Refrigerator with storage battery power supply function and method for preparing battery catalysts
A storage battery and catalyst technology, which is applied in the field of refrigerators with battery power supply function and battery catalyst preparation, can solve the problems of high overvoltage, low catalytic activity of oxygen evolution reaction, low catalytic activity of oxidation-reduction reaction, etc., so as to improve energy efficiency and reduce Side effects, effects of improving stability and activity
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Embodiment 1
[0025] Such as figure 1 As shown, an embodiment of the present invention has a refrigerator with battery power supply function, including a box body 1, a refrigeration system 2 is arranged in the box, and a battery 3 connected to the refrigeration system and used to supply power to refrigeration; preferably, The storage battery described in this embodiment is a lithium-air battery, and the lithium-air battery includes a MnO2-RuO2 / C catalyst for a lithium-air battery. The active material of the catalyst is MnO2-RuO2, and the carrier is nano-carbon. The MnO2 - The mass percentages of RuO2 and nano-carbon are respectively: MnO2: 5% to 20%, nano-carbon: 25% to 55%, and the remaining content is RuO2.
[0026] According to other embodiments of the present invention, the following embodiments provide the preparation method of MnO2-RuO2 / C catalyst for lithium-air batteries.
Embodiment 2
[0028] Dissolve 0.82g potassium permanganate in 24ml deionized water, and dissolve 0.37g manganese sulfate in 10ml deionized water. Potassium permanganate solution was added dropwise to manganese sulfate solution, fully stirred evenly, hydrothermally reacted in a reaction kettle at 160°C for 12h, filtered and washed 6 times, and dried at 100°C for 12h. Take 0.0545g RuCl3·ⅹH2O, 0.1g multi-walled carbon nanotubes, 0.05g MnO2 dissolved in deionized water, ultrasonically disperse for 0.5h, put the mixed solution into the reaction kettle, react with water at 180℃ for 12h, suction filter, and use Ionized water and ethanol were washed three times respectively, and dried at 100° C. for 8 hours to obtain a multi-walled carbon nanotube catalyst coated with MnO2-RuO2.
Embodiment 3
[0030] Dissolve 0.82g potassium permanganate in 24ml deionized water, and dissolve 0.37g manganese sulfate in 10ml deionized water. Potassium permanganate solution was added dropwise to manganese sulfate solution, fully stirred evenly, hydrothermally reacted in a reaction kettle at 160°C for 12h, filtered and washed 6 times, and dried at 100°C for 12h. Take 0.05g RuCl3·ⅹH2O, 0.1g Super P, 0.05g MnO2 dissolved in deionized water, ultrasonically disperse for 0.5h, put the mixed solution in the reaction kettle, 180°C hydrothermal reaction for 12h, filter with suction, use deionized water respectively, Wash with ethanol three times and dry at 110°C for 8 hours to obtain the MnO2-RuO2 coated Super P catalyst.
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