Preparation of coated sand by use of phosphate inorganic binder and molding method thereof

An inorganic binder and phosphate technology, applied in casting molding equipment, casting molds, cores, etc., can solve the problems of large gas generation, low high-temperature strength, and large resin odor of sand molds, and achieve wide range of raw material resources and wide application Foreground, fast hardening effect

Active Publication Date: 2015-01-21
HUBEI UNIV OF TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] One is that the resin has a strong smell, not only in the preparation stage of coated sand, but also when the coated sand is used for molding, the sand mold is heated and solidified, and it is easier to emit an unpleasant smell. Very poor, seriously harming the health of workers;
[0005] The second is that the sand mold generates a large amount of gas during pouring, which can easily cause gas defects in the casting;
[0006] The third is that the high temperature resistance of organic resin coated sand is poor, and the high temperature strength is low;
[0007] Fourth, the recycling performance of coated sand is poor;
[0008] Fifth, the casting of organic resin coated sand is more costly than other sand casting
However, the coated sand prepared by this method has poor collapsibility, and it is difficult to reuse the old sand. In fact, there is no development prospect and cannot be popularized.
[0010] In summary, there is no new type of binder-coated sand that can overcome the defects of existing coated sand products.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] The preparation method of the phosphate inorganic binder: first disperse toothpaste grade aluminum hydroxide in water for later use. During synthesis, first heat 85% phosphoric acid to the boiling temperature, and then slowly add the dispersed aluminum hydroxide gradually In the boiling phosphoric acid, stir while adding, and continue heating until the reaction is over, the solution is transparent; then slowly add borax, after the addition is complete, until the reaction is over, the solution is transparent; finally add magnesium chloride slowly, after the addition, until the reaction is over , The solution is transparent. The molar ratio of boron to phosphorus in the phosphate inorganic binder is 0.07:1, the molar ratio of boron to aluminum is 0.2:1, the molar ratio of magnesium to phosphorus is 0.08:1, and the molar ratio of magnesium to aluminum is 0.23:1 .

[0029] Preparation method of phosphate inorganic binder coated sand:

[0030] 1) Weigh 40 grams of the above-pre...

Embodiment 2

[0039] The preparation method of the phosphate inorganic binder: first disperse toothpaste grade aluminum hydroxide in water for later use. When synthesizing, first heat 85% phosphoric acid to the boiling temperature, and then slowly add the dispersed aluminum hydroxide gradually In the boiling phosphoric acid, stir while adding, and continue heating until the reaction is over, the solution is transparent; then slowly add borax, after the addition is complete, until the reaction is over, the solution is transparent; finally add magnesium chloride slowly, after the addition, until the reaction is over , The solution is transparent. The molar ratio of boron to phosphorus in the phosphate inorganic binder is 0.08:1, the molar ratio of boron to aluminum is 0.25:1, the molar ratio of magnesium to phosphorus is 0.1:1, and the molar ratio of magnesium to aluminum is 0.3:1 .

[0040] Preparation method of phosphate inorganic binder coated sand:

[0041] 1) Weigh 35 grams of the phosphate...

Embodiment 3

[0050] The preparation method of the phosphate inorganic binder: first disperse toothpaste grade aluminum hydroxide in water for later use. During synthesis, first heat 85% phosphoric acid to the boiling temperature, and then slowly add the dispersed aluminum hydroxide gradually To the boiling phosphoric acid, stir while adding, and continue heating until the reaction is over, the solution is transparent; then slowly add borax until the reaction is over, the solution is transparent; finally add magnesium chloride slowly, and after the addition, until the reaction is over , The solution is transparent. The molar ratio of boron to phosphorus in the phosphate inorganic binder is 0.10:1, the molar ratio of boron to aluminum is 0.3:1, the molar ratio of magnesium to phosphorus is 0.12:1, and the molar ratio of magnesium to aluminum is 0.35:1.

[0051] Preparation method of phosphate inorganic binder coated sand:

[0052] 1) Weigh 50 grams of the phosphate inorganic binder prepared abov...

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Abstract

The invention discloses preparation of coated sand by the use of a phosphate inorganic binder and a molding method thereof. Preparation of the coated sand comprises the following steps: uniformly mixing the phosphate inorganic binder and quartz sand; heating and drying to a semi-dry state; adding calcium stearate with the granularity being 600 meshes and uniformly mixing; and drying and cooling so as to obtain the phosphate inorganic binder coated sand which is in a dry arenaceous state. During molding of the coated sand, the coated sand undergoes hydration only by high temperature steam, the binder is dissolved, sand grains are connected, and finally hot-air is blown for drying and curing molding. The hardening speed is fast. During preparation and curing molding of the coated sand, smell or any harmful gas or substance is not generated. The sand mould has low gas-forming property, is harmless to the health of workers, causes no pollution to the environment and is energy-saving and environmentally friendly. The coated sand provided by the invention has characteristics of high strength, high temperature resistance, low gas evolution, no curing agent required for molding and good storage stability.

Description

Technical field [0001] The invention relates to a preparation method of coated sand, in particular to a preparation method of phosphate inorganic binder coated sand and its forming method. Background technique [0002] Coated sand refers to molding sand or core sand whose surface is covered with a layer of cured resin film before modeling. As an approximate precision casting molding method, coated sand casting has the advantages of simplified process, short molding cycle and low cost compared with lost wax casting methods, making coated sand casting widely used. [0003] In a large number of patents and other documents on coated sand, the binder of coated sand is mostly organic phenolic resin. However, the use of organic phenolic resin as the binder of coated sand has the following problems: [0004] First, the resin has a strong smell, which not only has an odor during the preparation stage of the coated sand, but also when the coated sand is used for modeling, the sand mold is cur...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B22C1/18
CPCB22C1/185
Inventor 张友寿夏露李四年黄晋吴祥忠
Owner HUBEI UNIV OF TECH
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