Active carbon absorbent for removing mercury in flue gas

An activated carbon adsorption and activated carbon technology, which is applied in the field of air purification, can solve the problems that oxidants are difficult to enter and deposit on the surface, and achieve the effects of stable adsorption, improved pore structure, and simple operation

Inactive Publication Date: 2015-11-18
QINGDAO JINZHI HIGH NEW TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] However, since the pore size distribution of activated carbon is mainly concentrated in the micropore area, and the micropores are too small for the oxidant molecules, it is difficult for the oxidant to enter the inner pores of the activated carbon, so the oxidant loaded on the activated carbon is only deposited on the surface.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Anthracite is removed from impurities and pulverized into particles with a particle size of 0.01-0.1mm; polymethacrylate is added and stirred for molding, calcined at 120°C for 10 hours, calcined at 800°C for 12 hours, and activated at 800°C and water vapor for 24 hours, The activated carbon is obtained; an aqueous solution of calcium nitrate with a mass concentration of 20% is prepared; the activated carbon is immersed in the obtained aqueous solution for 15 hours; the activated carbon impregnated with the aqueous solution is frozen at a low temperature of -30°C for 2 hours; the temperature is raised to 120°C and dried for 3 hours; Activated under supercritical water conditions for 3h; washed with water at room temperature, then immersed in 15wt% ammonium persulfate solution at 50℃ for 5h; dried to obtain modified activated carbon support;

Embodiment 2

[0024] Coal-based activated carbon with 30% ignition loss is immersed in a 25wt% calcium nitrate aqueous solution for 10 hours; the activated carbon impregnated with the aqueous solution is frozen at a low temperature of -20°C for 3 hours; heated to 150°C and dried for 2 hours; activated under supercritical water conditions 3h; wash with water at room temperature, immerse in 20wt% sodium persulfide solution for 10h at 50℃; 1 dry to obtain modified activated carbon carrier;

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PUM

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Abstract

The invention aims to provide an active carbon absorbent for removing heavy metals especially mercury in flue gas and a preparation method thereof. By improving the preparation method of active carbon, the ratio of mesoporous pore canals in active carbon is increased, thus the oxidant load capacity and dispersion degree of active carbon are both improved; the performance of active carbon on absorbing mercury is enhanced, thus the mercury can be removed more easily, and moreover, the provided method has little pollution and can be applied to the industry.

Description

Technical field [0001] The invention relates to an activated carbon adsorbent for removing heavy metals in flue gas and a preparation method thereof, belonging to the field of air purification. Background technique [0002] As the main energy source of our country, the flue gas produced by coal contains a lot of heavy metals. These harmful or potentially harmful trace elements will be discharged into the atmosphere in different forms, causing a certain degree of air pollution. Although the content of harmful metal elements in coal is very low, due to the huge consumption of coal, its harm to the environment cannot be ignored. The "Clean Atmosphere Amendment" (CAAA) regulation, an amendment to the Air Purification Regulation passed by the US Congress in 1990, focused on strengthening the emission control of metal hazardous gas pollutants (HAP), mainly Hg, Cd, Pb, Cr and As, etc. . Among the 11 metals listed in the bill, mercury ranks first among toxic metals in terms of emission...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/20B01J20/30B01D53/02
Inventor 不公告发明人
Owner QINGDAO JINZHI HIGH NEW TECH
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