All-biodegradable modified polylactic acid film-blowing resin and preparation method thereof

A technology of biodegradation and polylactic acid, which is applied in the field of modified polylactic acid blown film grade resin and its preparation, can solve the problems of material tension reduction, cost increase, ductility reduction, etc., and achieve good processing performance and cost reduction.

Inactive Publication Date: 2015-09-30
广东华芝路生物材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] With the improvement of people's living standards, the requirements for the environment are getting higher and higher. At the same time, countries are paying more and more attention to the protection of the environment. Plastic is a very common material in daily life and industrial production. The degradation rate is very slow, even non-degradable, resulting in white pollution. In this regard, there are more and more researches and developments on biodegradable resins. At present, there are also many degradable materials produced and used in some daily life Among them, such as garbage bags, shopping bags, etc., are generally degradable materials (such as photodegradation, oxidative degradation, etc.), although they bring the excellent performance of degradability, but at the same time sacrifice many physical properties, the cost is also

Method used

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  • All-biodegradable modified polylactic acid film-blowing resin and preparation method thereof
  • All-biodegradable modified polylactic acid film-blowing resin and preparation method thereof
  • All-biodegradable modified polylactic acid film-blowing resin and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0025] Example 1

[0026] A completely biodegradable modified polylactic acid blown film grade resin, in terms of weight percentage, the modified polylactic acid blown film grade resin is made from the following components:

[0027]

[0028]

[0029] Prepared as follows:

[0030] In step 1, the polylactic acid (PLA), polyadipate / butylene terephthalate (PBAT), polypropylene carbonate resin (carbon dioxide-based material PPC), talc, ethylene-acrylic acid copolymer, PE Add the wax into the low-speed mixer for stirring and mixing, and then add the required percentage of chain extender, erucamide, zinc stearate (Zist), melt enhancer, anti-hydrolysis stabilizer, and then transfer to the high-speed mixer. After stirring and mixing, the mixture can be obtained;

[0031] Step 2, the mixture in step 1 is stirred in separate pots according to 150-250kg, and the stirring time of each pot is 8-10 minutes, and no heating is required during stirring. The temperature must be kept bel...

Example Embodiment

[0035] Example 2

[0036] The difference between this example and Example 1 is that the composition ratio of the modified polylactic acid blown film grade resin is different. In terms of weight percentage, the modified polylactic acid blown film grade resin of this embodiment is composed of the following components production:

[0037]

[0038] The modified polylactic acid blown film grade resin provided in this example is used to make a film product, which is stored for 18 months at a normal temperature of 23°C without change; the biodegradation rate under forced composting is 93.8% within 90 days.

Example Embodiment

[0039] Example 3

[0040] The difference between this example and Example 1 is that the composition ratio of the modified polylactic acid blown film grade resin is different. In terms of weight percentage, the modified polylactic acid blown film grade resin of this embodiment is composed of the following components production:

[0041]

[0042] The modified polylactic acid blown film grade resin provided in this example is used to make a film product, which is stored for 18 months at a normal temperature of 23°C with no change; the biodegradation rate under forced composting is 94.6% within 90 days.

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Abstract

The invention provides an all-biodegradable modified polylactic acid film-blowing resin and a preparation method thereof. The modified polylactic acid film-blowing resin comprises 20-60% of polylactic acid, 20-45% of polyadipic acid/butylene terephthalate, 12-20% of polypropylene carbonate resin, 3-5% of talcum powder, 1-2% of ethylene-acrylic acid copolymer, 1.5-3% of chain extender, 0.5-1% of erucyl amide, 0.5-1% of zinc stearate, 0.5-1% of melt strength enhancer, 0.5-1% of hydrolysis-resistant stabilizer and 0.5-1% of PE (polyethylene) wax. The film product prepared from the resin is stable at normal temperature, and has the biodegradability of at least 92% within 90 days under the condition of forced composting, thereby completely satisfying the requirements in relevant standards, The physical properties are greatly maintained, and the cost is lower than that of like products. The resin can be widely used in the fields of film packaging, agricultural mulching films, refuse classification landfilling and composting, and the like.

Description

technical field [0001] The invention relates to the field of biodegradable materials, in particular to a completely biodegradable modified polylactic acid blown film grade resin and a preparation method thereof. Background technique [0002] With the improvement of people's living standards, the requirements for the environment are getting higher and higher. At the same time, countries are paying more and more attention to the protection of the environment. Plastic is a very common material in daily life and industrial production. The degradation rate is very slow, even non-degradable, resulting in white pollution. In this regard, there are more and more researches and developments on biodegradable resins. At present, there are also many degradable materials produced and used in some daily life Among them, such as garbage bags, shopping bags, etc., are generally degradable materials (such as photodegradation, oxidative degradation, etc.), although they bring the excellent pe...

Claims

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Application Information

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IPC IPC(8): C08L67/04C08L67/02C08L69/00C08L23/08C08L23/06C08K3/34C08K5/20C08K5/098
Inventor 杜俊速杜泽鑫
Owner 广东华芝路生物材料有限公司
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