Compound herbicide suitable for planting sesban and alfalfa in Huang-Huai-Hai region

A herbicide and regional technology, applied in the direction of herbicides and algicides, chemicals for biological control, plant growth regulators, etc., can solve the problems of staying in the screening stage, prolonging the efficacy period, and cumbersome processes, etc., to achieve Manufacture and use safety, increase response speed, and reduce environmental pollution

Active Publication Date: 2014-12-24
SHANDONG CROP GERMPLASM CENT +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Comparing the above studies comprehensively, the shortcomings are: (1) The herbicide screening tests were all carried out at the seedling stage (pre-emergence to 5-leaf stage), and there was a lack of research on the entire growth period, especially the pre-emergence, post-emergence to ridge sealing stage , The herbicide research from the ridge sealing period to the pod setting period is not involved; (2) The relevant experiments only stay in the screening stage of the existing herbicides, and the research and development of special herbicides for alfalfa and field greens has not been reported; (3) The experimental treatment They are all single-sprayed, and no compound research has been carried out. In particular, the article "Test of Fourteen Chemical Herbicides on Weeds in Alfalfa Fields in Cangzhou Area" pointed out that "Gramina herbicides or broad-leaved grasses alone in the seedling stage of alfalfa sown in Cangzhou area Herbicides are not working well," but no solution is given
The shortcomings of current related research and application are: (1) When the two are used alone, the drug effect period is prolonged. Cyclohexenone herbicides generally kill weeds in about 10 days, and imidazolinone herbicides generally kill weeds in about 20 days. (2) The research on the mixed use of the two has not been reported or made public; (3) The dosage form of cyclohexenone herbicides is mainly emulsifiable concentrate, which causes serious environmental pollution; (4) The dosage form of imidazolinone herbicides is water Cyclohexenone herbicides are mainly herbicides, and the solubility of cyclohexenone herbicides is poor, and there is no research and development of mixed formulations
[0010] Comprehensively comparing the above studies, the shortcomings of the current research and development of biochemical fulvic acid are: (1) Although the fermentation process is relatively simple, there are fermentation microorganisms that are easily affected by the external environment, unstable activity, long fermentation time, low efficiency, and harmful Bacterial growth and other issues
(2) Although the currently disclosed oxidation method shortens fermentation 60d-90d to oxidation 18d-36d, there are still shortcomings such as complex equipment, cumbersome process, high energy consumption, high cost, and low efficiency.
(3) Although the fulvic acid prepared by the sulfuric acid acetone method has high purity, the preparation process is too complicated, and there are problems such as strong acid and strong alkali pollution and high equipment requirements
In addition, water-soluble carbohydrates, amino acids, proteins, sugar and acid substances, etc. are discarded, and the biological activity of the product is not as good as that of fermentation and oxidation.
(4) The finished fulvic acid is generally used in the currently disclosed herbicides, and the cost is high, and the application of biochemical fulvic acid in herbicides has not been reported or disclosed

Method used

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  • Compound herbicide suitable for planting sesban and alfalfa in Huang-Huai-Hai region
  • Compound herbicide suitable for planting sesban and alfalfa in Huang-Huai-Hai region
  • Compound herbicide suitable for planting sesban and alfalfa in Huang-Huai-Hai region

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] A compound herbicide, the raw material composition is: biochemical fulvic acid 4wt%, imazamox 4wt%, clethodim 1wt%, and auxiliary agent 91wt%. The preparation method is as follows:

[0046] (1) Naturally dry the edible fungus residue or wood residue to a moisture content of less than 15%, and pulverize to a particle diameter of 0.1-0.3mm; add 15wt% peroxide in 5 equal amounts according to the ratio of 1:3 (w / v) Hydrogen, and after adding hydrogen peroxide for the first time, add the catalyst manganese dioxide at a ratio of 20:1 (v / w), stir fully for 6-8h until the foam disappears; let it stand for more than 24h, and spray dry the liquid after solid-liquid separation , That is, biochemical fulvic acid.

[0047] (2) Dissolve clethodim 1wt%, xylene 1wt%, Termul 2002wt%, Termul 12833wt%, butanol 1wt% into a homogeneous oil phase, and add them to a reactor with a high-shear emulsifier; Smoke 4wt%, biochemical fulvic acid 4wt%, polyvinyl alcohol 2wt%, ethylene glycol 5wt%, organ...

Embodiment 2

[0059] A compound herbicide, the raw material composition is: biochemical fulvic acid 8wt%, imazamox 4wt%, clethodim 3wt%, and adjuvant 85wt%. The preparation method is as follows:

[0060] (1) The furfural residue or xylose residue is naturally dried to a water content of less than 15%, and crushed to a particle diameter of 0.1-0.3 mm. Add 15wt% hydrogen peroxide in 4 equal amounts according to the ratio of 1:2 (w / v), and add the catalyst manganese dioxide at a ratio of 30:1 (v / w) after the first addition of hydrogen peroxide, and stir thoroughly 6h-8h until the foam disappears. Let it stand fully for more than 24 hours, and spray dry the liquid after solid-liquid separation to obtain biochemical fulvic acid.

[0061] (2) Add clethodim 3wt%, xylene 3wt%, PE 640010wt%, ethanol 5wt% into a reaction kettle with stirring function, dissolve and mix to obtain a transparent oil phase; mix imazamox 4wt%, biochemical yellow Humic acid 8wt%, ethylene glycol 5wt%, Alkanate CS 10wt% are di...

Embodiment 3

[0073] A compound herbicide, the raw material composition is: biochemical fulvic acid 5wt%, imazamox 4wt%, clethodim 5wt%, and adjuvant 86wt%. The composition of the auxiliary agent is: xylene 5wt%, Termul 2002wt%, Termul 12833wt%, butanol 1wt%, polyvinyl alcohol 2wt%, ethylene glycol 5wt%, organosilicone 0.05wt%, water balance. The preparation method is the same as in Example 1.

[0074] The compound herbicide of Example 3 is 1800ml / hm 2 Dosage, add water 225kg / hm 2 After fully stirring, after 16:00 in the sealing period of Sesbania and Alfalfa, and there is no rainfall within 8 hours after the medicine, spray uniformly according to conventional techniques in the field.

[0075] Field test results of Example 3:

[0076] Comparative Example: Same as the comparative example of Example 1, and the dosages of clethodim, imazamox, biochemical fulvic acid, clethodim + imazamox, and water are the same as in Example 3.

[0077] The test location, test setup and test time are the same as thos...

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Abstract

The invention discloses a compound herbicide suitable for planting sesban and alfalfa in the Huang-Huai-Hai region. The compound herbicide is prepared by producing biochemical fulvic acid by using fungi residue, wood residue, furfural residue, corn cob residue and the like, and compounding basic materials including biochemical fulvic acid, a cyclohexenone herbicide and an imidazolone herbicide. All the components of the compound herbicide are obvious in a synergistic effect; the compound herbicide is simple in processing technology, low in cost and remarkable in economic and ecological benefits, thus belonging to an environment-friendly herbicide.

Description

Technical field [0001] The invention relates to the field of herbicide preparation, in particular to the use of biochemical fulvic acid, cyclohexenone herbicides, imidazolinone herbicides and the like to produce a compound herbicide suitable for planting sesame and alfalfa in the Huanghuaihai area. Background technique [0002] Sesbania and alfalfa are currently the main green manure crops grown in the Huanghuaihai area. In recent years, driven by the adjustment of agricultural structure, the development of deep processing industries, returning farmland to grassland and grassland rotation projects, the planting area has expanded year by year. However, affected by the traditional planting industry layout and policies, the production bases of Sesbania and Alfalfa in the Huanghuaihai area are mostly distributed in low-yield fields, coastal areas or along the Yellow Beach, where the soil is barren and the weeds are serious. However, due to the lack of special herbicides, growers are...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): A01N61/00A01P13/00A01P21/00A01N43/50A01N35/10
Inventor 张晓冬隋学艳丁汉凤盛亦兵陈恩昌刘世华李润芳王栋李湛李娜娜辛富刚王存娥
Owner SHANDONG CROP GERMPLASM CENT
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