Production method for preparing tripotassium phosphate and by-producing special fertilizer for litchi

A technology of tripotassium phosphate and its production method, which is applied in the direction of chemical instruments and methods, applications, phosphorus compounds, etc., can solve the problems of poor purity of tripotassium phosphate products, achieve significant environmental protection value and economic benefits, reduce production costs, and significantly economical benefit effect

Inactive Publication Date: 2015-01-21
GUIZHOU KAILIN GRP CO LTD +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Moreover, in the preparation process of tripotassium phosphate products, the product is usually obtained by crystallization after the reaction of phosphoric acid and potassium components, but often in order to reduce the waste of raw materials and increase the output of the product, the reaction solution will be deeply crystallized, thereby making the solution Phosphorus and potassium elements are separated out in the form of tripotassium phosphate, but this deep crystallization tends to precipitate other impurity products. There are many impurities, so some researchers use urea phosphate as an intermediate to convert and prepare tripotassium phosphate products, but such conversion still cannot avoid the impurity problem caused by deep crystallization, but only phosphoric acid products prepared by wet-process phosphoric acid However, the purity of the tripotassium phosphate product is still poor at the same time as the deep crystallization, because it will also be accompanied by the precipitation of other phosphate products, resulting in tripotassium phosphate The purity of the product is poor

Method used

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  • Production method for preparing tripotassium phosphate and by-producing special fertilizer for litchi
  • Production method for preparing tripotassium phosphate and by-producing special fertilizer for litchi
  • Production method for preparing tripotassium phosphate and by-producing special fertilizer for litchi

Examples

Experimental program
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Effect test

Embodiment 1

[0048] A production method for preparing special fertilizer for litchi by-product of tripotassium phosphate,

[0049] (1) Preparation of intermediate slurry: Put phosphoric acid and carbonamide into a stirred reactor at a molar ratio of 1.95:1, and control the reaction temperature at 92°C, and stir for 20 minutes at a constant stirring speed of 50 r / min. Obtain intermediate slurry;

[0050] (2) Add potassium hydroxide: to step 1) prepare and obtain intermediate slurry and add potassium hydroxide, the concentration of the potassium hydroxide added is 30%, and the addition is 2 times of carbonamide addition, and control temperature of reaction is At 40°C, stir and react at a stirring speed of 35r / min for 30min to obtain tripotassium phosphate slurry;

[0051] (3) Crystallization separation: the tripotassium phosphate slurry obtained in step 2) is cooled and crystallized in a reactor, the temperature during cooling and crystallization is 30°C, and the content of nitrogen, phosph...

Embodiment 2

[0056] A production method for preparing special fertilizer for litchi by-product of tripotassium phosphate,

[0057] (1) Preparation of intermediate slurry: put phosphoric acid and carbonamide into a stirred reactor at a molar ratio of 2.05:1, and control the reaction temperature to 102°C, and stir at a constant stirring speed of 70r / min for 30min. Obtain intermediate slurry;

[0058] (2) Add potassium hydroxide: to step 1) prepare and obtain intermediate slurry and add potassium hydroxide, the concentration of the potassium hydroxide added is 30%, and the addition is 3 times of carbonamide addition, and control temperature of reaction is At 80°C, stir and react at a stirring speed of 40r / min for 60min to obtain tripotassium phosphate slurry;

[0059] (3) Crystallization separation: the tripotassium phosphate slurry obtained in step 2) is cooled and crystallized in a reactor, and the temperature during cooling and crystallization is 28° C., and the content of nitrogen, phosp...

Embodiment 3

[0064] A production method for preparing special fertilizer for litchi by-product of tripotassium phosphate,

[0065] (1) Preparation of intermediate slurry: put phosphoric acid and carbonamide into a stirred reactor at a molar ratio of 2:1, and control the reaction temperature at 98°C, and stir at a constant stirring speed of 60r / min for 25min. Obtain intermediate slurry;

[0066] (2) Add potassium hydroxide: to step 1) prepare and obtain intermediate slurry and add potassium hydroxide, the concentration of the potassium hydroxide added is 30%, and the addition is 2.5 times of carbonamide addition, and control temperature of reaction is At 60°C, stir and react at a stirring speed of 38r / min for 45min to obtain tripotassium phosphate slurry;

[0067] (3) Crystallization separation: the tripotassium phosphate slurry obtained in step 2) is cooled and crystallized in a reactor, and the temperature during cooling and crystallization is 25° C., and the content of nitrogen, phospho...

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Abstract

The invention relates to the technical field of chemical industry, and particularly relates to a production method for preparing tripotassium phosphate and by-producing a special fertilizer for litchi. According to the production method, the effective absorption amount of nitrogen, phosphorus and potassium elements is analyzed according to the fertilizer requirement of litchi, and element content is regulated and collocated in a production process course, so that a prepared compounded-form compound fertilizer can furthest meet the requirement of the litchi, excessively high cost caused due to improper element collocation in the production of the compound fertilizer is reduced, and environmental pollution caused by that the compound fertilizer is solidified by adding excessive elements to soil is further prevented; and the impurity removal cost needed when a tripotassium phosphate product is prepared by adopting the traditional wet-process phosphoric acid method is made up, so that the purity of the prepared tripotassium phosphate product reaches more than 95%, the production cost is reduced by 93%, and outstanding economic benefit is achieved.

Description

technical field [0001] The invention relates to the technical field of chemical industry, in particular to a production method for preparing special fertilizer for litchi by-product of tripotassium phosphate. Background technique [0002] Although litchi is a long-lived fruit tree, it is a kind of fruit tree. In its traditional planting technology, the fertilizer requirements of litchi are divided into different ages such as juvenile, mature and old, and different nitrogen and phosphorus are applied according to the different ages of litchi trees. Potassium fertilizers are usually made of heavy superphosphate, potassium dihydrogen phosphate, urea, etc. as raw materials according to a certain amount of ratio to meet the growth needs of litchi, and in the process of preparation, some urine, poultry, etc. will also be added. Manure is added as an additive, but for this traditional compound fertilizer applied to the soil, the amount that can only be absorbed is about 15-20% of n...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B25/30C05G1/00
Inventor 廖吉星陈肖虎魏发展高贵龙石秀明薛涛彭宝林何敏朱飞武
Owner GUIZHOU KAILIN GRP CO LTD
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