Super-macroporous adsorbent resin and preparation method thereof
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A pore adsorption and resin technology, applied in the field of polymer materials, can solve the problem of small pore size of macroporous adsorption resin, and achieve the effect of providing service life, ensuring mechanical strength, and broadening the application field.
Inactive Publication Date: 2014-09-24
BLUESTAR CHENGDU NEW MATERIALS
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Problems solved by technology
[0007] The purpose of the present invention is to solve the problem that the pore diameter of the macroporous adsorption resin in the prior art is small, and to prov
Method used
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Embodiment 1
[0038] A super-macroporous adsorption resin, comprising the following raw materials in parts by weight:
[0039] 50 parts of divinylbenzene
[0040] Styrene 5 parts
[0041] 10 parts of ethylene glycol dimethacrylate
[0042] 5 parts polystyrene
[0043] Diethyl phthalate 50 parts
[0044] No. 200 gasoline 30 parts
[0045] 1 part dibenzoyl peroxide
[0046] 150 parts of deionized water
[0047] 1 part polyvinyl alcohol.
Embodiment 2
[0049] A super-macroporous adsorption resin, comprising the following raw materials in parts by weight:
[0050] 70 parts of divinylbenzene
[0051] Styrene 10 parts
[0052] 20 parts of ethylene glycol dimethacrylate
[0053] 10 parts polystyrene
[0054] Diethyl phthalate 80 parts
[0055] No. 200 gasoline 50 parts
[0056] 2 parts dibenzoyl peroxide
[0057] 200 parts of deionized water
[0058] 2 parts polyvinyl alcohol.
Embodiment 3
[0060] A super-macroporous adsorption resin, comprising the following raw materials in parts by weight:
[0061] 60 parts of divinylbenzene
[0062] Styrene 7.5 parts
[0063] Ethylene glycol dimethacrylate 15 parts
[0064] 7.5 parts of polystyrene
[0065] 65 parts of diethyl phthalate
[0066] No. 200 gasoline 40 parts
[0067] Dibenzoyl peroxide 1.5 parts
[0068] 175 parts of deionized water
[0069] 1.5 parts of polyvinyl alcohol.
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Abstract
The invention relates to a super-macroporous adsorbent resin and a preparation method thereof, belonging to the field of high polymer materials. The super-macroporous adsorbent resin is prepared from the following raw materials in parts by weight: 50-70 parts of divinylbenzene, 5-10 parts of styrene, 10-20 parts of glycol bis-methacrylate, 5-10 parts of polystyrene, 50-80 parts of diethyl phthalate, 30-50 parts of 200# gasoline, 1-2 parts of diphenyl acyl peroxide, 150-200 parts of deionized water and 1-2 parts of polyvinyl alcohol. The polystyrene and diethyl phthalate used as the pore-forming agent component for preparing the super-macroporous adsorbent resin increase the pore size of the resin and widen the application range of the resin. The second crosslinking agent increases the pore size of the resin, ensures the mechanical strength of the resin and provides the service life of the resin.
Description
technical field [0001] The invention relates to an adsorption resin and a preparation method thereof, more specifically, the invention relates to a super-macroporous adsorption resin and a preparation method thereof, belonging to the technical field of polymer materials. technical background [0002] Macroporous adsorption resin is a kind of polymer adsorption resin with no exchange group and macroporous structure. It has a good macroporous network structure and large specific surface area, and can selectively adsorb organic substances from aqueous solution through physical adsorption. , is a new type of organic polymer adsorbent developed in the 1960s, and has been widely used in environmental protection, food, medicine and other fields. [0003] Macroporous adsorption resin, also known as fully porous adsorption resin, is prepared by polymerizing monomers and additives such as crosslinking agents, porogens, and dispersants through polymerization. After the polymer is form...
Claims
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Application Information
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