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Refrigerator with storage battery power supply function and method for preparing battery catalysts

A storage battery and catalyst technology, which is applied in the field of refrigerators with battery power supply function and battery catalyst preparation, can solve the problems of high overvoltage, low catalytic activity of oxygen evolution reaction, low catalytic activity of oxidation-reduction reaction, etc., so as to improve energy efficiency and reduce Side effects, effects of improving stability and activity

Inactive Publication Date: 2014-11-12
JIANGSU SONLU ELECTRICAL APPLIANCE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] First of all, the overvoltage is high, mainly due to the high overvoltage of the oxygen evolution reaction in the discharge process, and RuO2 is a good and efficient catalyst for the oxygen evolution reaction, but its catalytic activity for the redox reaction is low; MnO2 is A better oxygen reduction catalyst, but the catalytic activity of the oxygen evolution reaction is low; therefore, the composite of MnO2-RuO2 can be used as an efficient dual-function catalyst

Method used

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  • Refrigerator with storage battery power supply function and method for preparing battery catalysts

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Embodiment 1

[0025] Such as figure 1 As shown, an embodiment of the present invention has a refrigerator with battery power supply function, including a box body 1, a refrigeration system 2 is arranged in the box, and a battery 3 connected to the refrigeration system and used to supply power to refrigeration; preferably, The storage battery described in this embodiment is a lithium-air battery, and the lithium-air battery includes a MnO2-RuO2 / C catalyst for a lithium-air battery. The active material of the catalyst is MnO2-RuO2, and the carrier is nano-carbon. The MnO2 - The mass percentages of RuO2 and nano-carbon are respectively: MnO2: 5% to 20%, nano-carbon: 25% to 55%, and the remaining content is RuO2.

[0026] According to other embodiments of the present invention, the following embodiments provide the preparation method of MnO2-RuO2 / C catalyst for lithium-air batteries.

Embodiment 2

[0028] Dissolve 0.82g potassium permanganate in 24ml deionized water, and dissolve 0.37g manganese sulfate in 10ml deionized water. Potassium permanganate solution was added dropwise to manganese sulfate solution, fully stirred evenly, hydrothermally reacted in a reaction kettle at 160°C for 12h, filtered and washed 6 times, and dried at 100°C for 12h. Take 0.0545g RuCl3·ⅹH2O, 0.1g multi-walled carbon nanotubes, 0.05g MnO2 dissolved in deionized water, ultrasonically disperse for 0.5h, put the mixed solution into the reaction kettle, react with water at 180℃ for 12h, suction filter, and use Ionized water and ethanol were washed three times respectively, and dried at 100° C. for 8 hours to obtain a multi-walled carbon nanotube catalyst coated with MnO2-RuO2.

Embodiment 3

[0030] Dissolve 0.82g potassium permanganate in 24ml deionized water, and dissolve 0.37g manganese sulfate in 10ml deionized water. Potassium permanganate solution was added dropwise to manganese sulfate solution, fully stirred evenly, hydrothermally reacted in a reaction kettle at 160°C for 12h, filtered and washed 6 times, and dried at 100°C for 12h. Take 0.05g RuCl3·ⅹH2O, 0.1g Super P, 0.05g MnO2 dissolved in deionized water, ultrasonically disperse for 0.5h, put the mixed solution in the reaction kettle, 180°C hydrothermal reaction for 12h, filter with suction, use deionized water respectively, Wash with ethanol three times and dry at 110°C for 8 hours to obtain the MnO2-RuO2 coated Super P catalyst.

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PUM

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Abstract

The invention discloses a refrigerator with a storage battery power supply function. The refrigerator comprises a refrigerator body, a refrigerating system and a storage battery are arranged in the refrigerator body, and the storage battery is connected with the refrigerating system and used for supplying power to the refrigerating system. The storage battery is a lithium air battery, the lithium air battery contains MnO2-RuO2 / C catalysts used for the lithium air battery, an active substance of the catalysts is MnO2-RuO2, a carrier of the catalysts is nanocarbon, and the catalysts comprise, by mass, 5%-20% of MnO2, 25%-55% of the nanocarbon and the balance RuO2. According to the refrigerator, the storage battery is arranged on a common refrigerator, so that the refrigerator can be moved in use. Meanwhile, due to the fact that the nanocarbon is wrapped, the contact probability of the nanocarbon and Li2O2 is reduced, and accordingly side reactions are reduced. Accordingly, energy efficiency of the battery and cycle performance of the battery are improved.

Description

technical field [0001] The invention relates to a refrigerator, in particular to a refrigerator with battery power supply function and a method for preparing a battery catalyst. Background technique [0002] A refrigerator is a kind of refrigeration equipment that keeps a constant low temperature, and it is also a civilian product that keeps food or other items in a constant low temperature and cold state. There are compressors, refrigerators or cabinets for freezing in the box, and storage boxes with refrigeration devices. However, it is usually desired to bring some food or other objects that need to be frozen for a long time during family trips. A travelable refrigerator is the first choice for family trips. However, refrigerators in the prior art all use alternating current, which cannot meet daily needs. As a new type of high-efficiency green and environmentally friendly energy, lithium-air batteries have ultra-high specific capacity, energy density as high as 11140wh / ...

Claims

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Application Information

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IPC IPC(8): F25D11/00H01M4/90B82Y30/00
CPCY02E60/50
Inventor 谢全胜
Owner JIANGSU SONLU ELECTRICAL APPLIANCE
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