from the ideal level, which will directly lead to the uneven shading effect of the black matrix 3
[0005] Nowadays, in order to meet the requirements for the shading performance of the black matrix, it is mainly achieved by increasing the amount of carbon black in the black matrix or increasing the thickness of the black matrix. The direct consequence of this is that the surface gap of the display substrate where the black matrix is ​​located increases. The increase of the surface gap will cause a series of problems, such as the control of the position accuracy of the spacer in the display panel, the friction unevenness caused by the gap when the alignment film is formed by rubbing, etc.
On the other hand, in the reliability test of the display panel, it is found that when the test electrode is peeled off, the black matrix and the display substrate (glass substrate) where the black matrix is ​​located are usually separated under the peeling force, which shows that the black matrix Insufficient bond strength with the glass substrate on which it is placed

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Composition for forming black matrix, black matrix, display substrate and modification method
  • Composition for forming black matrix, black matrix, display substrate and modification method
  • Composition for forming black matrix, black matrix, display substrate and modification method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] This embodiment provides a composition for forming a black matrix 3, such as image 3 As shown, including carbon black 1, the surface of carbon black 1 has active groups, and the active groups can make carbon black 1 change from an aggregate state to a monodisperse state of nanoparticles.

[0041] Such as Figure 4 As shown, the size range of the nanoparticles is 10-100 nm.

[0042] In this embodiment, the carbon black 1 is modified by a modifier to have active groups on its surface, and the modifier includes oxidizing acids. Among them, the oxidizing acid is nitric acid, such as Figure 5 As shown, the active groups include carboxyl groups and nitrate groups, and nitric acid can oxidize carbon black 1, so that the surface of carbon black 1 has carboxyl groups (-COOH) and a small amount of nitrate group NO 3 - , the carboxyl group is easy to ionize in water, and the carboxyl group can make the surface of carbon black 1 have COO after ionization. - key, due to COO ...

Embodiment 2

[0059] This embodiment provides a composition for forming a black matrix. The difference from Embodiment 1 is that the oxidizing acids are ammonium persulfate and / or sulfuric acid. In this example, if Figure 7 As shown, the oxidizing acid is sulfuric acid, and the active groups include carboxyl and sulfate groups. Sulfuric acid can oxidize carbon black 1, so that the surface of carbon black 1 has carboxyl groups (COOH) and sulfate groups (SO 4 2- ), the carboxyl group can make the surface of carbon black 1 with COO after ionization - .

[0060] due to COO - key and SO 4 2- Both have negative charges, so the surface of carbon black 1 can be negatively charged. Based on the principle that the same-sex charges repel each other, carbon black 1 can form micron aggregates with larger particle sizes under the action of the same-sex charge repulsion. The state is converted to a nano-monodisperse state with a smaller particle size, so that the dispersion effect of the carbon bla...

Embodiment 3

[0064] This embodiment provides a composition for forming a black matrix. The difference from Embodiment 1-2 is that the modifying agent only includes oxidizing acids and does not include a silane coupling agent.

[0065] In this example, although the silane coupling agent is no longer used to modify the carbon black, as long as the surface of the carbon black can have sufficient same-sex charges after the carbon black is modified by oxidizing acids, the same The carbon black can be converted from an aggregate state to a monodisperse state of nanoparticles, thereby improving the dispersion effect of the carbon black in the composition forming the black matrix, thereby making the shading effect of the black matrix more uniform.

[0066] Correspondingly, in the method for modifying carbon black, the modifying agent only includes oxidizing acids.

[0067] Other compositions of the composition in this example and other steps of the modification method are the same as those in Exam...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
particle sizeaaaaaaaaaa
particle diameteraaaaaaaaaa
Login to View More

Abstract

The invention provides a composition for forming a black matrix, the black matrix, a display substrate and a modification method. The composition forming the black matrix comprises carbon black, wherein active groups are formed on the surface of the carbon black and can enable the carbon black to be converted from an aggregation state to a monodisperse state of nanoparticles. According to the composition provided by the invention, by means of the active groups on the surface of the carbon black, the carbon black can be converted into the monodisperse state from the aggregation state, thus the dispersion effect of the carbon black in the composition for forming the black matrix is greatly promoted, and further the light shading effect of the black matrix is more uniform; in addition, the adhesion strength between the black matrix and a glass substrate is greatly enhanced by means of the improved carbon black. According to the composition for forming the black matrix, a dispersing agent and other coupling agents are not needed to be added, and thus the working procedures are reduced and the cost is saved.

Description

technical field [0001] The invention relates to the field of display technology, in particular to a composition for forming a black matrix, a black matrix, a display substrate and a modification method. Background technique [0002] Thin film transistor liquid crystal display (TFT-LCD) has been developed in recent decades, and its technology and process have become increasingly mature. It has replaced the cold cathode diode (CCFL) display and has become the mainstream product in the display field. [0003] In the display panel of TFT-LCD, due to the confusion of the electric field at metal leads (such as gate lines and data lines), thin film transistors, etc., the light transmission is not controlled and cannot be used for display, so the light at these positions must be blocked. It is necessary to set the black matrix at these positions. [0004] Since carbon black has good light-shielding properties, it is widely used as a main material for forming a black matrix. Howeve...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C09C1/48C09C3/06C09C3/12G02F1/1335
Inventor 周永山李建丁金波
Owner BOE TECH GRP CO LTD