Steel plate resistant to sulfuric acid dew point corrosion and manufacturing method for steel plate

A technology of dew point corrosion and manufacturing method, applied in the direction of temperature control, etc., can solve problems such as inability to meet requirements, low yield ratio, etc., and achieve the effect of increasing yield strength, increasing strength, and wide application range

Active Publication Date: 2015-02-18
JIANGYIN XINGCHENG SPECIAL STEEL WORKS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The disadvantage is that the yield strength of the sulfuric acid dew-point corrosion-resistant steel involved in this patent is too large to reach more than 690MPa, resulting in an excessively high yield ratio (yield strength/tensile strength) of the sulfuric acid dew-point corrosi

Method used

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  • Steel plate resistant to sulfuric acid dew point corrosion and manufacturing method for steel plate
  • Steel plate resistant to sulfuric acid dew point corrosion and manufacturing method for steel plate
  • Steel plate resistant to sulfuric acid dew point corrosion and manufacturing method for steel plate

Examples

Experimental program
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Effect test

Embodiment 1

[0037] The thickness of the sulfuric acid dew-point corrosion-resistant steel plate involved in this example is 32 mm, and its chemical composition is calculated by mass percentage: C: 0.07%, Si: 0.32%, Mn: 1.16%, P: 0.010%, S: 0.003%, Cr : 0.46%, Ni: 0.19%, Cu: 0.35%, Al: 0.028%, V: 0.026%, Nb: 0.032%, Ti: 0.013%, Ca: 0.0006%, N: 0.0059%, balance For iron and inevitable impurity elements.

[0038] The manufacturing process of the 32mm thick sulfuric acid dew point corrosion resistant steel plate is as follows: according to the chemical composition of the above sulfuric acid dew point corrosion resistant steel plate, the smelting raw materials are sequentially subjected to KR molten iron pretreatment, converter smelting, LF refining, and RH vacuum degassing to obtain high purity. The molten steel is then continuously cast into a continuous casting slab with a thickness of 150mm by the continuous casting machine. Heat the continuous casting slab to 1220°C and hold it for 2.5 h...

Embodiment 2

[0043] The thickness of the sulfuric acid dew point corrosion-resistant steel plate involved in this example is 19mm, and its chemical composition is calculated by mass percentage: C: 0.08%, Si: 0.38%, Mn: 1.07%, P: 0.011%, S: 0.002%, Cr : 0.52%, Ni: 0.25%, Cu: 0.40%, Al: 0.032%, V: 0.028%, Nb: 0.036%, Ti: 0.014%, Ca: 0.0009%, N: 0.0024%, and the balance is iron and unavoidable impurity elements.

[0044] The manufacturing process of the 19mm thick sulfuric acid dew point corrosion resistant steel plate is that the smelting raw materials are configured according to the chemical composition of the above sulfuric acid dew point corrosion resistant steel plate, followed by KR molten iron pretreatment, converter smelting, LF refining, and RH vacuum degassing to obtain high purity. The molten steel is then continuously cast into a continuous casting slab with a thickness of 150mm by the continuous casting machine. The continuous casting slab is heated to 1200°C and held for 2.2 ho...

Embodiment 3

[0048] The thickness of the sulfuric acid dew point corrosion-resistant steel plate involved in this example is 10mm, and its chemical composition is calculated by mass percentage: C: 0.06%, Si: 0.32%, Mn: 1.19%, P: 0.009%, S: 0.003%, Cr : 0.45%, Ni: 0.20%, Cu: 0.42%, Al: 0.034%, V: 0.031%, Nb: 0.036%, Ti: 0.015%, Ca: 0.0008%, N: 0.0036%, and the balance is iron and unavoidable impurity elements.

[0049] The manufacturing process of the 10mm thick sulfuric acid dew point corrosion resistant steel plate is that the smelting raw materials are configured according to the chemical composition of the above sulfuric acid dew point corrosion resistant steel plate, followed by KR molten iron pretreatment, converter smelting, LF refining, and RH vacuum degassing to obtain high purity. The molten steel is then continuously cast into a continuous casting slab with a thickness of 150mm by the continuous casting machine. The continuous casting slab is heated to 1200°C and held for 2.6 ho...

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Abstract

The invention discloses a strong-strength and low-yield ratio steel plate resistant to sulfuric acid dew point corrosion and a manufacturing method for the steel plate. The steel plate comprises the following chemical components in percentage by mass: 0.06 to 0.10 percent of C, 0.15 to 0.50 percent of Si, 0.90 to 1.20 percent of Mn, less than or equal to 0.012 percent of P, less than or equal to 0.008 percent of S, 0.40 to 0.70 percent of Cr, 0.15 to 0.45 percent of Ni, 0.20 to 0.50 percent of Cu, 0.02 to 0.04 percent of Al, 0.02 to 0.05 percent of V, 0.015 to 0.04 percent of Nb, 0.01 to 0.02 percent of Ti, 0.0005 to 0.005 percent of Ca, less than or equal to 0.007 percent of N and the balance of Fe and inevitable impurity elements. The steel plate resistant to sulfuric acid dew point corrosion is directly manufactured by a continuous casting billet of 150mm or more, and the manufacturing method comprises the following steps of heating the continuous casting billet to 1,180 to 1,230 DEG C, preserving heat for 2 to 3 hours, performing rolling after high-pressure water scale removal, cooling the continuous casting billet to 500 to 620 DEG C at the cooling speed of 7 to 15 DEG C/s, and performing straightening and cooling to obtain the steel plate resistant to sulfuric acid dew point corrosion. According to the steel plate and the manufacturing method, a trace amount of Ca, and Nb and V favorable for improving the toughness of steel are added on the basis of Cu-Cr-Ni-Ti anticorrosion, and the content of each element is reasonably set, so that the strength and toughness of the steel are improved on the basis of ensuring the resistance of the steel to the sulfuric acid dew point corrosion, and the yield ratio is lowered.

Description

technical field [0001] The invention belongs to a steel plate for sulfuric acid dew point corrosion resistance and a manufacturing method thereof, in particular to a sulfuric acid dew point corrosion resistant steel plate with a yield strength of 500 MPa, low yield ratio and high toughness, and a manufacturing method thereof. Background technique [0002] Sulfuric acid dew point corrosion will cause great damage to the equipment in metallurgy, electric power, petroleum and chemical flue gas treatment systems that use coal or heavy oil as the main fuel. Non-metallic coatings can be used to avoid sulfuric acid dew point corrosion of components to a certain extent. However, the construction is difficult and affects the heat transfer efficiency at the same time. The most ideal solution to this problem is to use steel with sulfuric acid dew point corrosion resistance in the environment of sulfuric acid dew point corrosion. [0003] At present, the steels resistant to sulfuric a...

Claims

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Application Information

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IPC IPC(8): C22C38/50B21B37/74
CPCC21D8/0226C22C38/02C22C38/04C22C38/08C22C38/12C22C38/16C22C38/18
Inventor 苗丕峰刘观猷李国忠吴小林李经涛赵孚
Owner JIANGYIN XINGCHENG SPECIAL STEEL WORKS CO LTD
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