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Salt-free pickling two-step chrome tanning process

A salt-free pickling and chrome tanning technology, applied in small raw hide/large raw hide/leather/fur treatment, tanning treatment, small raw hide/large raw hide/leather hide/fur chemical treatment, etc. Secondary pollution and other problems, to avoid the use of neutral salt, fine grain, reduce the content of neutral salt

Active Publication Date: 2015-06-24
SHAANXI UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The development of new pickling aids provides an effective way to achieve no (less) salt, but there are also certain shortcomings. The use of pickling aids may introduce new toxic and harmful substances, which may cause secondary pollution. Bring new difficulties to the treatment of subsequent wastewater, etc.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0014] A two-step chrome tanning process without salt pickling, comprising the following steps:

[0015] 1) After washing the softened limed leather, put it into the drum for the first step of tanning, add 100% water of the weight of the limed hide, and then add SF-1 with 2% weight of the limed hide Chrome powder tanning agent, at a temperature of 22°C, rotate for 2 hours;

[0016] 2) Add the diluted formic acid or sulfuric acid solution to the first step tanning bath solution in batches and adjust the pH of the bath solution to 2.2 within 30 minutes, and rotate for 2 hours at 22°C; then carry out the second step tanning and add liming 33% chrome powder with a tare weight of 4% alkalinity, at a temperature of 22°C, rotate for 2 hours; then use 2.2% sodium bicarbonate of liming tare weight to prepare an aqueous solution with a concentration of 10%, and add it in 6 times, with an interval of 20 minutes between each time. When the pH reaches 4.0, rotate for 1 hour, add 150% of t...

Embodiment 2

[0019] A two-step chrome tanning process without salt pickling, comprising the following steps:

[0020] 1) After washing the softened limed leather, put it into the drum for the first step of tanning, add water with 100% weight of the limed hide, make the grayed hide pigskin, and then add 2.5% SF- 1 chrome powder tanning agent, rotate for 3 hours at a temperature of 20°C;

[0021] 2) Add the diluted formic acid or sulfuric acid solution to the first step tanning bath solution in batches and adjust the pH of the bath solution to 3.0 within 30 minutes, and rotate for 1 hour at 20°C; then carry out the second step tanning and add liming 33% chrome powder with a tare weight of 3.5% alkalinity, at a temperature of 20°C, rotate for 2 hours; then use 1.8% baking soda with a liming tare weight to prepare an aqueous solution with a concentration of 10%, and add it in 6 times, with an interval of 20 minutes each time. Adjust the pH to 3.8, rotate for 1 hour, add 150% of the weight of ...

Embodiment 3

[0024] A two-step chrome tanning process without salt pickling, comprising the following steps:

[0025] 1) After the delimed and softened limed hide is washed with water, put it into the drum for the first step of tanning, add water with 100% weight of the limed hide, make the limed hide into sheepskin, and then add SF-1 with 3% weight of the limed hide Chrome powder tanning agent, at a temperature of 25°C, rotate for 4 hours;

[0026] 2) Add the diluted formic acid or sulfuric acid solution to the first step tanning bath solution in batches and adjust the pH of the bath solution to 3.0 within 30 minutes, and rotate for 2 hours at 25°C; then carry out the second step tanning and add liming 33% chrome powder with 3% alkalinity in tare weight, at a temperature of 25°C, rotate for 2 hours; then use baking soda with 2.2% liming tare weight to prepare an aqueous solution with a concentration of 10%, and add it in 6 times with an interval of 20 minutes each time. Adjust the pH to ...

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PUM

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Abstract

The invention provides a salt-free pickling two-step chrome tanning process. The process comprises the following steps: firstly pre-tanning softened leather by using an SF-1 tanning agent; and performing salt-free pickling and conventional chrome tanning. According to the process flow, usage of edible salt is completely avoided, the prepared wet-blue leather has pure color, fine grain side and soft leather body, usage of neutral salt is avoided in pickling, and thus the content of neutral salt in tanning waste water is greatly reduced.

Description

technical field [0001] The invention relates to the technical field of clean ecological tanning, in particular to a two-step chrome tanning process without salt pickling. Background technique [0002] Pickling is a very critical process before conventional chrome tanning. Good pickling can make the chrome tanning agent penetrate into the collagen fiber matrix smoothly. When pickling, it is necessary to add about 8% neutral salt to inhibit the expansion of collagen in acidic medium. The resulting high-concentration salt-containing tannery wastewater is a serious environmental problem. In order to achieve the sustainable development of the leather industry For the purpose, the cleanliness of tanning is also imperative, and salt-free pickling is an important part of it. [0003] In recent years, as far as domestic research is concerned, Feng Lianxiang and others have synthesized a new type of salt-free pickling additive by using organic sulfonic acid compounds, disodium EDTA, ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C14C3/28
CPCC14C3/06C14C3/28
Inventor 强西怀陈兴幸张辉陈渭刘璐吴淼江王亚辉张莹
Owner SHAANXI UNIV OF SCI & TECH