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A kind of mg-Al base alloy refinement modification agent and its preparation method and application

A technology for refining modifiers and base alloys, applied in the field of metal material processing, can solve the problems of poor plasticity and strength of as-cast alloys, poor heat treatment strengthening effect of alloys, and easy to grow thick, etc., and achieves improved plasticity and strength. Improve comprehensive mechanical properties and overcome the effect of coarse phase

Active Publication Date: 2016-03-30
河南誉金技术服务有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, Mg-Al alloys have the following disadvantages: during the solidification process, the coarse β-Mg 17 al 12 The phase precipitates along the grain boundary in the form of divorced eutectic, which makes the plasticity and strength of the cast alloy poor. The heat treatment strengthening effect of the alloy is not obvious

Method used

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  • A kind of mg-Al base alloy refinement modification agent and its preparation method and application
  • A kind of mg-Al base alloy refinement modification agent and its preparation method and application
  • A kind of mg-Al base alloy refinement modification agent and its preparation method and application

Examples

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Effect test

Embodiment 1

[0032] Take the rapidly solidified Al-2Ti-B-2Sr strip thinned 1KgAZ91D magnesium alloy as an example.

[0033] Preparation of rapidly solidified Al-2Ti-B-2Sr strips (taking 1Kg as an example):

[0034] 1), the 133gK 2 TiF 6 and 185gK 2 BF 6 Preheat in a drying oven at 100°C for 20 minutes;

[0035] 2) Put 975g of industrial pure aluminum into an intermediate frequency induction furnace and keep warm at 720°C until the pure aluminum is completely melted;

[0036] 3) Raise the temperature to 800°C, put the preheated K 2 TiF 6 and K 2 BF 6 Mix evenly and add to the aluminum melt;

[0037] 4) Heat up to 1000°C and hold for 10 minutes;

[0038] 5) Take 40g of pure strontium out of the kerosene within a few minutes before putting it into the aluminum melt, then clean it with acetone, wrap it tightly with aluminum foil and put it in a drying oven for preheating at 150°C for 3 minutes;

[0039] 6) Cool down to 900°C, add pretreated pure strontium and keep warm for 10 minute...

Embodiment 2

[0051] Take the rapidly solidified Al-5Ti-2B-8Sr strip thinned 1KgAM60B magnesium alloy as an example.

[0052] Preparation of rapidly solidified Al-5Ti-2B-8Sr strips (take 1Kg as an example):

[0053] 1), the 333gK 2 TiF 6 and 375gK 2 BF 6 Preheat in a drying oven at 100°C for 40 minutes;

[0054] 2) Put 875g of industrial pure aluminum into an intermediate frequency induction furnace and heat it at 720°C until the pure aluminum is completely melted;

[0055] 3) Raise the temperature to 900°C, put the preheated K 2 TiF 6 and K 2 BF 6 Mix evenly and add to the aluminum melt;

[0056] 4) Heat up to 1300°C and hold for 30 minutes;

[0057] 5) Take 160g of pure strontium out of the kerosene within a few minutes before putting it into the aluminum melt, then clean it with acetone, wrap it tightly with aluminum foil and put it in a drying oven for preheating at 150°C for 5 minutes;

[0058] 6) Cool down to 1000°C, add pretreated pure strontium and keep it warm for 30 minut...

Embodiment 3

[0069] Take the rapidly solidified Al-3Ti-1.5B-5Sr strip thinning 1KgAM60B magnesium alloy as an example.

[0070] Preparation of rapidly solidified Al-3Ti-1.5B-5Sr strips (take 1Kg as an example):

[0071] 1), the 180gK 2 TiF 6 and 281gK 2 BF 6 Preheat in a drying oven at 100°C for 30 minutes;

[0072] 2) Put 920g of industrial pure aluminum into an intermediate frequency induction furnace and keep warm at 720°C until the pure aluminum is completely melted;

[0073] 3) Raise the temperature to 850°C, put the preheated K 2 TiF 6 and K 2 BF 6 Mix evenly and add to the aluminum melt;

[0074] 4) Heat up to 1200°C and hold for 20 minutes;

[0075] 5) Take 100g of pure strontium out of the kerosene within a few minutes before putting it into the aluminum melt, then clean it with acetone, wrap it tightly with aluminum foil and put it in a drying oven for preheating at 150°C for 5 minutes;

[0076] 6) Cool down to 950°C, add pretreated pure strontium and keep it warm for ...

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Abstract

The invention belongs to the technical field of metal material processing, and in particular relates to a Mg-Al-based alloy refinement modifier and a preparation method and application thereof. The refinement modificator is a rapidly solidified Al-Ti-B-Sr strip, which is composed of Ti: 2-5%, B: 1-2%, Sr: 2-8%, and the rest are aluminum . The present invention has developed a rapid solidification Al-Ti-B-Sr double-effect refinement modifier for magnesium alloys, which can reduce the number of eutectic β-Mg17Al12 phases on the grain boundaries of Mg-Al-based alloys and form a continuous network structure It becomes a banded structure with intermittent distribution, which overcomes the shortcomings of coarse β-Mg17Al12 phase in Mg-Al-based alloys, solves the problem of poor plasticity and strength in as-cast Mg-Al-based alloys, and improves its comprehensive mechanical properties.

Description

technical field [0001] The invention belongs to the technical field of metal material processing, and in particular relates to a Mg-Al-based alloy refinement modifier and a preparation method and application thereof. Background technique [0002] Mg-Al series magnesium alloys are the most widely used magnesium alloys so far, among which AZ91D and AM60B account for 90% of the application of magnesium alloys in automobiles. The strengthening phase of Mg-Al alloy is β-Mg 17 al 12 Mutually. However, Mg-Al alloys have the following disadvantages: during the solidification process, the coarse β-Mg 17 al 12 The phase precipitates along the grain boundary in the form of divorced eutectic, which makes the plasticity and strength of the as-cast alloy poor. The β phase exists in the form of a discontinuous precipitation plate that is not coherent with the matrix, and it is easy to grow very thick. Therefore, The heat treatment strengthening effect of the alloy is not obvious. The...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C21/00C22C1/02C22C1/06
Inventor 王鹏
Owner 河南誉金技术服务有限公司