Zinc borate corrosion preventing and flame retarding agent

A zinc borate and flame retardant technology, applied in the field of flame retardants, can solve the problems of reducing the flame-retardant and anti-corrosion effect of borides, the application range is not very wide, and the loss resistance is poor, so as to suppress smoke and poisonous gas, enhance anti-corrosion performance, Good flame retardant effect

Inactive Publication Date: 2015-12-30
FUJIAN ZHANGPING KIMURA FORESTRY PROD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But its biggest shortcoming is that it has not been able to effectively fix it in wood so far, and its resistance to loss is poor.
In order to improve the loss resistance of borides, the measures currently taken mainly include 1. Apply a layer of waterproof paint on the treated wood surface or impregnate it with oil-borne preservatives and use it outdoors or in an environment that is in contact with the ground. The effect of this method is Generally, and the maintenance cost is high; 2. Impregnating borides and polymer monomers (such as adhesives) into wood together, as the monomers polymerize into polymers, encapsulating borides in polymers can also be used Reduce the loss of borides, but this method reduces the flame-retardant and anti-corrosion effect of borides, so the scope of use is not very wide

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] Dissolve 5kg of anhydrous zinc borate in 28kg of 20% ammonia water (the ammonia content is 5.6kg), add 9.4kg of 2-aminoethanol, 10kg of 50% dodecyl benzyl dimethyl ammonium chloride (dodecyl The content of benzyl dimethyl ammonium chloride is 5kg) and 47.6kg water, fully mixes and stirs, promptly makes the weight / weight of all substances] zinc borate anticorrosion flame retardant formulations. In mass production, feed in proportion, fully stir and react in a stainless steel reactor for 1.5-3 hours, and fill it after cooling.

[0017] The above-prepared zinc borate anticorrosion and flame retardant is used for the full-cell anticorrosion and flame-retardant treatment of wood, including the following steps:

[0018] (1) Dilute with water to configure zinc borate anti-corrosion and flame-retardant liquid, zinc borate anti-corrosion and flame retardant: water = 1:5;

[0019] (2) Put the wood in the impregnation tank and vacuumize it to make the vacuum in the impregnation...

Embodiment 2

[0025] 10kg anhydrous zinc borate, 2-aminoethanol of 30kg, 20kg of 50% didecyl dimethyl ammonium chloride (the content of didecyl dimethyl ammonium chloride is 10kg) and 40kg water, fully mix and stir, promptly make The zinc borate anticorrosion and flame retardant preparation with an effective concentration of 20% [(zinc borate+didecyl dimethyl ammonium chloride) weight / weight of all substances] is obtained.

[0026] The above-prepared zinc borate anticorrosion and flame retardant is used for the full-cell anticorrosion and flame-retardant treatment of wood, including the following steps:

[0027] (1) Dilute with water to configure zinc borate anti-corrosion and flame-retardant liquid, zinc borate anti-corrosion and flame retardant: water = 1:10;

[0028] (2) Put the wood in the impregnation tank, and vacuumize it to make the vacuum degree in the impregnation tank reach -0.086Mpa, keep the constant pressure for 0.3 hours, and carry out the pre-vacuum operation;

[0029] (3) ...

Embodiment 3

[0034] 10kg of zinc borate 3.5 water (the content of zinc borate is 8.55kg), 34.2kg of 50% ammonia water (the content of ammonia is 17.1kg), 19.95kg of aminoethanol, 19kg of 60% octadecyldecyldimethylammonium chloride (the content of octadecyldecyl dimethyl ammonium chloride is 11.4kg) and 16.85kg water, fully mixes and stirs, promptly makes effective concentration 19.95% [(zinc borate+dodecyl benzyl dimethyl chloride The weight of ammonium chloride) / the weight of all substances] zinc borate anticorrosion flame retardant preparation.

[0035] The above-prepared zinc borate anticorrosion and flame retardant is used for the full-cell anticorrosion and flame-retardant treatment of wood, including the following steps:

[0036] (1) Dilute with water to configure zinc borate anti-corrosion and flame-retardant liquid, zinc borate anti-corrosion and flame retardant: water = 1:10;

[0037] (2) Put the wood in the impregnation tank and pump the vacuum to make the vacuum degree in the i...

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PUM

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Abstract

The invention relates to a zinc borate corrosion preventing and flame retarding agent which is solvent prepared from effective ingredients and water. The effective ingredients comprise 10-20 wt% of zinc borate, 0-47 wt% of ammonia, 6-60 wt% of 2-aminoethanol and 10-20 wt% of quaternary ammonium surfactants. According to the zinc borate corrosion preventing and flame retarding agent, the problem that a borate flame retarding and corrosion preventing agent is poor in leachability is solved, and the zinc borate which cannot be easily dissolved in water is prepared into a soluble complex which can enable wood to be completely permeated and is finally combined with wood fiber in the mode of the zinc borate; the treated wood is colorless and odorless, the flame retarding and corrosion preventing effects are simultaneously achieved, harm of fungi, moulds, termites, longhorn beetles, lyctus and carpenter bees to the wood can be effectively resisted, the good smoke inhibiting effect and the good leachability resistance are achieved, the leachability of the normally-used borate flame retarding and corrosion preventing agent is larger than or equal to 80 percent, and the leachability of the zinc borate is about 3 percent.

Description

technical field [0001] The invention relates to a flame retardant, in particular to a zinc borate anticorrosion flame retardant. Background technique [0002] In recent years, borides have been widely used in the food antiseptic industry and indoor flame retardant industry due to their good anti-corrosion and anti-mold effects and considerable flame-retardant effects, which are non-toxic and environmentally friendly to humans and animals. With the improvement of people's environmental protection requirements, the application of colorless, odorless and non-toxic boride preservatives in the wood preservation industry is also increasing. Boron compounds currently used in mass production of anti-corrosion and flame-retardant wood mainly include: Borax decahydrate: Na 2 B 4 o 7 10H 2 O, (wherein the percentage of boron is 11.34%); Borax pentahydrate: Na 2 B 4 o 7 ·5H 2 O, (wherein the percentage of boron is 14.84%); boric acid: H 3 BO 3 , (wherein the percentage of boro...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B27K3/52
Inventor 黄键张益宏陈云峰
Owner FUJIAN ZHANGPING KIMURA FORESTRY PROD
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